Preparation of light colore high softening point maleated rosin pentaerythritol
A technology of rosin pentaerythritol ester and high softening point, which is applied in the chemical modification of natural resins, etc., can solve problems such as difficult color reduction, and achieve the effect of improving hardness
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0020] A kind of preparation method of light color high softening point maleic rosin pentaerythritol ester, comprises the steps:
[0021] In the first step, the rosin is refined under the conditions of a vacuum of 0-1kPa and a temperature of 200-270°C to obtain a refined rosin with a softening point of 80-86°C;
[0022] In the second step, under the protection of inert gas, add maleic anhydride of 5-14% of the mass of refined rosin and reducing agent of 0.03-1.0% of the mass of refined rosin to the molten refined rosin, and heat it at a temperature of 150-230°C The reaction time is 0.5-2h; Among them, the reducing agent is phosphite or phosphite esters: such as sodium phosphite, triphenyl phosphite, phenylenedioctyl phosphite, 3,5-di-tert- -An arbitrary proportion mixture of one or several kinds of 4-hydroxybenzyl diethylphosphonate; the proportion of maleic rosin in the quality of refined rosin can be 5%, 8%, 9%, 10%, 11% , 12%, the proportion of reducing agent in the qualit...
Embodiment 2
[0028] 98g rosin essence is made 87g refined rosin, feeds N 2, heat to melt, add 0.183g of triphenyl phosphite, 4.4g of maleic anhydride, raise the temperature to 180°C, and keep it for 1h, continue to raise the temperature, and add bis(3,5-di-tert-butyl-4-hydroxybenzyl Monoethyl phosphonate) calcium 0.17g, 2,2'-thiobis(4-methyl-6-tert-butylphenol) 0.17g, pentaerythritol 11.4g, pentaerythritol was uniformly added to the reaction system within 0.5 hours . The temperature was raised to 270°C, and 0.15 g of tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid]pentaerythritol ester and 0.15 g of alkylphenol disulfide oligomer were added after 1 hour. Regular sampling. When the acid value drops to 20 mg / g, decompress and evacuate.
[0029] After 2.5 hours of esterification in this example, the acid value of the product dropped to 16mg / g, the color was Ghana Color No. 2, and the softening point was 124°C.
Embodiment 3
[0031] 114g rosin essence is made 102g refined rosin, feeds N 2 , heat and melt, add 0.05g of triphenyl phosphite, 7.2g of maleic anhydride, raise the temperature to 180°C, and keep it for 1h, continue to raise the temperature, and add tetrakis[β-(3,5-di-tert-butyl-4 -Hydroxyphenyl)propionic acid]pentaerythritol ester 0.11g, 4,4'-thiobis(6-tert-butyl-3-methylphenol) 0.15g, pentaerythritol 14.1g, pentaerythritol was evenly added to the reaction within 0.5 hours in the system. Raise the temperature to 270°C, add 0.13 g of bis(3,5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester) calcium, 2,2'-thiobis(4-methyl-6- tert-butylphenol) 0.11 g. Regular sampling. When the acid value drops to 20 mg / g, decompress and evacuate.
[0032] After 2.5 hours of esterification in this example, the acid value of the product dropped to 15.6 mg / g, the color was Ghana color number 2+, and the softening point was 135°C.
PUM
Property | Measurement | Unit |
---|---|---|
Acid value | aaaaa | aaaaa |
Softening point | aaaaa | aaaaa |
Acid value | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com