Method and apparatus for treating high-temperature slag

A processing method and processing device technology, applied in the direction of processing discharged materials, furnaces, furnace components, etc., can solve the problems of low cooling efficiency, long time, huge equipment and cost, etc., to achieve improved recovery efficiency, high separation efficiency, The effect of cheap equipment cost

Active Publication Date: 2010-10-27
NIPPON STEEL CORP
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, cooling by spraying a large amount of water in a pit or field has the following problems: Since the cooling efficiency is low, it takes a long time for cooling, and, in order to Prevents scattering of dust generated from the surface of solidified slag, increasing dust collection cost
[0010] In addition, as mentioned above, the slag is separated into pig iron and slag by passing the slag several times through the crusher and the magnetic separator, but the solidified slag has a relatively high hardness, Therefore, if a powerful crusher is not used, it cannot be crushed sufficiently
In addition, there is also the following problem: the pig iron obtained in this way has a low iron content because the slag is not sufficiently separated, and even if it passes through a second-stage crusher, only 70 to 80% of the iron content can be obtained. Class crushers can only get 80-90% iron content
However, this method requires huge equipment and costs for high-temperature pressure vessels, and cannot avoid water vapor explosion accidents.
In addition, there are the same problems as those in JP-A-6-346161: the obtained slag lumps have a large particle size deviation, and mechanical crushing requires wind separation, and the iron content of pig iron is 50-90%, and the grade is low. Moreover, the deviation is large, and it is difficult to use it in a steelmaking furnace, etc.
[0018] In this way, although various methods related to the processing method of high-temperature slag have been proposed, they have not been put into practical use due to the above reasons. Such as Figure 6, Figure 7 shows the inefficient and costly method for steelmaking slag containing CaO and other high temperature slags for processing
This conventional method has left many problems as follows: the generation of dust after discharge from the slag pan and / or the occurrence of fire powder and flames is large, and the equipment is also degraded early. In addition, the remaining CaO in the slag is effectively used as a roadbed material. hindrance, etc.
However, this technology is a technology for recovering heat from slag, and there is no suggestion of efficiently cooling slag or recovering pig iron in slag

Method used

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  • Method and apparatus for treating high-temperature slag

Examples

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Effect test

Embodiment 1

[0113] About 20 tons of molten iron pretreatment slag containing CaO at about 1300 °C generated when CaO powder was blown in for dephosphorization and desulfurization of molten iron was transferred to such as figure 1 The shown pit covered with steel slag was stirred to a uniform thickness, and then water was sprayed on the surface to cool down to 1000°C once. The thickness of the slag layer is 0.25 m and its area is about 6 m x 5 m. The cooling water evaporates instantly without producing free water.

[0114] The slag which has been cooled once in this way is put into the hopper, and the large pieces of pig iron are separated and removed by a grid screen, and thereafter, it is supplied to a slag with a diameter of about 2m and a length of about 8m. figure 1 The rotary cooler shown in , with secondary cooling. The slag temperature at the slag charging port of the rotary cooler was 850°C. Inject 142m to the slag 3 / hour of cooling air, air cooling inside the rotary coole...

Embodiment 2

[0119] The present invention was carried out using 1,000 tons of steelmaking slag discharged from the steelmaking process. The temperature of the slag discharged from the furnace is about 1400°C in a molten state, and it is Figure 4 The shown cooling pit was allowed to stand for 20 minutes to solidify, and instead of spraying cooling water as in the past, a 3.0m 3 / hour, 5 minutes of water spray cooling. Next, the slag was excavated by a power excavator and put into a rotary cooler. The feeding rate is 10 tons / hour, and the slag temperature at the time of feeding is about 1000°C.

[0120] The casing (shell) of the rotary cooler was rotated at 5 rpm, the residence time of the slag inside was 20 minutes, and 400 m of slag was supplied to the inside of the casing (shell). 3 / min of cooling air and 5m 3 / hour of cooling water. No free water was produced in this water cooling. Formed inside the case (shell) as Figure 5 As shown in the protrusion, the slag is crushed by th...

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Abstract

A method in which slag is cooled in a treatment step without generating strongly alkaline water and without necessitating a prolonged time for the treatment. Using this method, slag is efficiently recovered as a valuable material and the metal contained in the slag is efficiently recovered. Also provided is an apparatus for the method. High-temperature slag containing CaO is subjected to primary cooling and thereafter subjected to secondary cooling while being moved inside a cooler. Both the primary cooling and the secondary cooling are water cooling conducted to such a degree that no free water is generated. A rotary cooler comprising a housing equipped with projections on the inner surface thereof can be used as the cooler. Slag having a temperature as high as 500 DEG C or above is charged into the rotary cooler and cooled. The slag is separated into slag and a metal by means of the crushing that occurs due to impact when the slag falls due to the rotation of the housing and by the destruction caused by the rapid cooling of the slag.

Description

technical field [0001] The present invention relates to a processing method and a processing device for high-temperature slag discharged at a high temperature of 1200° C. or higher from a molten iron pretreatment process, a molten iron pretreatment furnace, a converter, an electric furnace, etc. in a steelmaking process. Specifically, it relates to a treatment method and a treatment device for effectively cooling molten iron pretreatment slag, converter slag, electric furnace slag, etc. containing CaO discharged at high temperature from a molten iron pretreatment furnace, a converter, an electric furnace, etc., and at a low cost. Furthermore, the pig iron contained in these slags is efficiently separated and recovered, so that the slags can be effectively used for roadbed materials, marine materials, and the like. Background technique [0002] A large amount of high-temperature slag containing CaO at 1200-1600°C is produced and discharged from the molten iron pretreatment pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/28C04B5/00C21C1/02C21C7/00F27D15/00F27D15/02
CPCF27D15/02C21B2300/02C04B5/00C21B3/08C21B2400/024C21B2400/052C21B2400/056
Inventor 田崎智晶务川进天田克己佐久间诚也井手雅明浦川伦明
Owner NIPPON STEEL CORP
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