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Waterborne normal-temperature self-crosslinking acrylic acid modified alkyd antirust paint

A technology of self-crosslinking acrylic and alkyd antirust paint, which is applied in the direction of anti-corrosion coatings, polyester coatings, coatings, etc., can solve problems such as being easily hydrolyzed, and achieve cost-effectiveness, fast drying, and low VOC emissions. Effect

Inactive Publication Date: 2009-12-02
CHANGZHOU GUANGHUI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to overcome the above-mentioned defects, the technical problem to be solved in the present invention is to provide a water-based normal temperature self-crosslinking acrylic acid modified alkyd resin for the problem that the side chain ester of the existing water-based alkyd resin is easily hydrolyzed in an alkaline aqueous solution. rust paint

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0016] 1. Synthesis of BM-6 core-shell configuration acrylic modified alkyd emulsion:

[0017] A. The composition of the matrix alkyd resin: high iodine value dry oil mixed acid: 10 kg; soybean oil: 40 kg; trimethylolpropane: 20 kg; 1.3-methylpropanediol: 6 kg; isophthalic acid : 19 kg; ε-polyacid: 5 kg; additives: 0.3 kg; deionized water: 70 kg; acrylic acid: 20 kg.

[0018] Synthetic process: First, according to the proportion of the formula, 10 kg of high iodine value dry oil mixed acid, 40 kg of soybean oil, 20 kg of trimethylolpropane, 6 kg of 1.3-methylpropanediol, and 19 kg of isophthalic acid are put into stainless steel Resin synthesis kettle, then heat the material to 100-120°C, start the mixer, then stir while raising the temperature until the temperature of the material reaches 190-220°C, control the heating amount, keep the material warm for esterification reaction, and at the same time separate the esterification water, Keep it for 4-6 hours. During the period, ...

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PUM

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Abstract

The invention relates to the technical field of waterborne antirust paint, in particular to modified alkyd resin antirust paint and a preparation method thereof. The waterborne normal-temperature self-crosslinking acrylic acid modified alkyd antirust paint has a formula as follows: 33 to 35 mass percent of core-shell acrylic acid modified alkyd emulsion, 18 to 21 mass percent of antirust pigment, 18 to 20 mass percent of filling material, 0.25 to 0.35 mass percent of defoaming agent, leveling agent and dispersing agent, 0.02 to 0.05 mass percent of pH adjusting agent, 0.2 to 0.5 mass percent of waterborne drier and 25 mass percent of deionized water; and the core-shell acrylic acid modified alkyd emulsion is put into a paint preparing jar, the pH value is adjusted by the pH adjusting agent, the core-shell acrylic acid modified alkyd emulsion is added with the antirust pigment, the filling material, the defoaming agent, the leveling agent, the dispersing agent and the deionized water, the mixture is stirred, dispersed, ground to the fineness less than or equal to 50 um and supplemented with the waterborne drier, the mixture is evenly stirred and subjected to pH adjustment to obtain a finished product of the waterborne normal-temperature self-crosslinking acrylic acid modified alkyd antirust paint.

Description

technical field [0001] The invention relates to the technical field of water-based antirust paint, in particular to a modified alkyd resin antirust paint and a preparation method thereof. Background technique [0002] The origin of water-based antirust paint can be traced back to the 1960s, when Rohm&Hass in the United States first introduced the acrylic emulsion antirust paint-Rhoplex MV-1 for steel surfaces. The research work of emulsion type acrylic metal anticorrosion paint in our country began in 1975. The former Institute of Paint Industry of the Ministry of Chemical Industry first developed the antirust emulsion primer BBL, which achieved good results in natural exposure and tests in Dalian, Qinhuangdao and other places. After more than 40 years of development, the water-based one-component antirust paint has roughly gone through the following stages according to the different water-based film-forming substances used: the first generation of water-based resin: the emu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D167/08C09D5/08
Inventor 许建刚赵绍洪张辉跃陆小英
Owner CHANGZHOU GUANGHUI CHEM
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