Electronic package and method of preparing same
A technology of electronic components and electronic devices, applied in the direction of electrical components, electrical solid devices, circuits, etc., can solve the problems of barrier coating cracking, reducing the effectiveness of coatings and device reliability, etc., and achieve the effect of low compressive stress
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[0039] The method for preparing electronic components of the present invention comprises:
forming a first inorganic barrier coating over a substrate and at least one electronic device having electrical connections disposed on or within the substrate;
forming a first interfacial coating on the first inorganic barrier coating in a region above the electronic device, wherein the first interfacial coating comprises a cured product of a silicone resin; and
forming a second inorganic barrier coating on the first interfacial coating and on any portion of the first inorganic barrier coating not covered by the first interfacial coating; provided that at least a portion of each electrical connection is not coated .
[0040] According to the aforementioned method of making an electronic assembly, a first inorganic barrier coating is formed on a substrate and at least one electronic device having electrical connections, wherein the electronic device is disposed on or within the substr...
Embodiment 1
[0171] Toluene (2400g), 2.40mol of 3-glycidoxypropyltrimethoxysilane, 4.80mol of methyltrimethoxysilane, 28.8mol of water, 2.4mL of tetramethylammonium hydroxide (25% aqueous solution ), and the methanol of 2400g are combined in the flask. The mixture was stirred and heated to reflux for 2 hours during which time 6950 g of solvent, mainly methanol, was removed by distillation using a Dean-Stark trap. During the distillation, toluene was added to the mixture to maintain a constant resin concentration. The temperature of the mixture was slowly raised to about 110°C over the course of about 1 hour. The mixture was then allowed to cool to room temperature. Acetic acid (3.4 mL) was then added dropwise to the stirred mixture over a period of 1 hour. The mixture was washed with 1,600 mL of deionized water (ten times), then filtered. Toluene was removed under reduced pressure using a rotary evaporator at 40 °C. The residue was placed under vacuum (1 Pa) at room temperature for 3 ...
Embodiment 2
[0172] Toluene (80 g), 0.20 mol of 3-methacryloxypropyltrimethoxysilane, 0.40 mol of phenyltrimethoxysilane, 2.40 mol of water, 1 g of 50% (w / w) hydrogen An aqueous cesium solution, 200 g of methanol, and 40 mg of 2,6-di-tert-butyl-4-methylphenol were combined in a flask. The solution was heated to reflux for 1 hour during which time 250 g of solvent was removed by distillation using a Dean-Stark trap, mainly methanol. During the distillation, toluene was added to the mixture to maintain a constant resin concentration. The temperature of the mixture was slowly raised to about 105°C over the course of about 1 hour. The mixture was then allowed to cool to room temperature. Toluene was removed under reduced pressure using a rotary evaporator at 40 °C. The residue was placed under vacuum (1 Pa) at room temperature for 3 hours to obtain a silicone resin of the formula:
(PhSiO 3 / 2 ) 0.67 (CH 2 =C(CH 3 )C(=O)OCH 2 CH 2 CH 2 SiO 3 / 2 ) 0.33 ,
as passed 29 Si NMR and 1...
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