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Electrochemical polymerization solution and electrochemical polymerization process for preparing solid electrolyte layer on capacitor

A technology of solid electrolyte layer and polymerization process, applied in the field of electrochemical polymerization solution and process, can solve the problems of high control cost and general performance in solid electrolytic capacitors, and achieve the effects of reduced control cost, low toxicity and common materials.

Active Publication Date: 2013-11-20
福建国光新业科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although electrolytes with higher conductivity can be obtained, the medium performance reflected in solid electrolytic capacitors is relatively general, and in large-scale production, it is necessary to control the diffusion of toxicity and the large amount of volatilization of solvents, and the cost of control is extremely high

Method used

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  • Electrochemical polymerization solution and electrochemical polymerization process for preparing solid electrolyte layer on capacitor

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Embodiment 1

[0011] The first solid electrolyte layer polypyrrole is prepared by chemical polymerization of a 13VF aluminum foil containing alumina (effective area 3.5mm × 4.0mm), and then an electrochemical polymerization process is performed. Specifically, the aluminum foil containing the first solid electrolyte layer polypyrrole is mixed with The external electrode is connected as the anode, with 2cm 2 The carbon conductive electrode was the cathode, and galvanostatic polymerization was carried out at 10°C in an aqueous solution containing 0.4M Py (pyrrole monomer) and 0.3M p-toluenesulfonate. The continuous time of the solution is controlled within 24 hours, and the polymerization electricity is 0.5C (coulomb). Then washing and drying, the second solid electrolyte layer polypyrrole is obtained. After the electrochemical polymerization process is completed, a carbon-containing cathode layer and a silver-containing cathode layer are sequentially formed on the outer surface of the second...

Embodiment 2

[0013] Different from Example 1, with 10cm 2 The carbon conductive electrode is used as the cathode, which is electrochemically polymerized in an ethanol solution at 0 °C with a polymerization charge of 1.0 C, and the continuous use of the solution is controlled within 96 hours.

Embodiment 3

[0015] Different from Example 1, with 1cm 2 The titanium conductive electrode is used as the cathode, which is electrochemically polymerized in a mixed solution of butanol and pure water at 30°C.

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Abstract

The invention provides an electrochemical polymerization solution and an electrochemical polymerization process for preparing a solid electrolyte layer on a capacitor. In the electrochemical polymerization solution, water, an organic solvent containing hydroxyl groups, a mixed solution of water and the organic solvent containing hydroxyl groups or a mixture of more than two kinds of organic solvents is taken as the solvent. The electrochemical polymerization process comprising the following steps: an anode body provided with a first solid electrolyte layer on the surface is connected with an external electrode to serve as an anode, a conductive electrode is adopted as a cathode, the constant current polymerization is performed in the electrochemical polymerization solution, then the anode and the cathode are cleaned and dried after being taken out, and a second solid electrolyte layer is prepared. The electrochemical polymerization solution has the advantages of wide raw materials, extremely low toxicity and easily-controlled large-scale production. Through the adoption of the electrochemical polymerization process, the rate of capacitance withdrawing of the solid electrolytic capacitor can be promoted, the ESR (equivalent series resistance) can be reduced, and the reliability can be enhanced at high temperature and high humidity.

Description

【Technical field】 [0001] The invention relates to a preparation process of a solid electrolytic capacitor, in particular to an electrochemical polymerization solution and a process for forming a solid electrolyte layer of the solid electrolytic capacitor. 【Background technique】 [0002] With the development of modern electronic products, high-frequency electronic equipment has also developed rapidly. For solid electrolytic capacitors used in the periphery of CPUs of personal computers, there is an increasing demand for large-capacity and excellent high-frequency characteristics. In order to obtain an electrolytic capacitor with excellent high-frequency characteristics, the equivalent series resistance (ESR) of the solid electrolytic capacitor must be sufficiently reduced. Therefore, conductive polymers are used as the electrolyte of solid electrolytic capacitors in the industry, so that the equivalent series resistance component of solid electrolytic capacitors is small and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L79/04C08L65/00C08L79/02C08G73/06C08G61/12C08G73/02H01G9/025C25B3/00
Inventor 张易宁陈远强
Owner 福建国光新业科技股份有限公司
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