Refractory castable for desulfurization stirrer

A refractory castable and castable technology, which is applied in the field of refractory materials for hot metal desulfurization pretreatment, can solve the problems affecting the service life of the agitator, high-temperature melt penetration and tissue deterioration, high sintering temperature of silicon carbide materials, etc., which affect the improvement effect of castables. Achieve the effects of improving compactness and slag penetration resistance, excellent sintering condition, and improving sintering condition

Inactive Publication Date: 2010-10-13
WUHAN IRON & STEEL (GROUP) CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the serious problem of high-temperature oxidation of steel fibers, it is restricted from fully exerting its effects on improving the strength of castables and thermal shock stability, resulting in serious thermal shock cracking and crack peeling of the working lining of agitator castables; in addition, due to The sintering temperature of silicon carbide material is high, and the addition of a high proportion is not conducive to the improvement of the m

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017]Take the production of 101.65kg refractory castable as an example. Among them, castable base material 100kg, additive 1.65kg. The components and weight of the castable base material are: sintered zirconium mullite: 33kg (of which: 18kg with a particle size of 5-8mm, and 15kg with a particle size of 8-15mm), ordinary electric fused mullite: 26kg (Among them: 3kg with a particle size of 0.1-1mm, 8kg with a particle size of 1-3mm, and 15kg with a particle size of 3-8mm), coke gem: 9kg (with a particle size of 0.1-1mm), kyanite: 4kg (with a particle size 150 mesh), super-grade high-alumina bauxite clinker: 10kg (of which: 180 mesh 5kg, 325 mesh 5kg), silica powder: 3kg, α-Al 2 o 3 Micropowder: 3kg, ρ-Al 2 o 3 Micropowder: 8kg, pure calcium aluminate cement: 1.5kg, dense corundum fine powder: 2.5kg (325 meshes in particle size); the components and weight of additives are: heat-resistant steel fiber: 1kg, polypropylene fiber: 0.15kg, Melamine: 0.5kg.

[0018] The above-m...

Embodiment 2

[0020] Take the production of 102.85kg refractory castable as an example. Among them, castable base material 100kg, additive 2.85kg. The components and weight of the castable base material are: sintered zirconium mullite: 26kg (of which: 14kg for 5-8mm particle size, 12kg for 8-15mm particle size), ordinary fused mullite: 35kg (Among them: 4kg with a particle size of 0.1-1mm, 11kg with a particle size of 1-3mm, and 20kg with a particle size of 3-8mm), coke gem: 5kg (with a particle size of 0.1-1mm), kyanite: 7kg (with a particle size 150 mesh), super-grade high-alumina bauxite clinker: 7kg (of which: 3kg for 180 mesh, 4kg for 325 mesh), silica powder: 5kg, α-Al 2 o 3 Micropowder: 5kg, ρ-Al 2 o 3 Micropowder: 5kg, pure calcium aluminate cement: 3.5kg, dense corundum fine powder: 1.5kg (particle size is 325 mesh). The components and weight of the additives are: heat-resistant steel fiber 2kg, metal aluminum powder 0.35kg, sodium tripolyphosphate 0.15kg, melamine 0.35kg.

...

Embodiment 3

[0023] Take the production of 102.3kg refractory castable as an example. Among them, castable base material 100kg, additive 2.3kg. The components and their weights of the castable base material are: sintered zirconium mullite: 30kg (of which: 16kg with a particle size of 5-8mm, and 14kg with a particle size of 8-15mm), ordinary fused mullite: 32kg (Among them: 4kg with a particle size of 0.1-1mm, 10kg with a particle size of 1-3mm, and 18kg with a particle size of 3-8mm), burnt gems: 8kg (with a particle size of 0.1-1mm), kyanite: 6kg (with a particle size 150 mesh), super-grade high-alumina bauxite clinker: 5kg (of which 2kg is 180 mesh, 3kg is 325 mesh), silicon powder: 3.5kg, α-Al 2 o 3 Micropowder: 3.5kg, ρ-Al 2 o 3 Micropowder: 6kg, pure calcium aluminate cement: 2.5kg, dense corundum fine powder: 3.5kg (325 meshes). The components and weight of the additive are: 1.5kg of heat-resistant steel fiber, 0.5kg of metal aluminum powder, and 0.3kg of sodium tripolyphosphate...

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PUM

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Abstract

The invention discloses a refractory castable for a desulfurization stirrer, which is prepared by mixing a castable base material and a proper amount of additives, wherein the castable base material comprises the following components in percentage by weight: 26-33% of sintered zirconium mullite, 26-35% of common fused mullite, 5-9% of flint clay, 4-7% of kyanite, 5-10% of superfine bauxite chamotte, 3-5% of fine silicon powder, 3-5% of fine alpha-Al2O3 powder, 5-8% of fine rho-Al2O3 powder, 1.5-3.5% of pure calcium aluminate cement and 1.5-3.5% of dense fine alundum powder. The additives comprise three or more of 1-2% of heat-proof steel fiber, 0-0.15% of polypropylene fiber, 0-0.5% of metallic aluminum powder, 0-0.3% of sodium tripolyphosphate and 0-0.5% of melamine based on the weight of the castable base material. The refractory castable has the advantages of good performance, low cost and wide sources of raw materials. Compared with the prior art, the refractory castable can enable the average service life of KR desulfurization stirrers to be improved by more than 100 times.

Description

technical field [0001] The invention belongs to a refractory material for desulfurization pretreatment of molten iron in a molten iron tank, in particular to a refractory castable for a desulfurization agitator. Background technique [0002] At present, the desulfurization agitator used in the external stirring desulfurization of the molten iron furnace before the converter steelmaking in the surrounding metallurgical enterprises is composed of a stirring metal core and a refractory lining. Among them, the refractory materials for the lining body of the agitator are all mullite refractory castables. Taking the KR hot metal desulfurization mixer in the second steelmaking plant of Wuhan Iron and Steel (Group) Company as an example, it can be seen from its production regulations that the main component of the refractory castable used is Al 2 o 3 ≥60%, SiO 2 It accounts for 30-35%; its physical properties are: compressive strength 110℃×24h≥24Mpa, 1500℃×3h≥60Mpa, bulk density ...

Claims

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Application Information

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IPC IPC(8): C04B35/66
Inventor 欧阳德刚罗安智罗巍朱善合李明晖王海青胡清明张爱平
Owner WUHAN IRON & STEEL (GROUP) CORP
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