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Method and device for preparing liquefied methane by using synthesis ammonia tail gas

A technology of liquefied methane and liquefaction equipment, which is applied in the field of recovery and utilization of tail gas from synthetic ammonia, which can solve the problems of greenhouse effect caused by energy carbon dioxide emissions, exhaust waste of synthetic ammonia tail gas, etc.

Active Publication Date: 2011-07-20
北京长征天民高科技有限公司
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Problems solved by technology

[0004] The technical problem to be solved by the present invention is to propose a method and device for producing liquefied methane by using synthetic ammonia tail gas, so as to solve the defects of prior art synthetic ammonia tail gas waste of energy and carbon dioxide emission in the production of synthetic ammonia to produce greenhouse effect

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  • Method and device for preparing liquefied methane by using synthesis ammonia tail gas
  • Method and device for preparing liquefied methane by using synthesis ammonia tail gas
  • Method and device for preparing liquefied methane by using synthesis ammonia tail gas

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Embodiment Construction

[0052] figure 1 It is a schematic diagram of a system for producing liquefied methane and liquid argon by utilizing synthetic ammonia tail gas of the present invention, as figure 1As shown, the device mainly includes: a methanation reactor 1, which is used to input the tail gas of synthetic ammonia after removal of harmful gases such as ammonia and hydrogen sulfide and pressurized treatment, and the carbon dioxide gas discharged from the production of synthetic ammonia into the methanation reactor 1 Carry out a methanation reaction to react carbon dioxide and hydrogen to produce methane and water; a gas purification device 2, connected to the methanation reactor 1, removes water and carbon dioxide in the gas after the methanation reaction through the gas purification device 2 The methane liquefaction device 3 is connected with the gas purification device 2, and the gas purified by the gas purification device 2 is cooled and liquefied by the methane liquefaction device 3 to pro...

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Abstract

The invention discloses a method and a device for preparing liquefied methane by using synthesis ammonia tail gas. The method comprises the following steps of: 1, removing the synthesis ammonia tail gas and harmful gas which is exhausted during the production of synthesis ammonia in carbon dioxide gas, pressurizing the synthesis ammonia tail gas and / or the carbon dioxide gas to ensure that the pressure of the two kinds of gas is consistent, and mixing; 2, introducing the mixed gas into a methanation reaction furnace for reaction to ensure that carbon dioxide is reacted with hydrogen to produce methane and water; 3, introducing the reacted gas into a gas purifying device to remove the water and the carbon dioxide in the gas; and 4, introducing the purified gas into a methane liquefaction device, liquefying methane gas by cooling and rectification processes, separating the liquefied methane out of the methane liquefaction device, storing and packaging. In addition, the gas separated out of the methane liquefaction device can be introduced into an argon liquefaction device to prepare liquid argon. By the method, energy in the emptied tail gas is recycled, and the exhaust amount of greenhouse gas is reduced.

Description

technical field [0001] The invention relates to the field of recovery and comprehensive utilization of chemical tail gas, in particular to a method for recovery and utilization of synthetic ammonia tail gas and an utilized device. Background technique [0002] The tail gas emitted by the synthetic ammonia plant contains methane, nitrogen, hydrogen, argon and ammonia, etc. At the same time, carbon dioxide is also emitted during the production of synthetic ammonia. However, there is no good method to deal with the tail gas of synthetic ammonia in China. At present, the tail gas of synthetic ammonia in nitrogen fertilizer plants is burned or directly vented. This method not only wastes energy, pollutes the environment, but also reduces the economic benefits of nitrogen fertilizer plants. The beneficial methane and argon therein cannot be recovered. In addition, the carbon dioxide produced in the production of synthetic ammonia is usually directly vented, which will inevitably ...

Claims

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Application Information

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IPC IPC(8): C07C9/04C07C1/12
Inventor 朱菁朱淼鑫胡浩雷齐德强王占法杨二愿李波
Owner 北京长征天民高科技有限公司
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