A kind of manufacturing method of low voltage formed foil for solid aluminum electrolytic capacitor

A technology for aluminum electrolytic capacitors and manufacturing methods, which is applied in the manufacture of electrolytic capacitors, solid electrolytic capacitors, electrolytic capacitors, etc., can solve the problems of unsatisfactory solid aluminum electrolytic capacitors, low capacitor capacity extraction rate, and large oxide film gap, etc., to achieve improvement Capacitance extraction rate, voltage distribution can be uniform, and the effect of dense oxide film

Active Publication Date: 2022-05-17
NANTONG HAIXING ELECTRONICS +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The low-voltage formed foil prepared by this scheme is used to prepare aluminum electrolytic capacitors. Although the leakage current of the capacitor can be reduced to a certain extent, since there will be a hydration film on the surface of the formed aluminum foil, the organic polymer after the solid aluminum electrolytic capacitor is made Difficult access will lead to a low capacity extraction rate of the capacitor, and the oxide film formed by chemical formation has a large gap, and the leakage current is still relatively large, which cannot meet the requirements of solid aluminum electrolytic capacitors

Method used

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  • A kind of manufacturing method of low voltage formed foil for solid aluminum electrolytic capacitor

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Experimental program
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Effect test

Embodiment 1

[0029] a) The corroded foil was placed in a 10 wt% ammonium adipate solution at a temperature of 90 °C and a current density of 200 mA / cm 2 , Under the condition of a voltage of 5 V, anodized for 10 min to obtain a primary formed foil;

[0030] b) Put the primary formed foil in a 10 wt% ammonium adipate solution at a temperature of 90°C and a current density of 200mA / cm 2 1. Under the condition of a voltage of 10 V, anodized for 10 minutes to obtain a secondary formed foil;

[0031] c) Place the secondary formed foil in a 10 wt% ammonium adipate solution at a temperature of 90°C and a current density of 200mA / cm 2 , Under the condition of a voltage of 15 V, anodized for 10 min to obtain a tertiary formed foil;

[0032] d) Place the tertiary formed foil in a 10 wt% ammonium adipate solution at a temperature of 90°C and a current density of 200mA / cm 2 , Under the condition of a voltage of 20 V, anodized for 10 minutes to obtain a four-stage formed foil;

[0033] e) Place the...

Embodiment 2

[0041] a) The corroded foil was placed in a 15 wt% ammonium adipate solution at a temperature of 85 °C and a current density of 150 mA / cm 2 1. Under the condition of a voltage of 10 V, anodized for 12 minutes to obtain a primary formed foil;

[0042] b) Put the primary formed foil in a 15 wt% ammonium adipate solution at a temperature of 85°C and a current density of 150mA / cm 2 , Under the condition of a voltage of 20 V, anodized for 12 minutes to obtain a secondary formed foil;

[0043] c) Place the secondary formed foil in a 15 wt% ammonium adipate solution at a temperature of 85°C and a current density of 150mA / cm 2 , Under the condition of a voltage of 30 V, anodized for 12 minutes to obtain a tertiary formed foil;

[0044] d) Place the tertiary formed foil in a 15 wt% ammonium adipate solution at a temperature of 85°C and a current density of 150mA / cm 2 , Under the condition of voltage 40 V, anodized for 10 min to obtain four-stage formed foil;

[0045] e) Place the q...

Embodiment 3

[0053] a) The corroded foil was placed in a 20 wt% ammonium adipate solution at a temperature of 80 °C and a current density of 100 mA / cm 2 1. Under the condition of a voltage of 20 V, anodized for 15 minutes to obtain a primary formed foil;

[0054] b) Put the primary formed foil in a 20 wt% ammonium adipate solution at a temperature of 80°C and a current density of 100mA / cm 2 1. Under the condition of voltage of 40 V, anodized for 15 minutes to obtain secondary formed foil;

[0055] c) Place the secondary formed foil in a 20 wt% ammonium adipate solution at a temperature of 80°C and a current density of 100mA / cm 2 1. Under the condition of voltage 60V, anodize for 15 minutes to obtain three-stage formed foil;

[0056] d) Place the tertiary formed foil in a 15 wt% ammonium adipate solution at a temperature of 80°C and a current density of 100mA / cm 2 , Under the condition of a voltage of 80 V, anodized for 15 minutes to obtain a four-stage formed foil;

[0057] e) Place th...

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Abstract

The invention discloses a method for manufacturing low-voltage forming foil for solid aluminum electrolytic capacitors, which mainly includes five stages of forming treatment, primary water washing, intermediate treatment, primary heat treatment, primary repair forming, secondary water washing, hydration resistance treatment, secondary heat treatment, and secondary In the process of repairing chemical formation and drying, the intermediate treatment step is to put the aluminum foil that has been washed once into 0.5-5 wt% ammonia solution, and immerse it at 30-50°C for 0.5-3 min; the temperature of the first heat treatment is 400 ~450℃, processing time 4~6 min. The intermediate treatment process can eliminate the hydration film on the surface of the foil, so that the organic polymer can enter the capacitor smoothly, thereby improving the capacity extraction rate of the device; and the hydration film has a larger gap than the crystalline oxide film, which will lead to a large leakage current of the aluminum electrolytic capacitor , After eliminating the hydration film through the intermediate treatment step, this problem can be solved well, and then the leakage current of the formed foil can be effectively reduced.

Description

technical field [0001] The invention belongs to the field of electronic material processing, and in particular relates to a method for manufacturing a low-voltage forming foil for a solid aluminum electrolytic capacitor. Background technique [0002] Formed foil is the product of special high-purity aluminum foil after electrochemical or chemical corrosion to expand the surface area, and then forms an oxide film (aluminum oxide) on the surface through electrochemical formation. As the core material in aluminum electrolytic capacitors, anodized foil plays a decisive role in various characteristics of the capacitor. The existing low-voltage anode foil formation process is generally three-stage formation, phosphoric acid treatment, four-stage formation, high-temperature heat treatment, five-stage formation, and finally ammonium dihydrogen phosphate solution in boric acid and borax solution or adipic acid and its brine solution. Medium dipping treatment, the low-voltage electro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D11/12C25D11/10C25D11/18H01G9/00H01G9/15
CPCC25D11/12C25D11/10C25D11/18H01G9/0029H01G9/15
Inventor 孙新明吴春春金学军何桂丽王贵州龚煜宋双喜肖飞
Owner NANTONG HAIXING ELECTRONICS
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