Compositions and methods are provided for reducing the permeability of subterranean zones. More particularly, water-soluble polymeric compositions which form cross-linked gels in the zones. In general, the composition comprises (a) at least one water-
soluble polymer; (b) at least one organic gelling agent capable of cross-linking the water-
soluble polymer; and (c) at least one water-soluble
formate. More preferably, the water-
soluble polymer is a
copolymer of (i) at least one non-acidic ethylenically unsaturated polar
monomer, and (ii) at least one copolymerisable ethylenically unsaturated ester. The gelling agent is preferably selected from the group consisting of a polyalkyleneimine, polyfunctional
aliphatic amine, an aralkylamine, and a heteroaralkylamine. The preferred water-soluble
formate is selected from the group consisting of
ammonium formate,
lithium formate,
sodium formate,
potassium formate,
rubidium formate, cesium formate, and francium formate. Water is used to make an aqueous composition prior to use in a subterranean formation. The methods of this invention for reducing the permeability of a subterranean zone are comprised of the steps of introducing an aqueous composition according to the invention into a subterranean zone, and then allowing the aqueous composition to form a cross-linked gel in the zone. Preferably, the method includes the step of subsequently producing hydrocarbons from the subterranean formation.