The invention relates to a manufacturing method of an
electrode foil for
solid-state aluminum electrolytic capacitors, which comprises a
corrosion part and a formation part. The
corrosion part comprises the following steps: pre-treating an electronic plain foil in a
hydrochloric acid solution; carrying out hole-forming power-on
corrosion on the foil in a
mixed solution of
hydrochloric acid and
sulfuric acid; carrying out reaming power-on corrosion on the foil, and cleaning and soaking the foil; and washing the foil with running water and carrying out annealing to obtain an etched foil. The formation part comprises the following steps: boiling the etched foil for
solid-state aluminum electrolytic capacitors in water; carrying out first-stage electrochemical
anodic oxidation and first annealing heat treatment; carrying out second-stage electrochemical
anodic oxidation, third-stage electrochemical
anodic oxidation and second annealing heat treatment; carrying out fourth-stage electrochemical anodic oxidation and third annealing heat treatment; soaking the etched foil in
phosphoric acid, soaking the etched foil in
ammonium dihydrogen
phosphate, and cleaning and
drying the etched foil;and obtaining an
electrode foil for
solid-state aluminum electrolytic capacitors. The disturbance of tip current can be reduced, the generation of invalid small holes in the corrosion process can be reduced, and the capacity extraction rate of the solid foil can be increased. Moreover, the quality of the
oxide film can be improved, the stability can be maintained, and the high-temperature stability of solid-state capacitors can be improved.