Cross-linking agent and crease finishing agent of sucrose glycidyl ether and synthesizing method thereof
A technology of glycidyl ether and anti-wrinkle finishing agent, which is applied in the field of fabric grafting crosslinking agent and anti-wrinkle finishing agent and its synthesis, can solve the problems of slow release of formaldehyde from fabric, yellowing of fabric or fiber, and no crosslinking agent. Achieve good cross-linking and anti-wrinkle finishing effect, low cost, good water-soluble effect
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Embodiment 1
[0018] Put a 500mL beaker containing 200mL of 10% sucrose aqueous solution in a constant temperature water bath, the temperature of the constant temperature water bath is 20°C, slowly add 45g of epichlorohydrin, 0.2g of tetrabutylammonium bromide, and 19.5g of sodium hydroxide , mechanically stirred; after the epichlorohydrin was added dropwise, the temperature rose to 35°C, and the reaction was stirred at a constant temperature for 4 hours, and then a small amount of excess sodium hydroxide in the reaction solution was neutralized with sulfuric acid to obtain sucrose glycidyl ether.
Embodiment 2
[0020] Put the 500mL beaker containing 300mL mass percentage concentration of 10% sucrose aqueous solution into a constant temperature water bath, the temperature of the constant temperature water bath is 20°C, slowly add 68g epichlorohydrin, 0.3g tetrabutylammonium bromide, 30g sodium hydroxide, Stir mechanically; after the epichlorohydrin is added dropwise, the temperature rises to 35°C, and the reaction is stirred at a constant temperature for 4 hours, and then a small amount of excess sodium hydroxide in the reaction solution is neutralized with sulfuric acid to obtain sucrose glycidyl ether.
Embodiment 3
[0022] A 500mL beaker containing 350mL of 10% sucrose aqueous solution was put into a constant temperature water bath, the temperature of the constant temperature water bath was 25°C, slowly added 78g of epichlorohydrin, 0.37g of tetrabutylammonium bromide, and 35g of sodium hydroxide, Stir mechanically; after the epichlorohydrin is added dropwise, the temperature rises to 35°C, and the reaction is stirred at a constant temperature for 6 hours, and then a small amount of excess sodium hydroxide in the reaction solution is neutralized with sulfuric acid to obtain sucrose glycidyl ether.
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