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Europium ion-doped sodium gadolinium tetrafluoride luminescent nanorod and preparation method thereof

A technology of nano-rods and rare-earth ions is applied in the field of preparation of rare-earth doped light-emitting materials, and achieves the effect of strong practicability and wide application prospect.

Inactive Publication Date: 2011-12-21
CHANGCHUN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At present, there is no use of sodium dodecyl sulfate assisted hydrothermal method to synthesize NaGdF at home and abroad. 4 :Eu 3+ Report on Luminescent Nanorods

Method used

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  • Europium ion-doped sodium gadolinium tetrafluoride luminescent nanorod and preparation method thereof
  • Europium ion-doped sodium gadolinium tetrafluoride luminescent nanorod and preparation method thereof
  • Europium ion-doped sodium gadolinium tetrafluoride luminescent nanorod and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0019] Embodiment 1: Weigh 430mg Gd 2 o 3 and 22mg Eu 2 o 3 In a beaker, add 5mL of dilute nitric acid (the volume ratio of nitric acid and deionized water is 1:1) to dissolve, add 21mL of deionized water after cooling to form a rare earth ion solution; weigh 1.44g of sodium lauryl sulfate and add it to 9mL of deionized In water, after being completely dissolved, mix the two solutions, and stir with a magnetic stirrer at room temperature for 30 minutes to obtain a mixed solution of rare earth ions and sodium dodecyl sulfate; weigh 1.11g of ammonium fluoride and dissolve it in 5mL of deionized water to obtain fluoride Ammonium fluoride solution: Add the ammonium fluoride solution dropwise to the mixed solution of rare earth ions and sodium lauryl sulfate, continue stirring at room temperature for 30 minutes to obtain a mixed solution, transfer it to a 50mL reaction kettle, and react at 180°C After 24 hours, the reactor was taken out, naturally cooled to room temperature, cen...

Embodiment 2

[0020] Embodiment 2: Weigh 362.5mg Gd 2 o 3 and 70.4mg Eu 2 o 3 In a beaker, add 5mL of dilute nitric acid (the volume ratio of nitric acid and deionized water is 1:1) to dissolve, add 21mL of deionized water after cooling to form a rare earth ion solution; weigh 1.80g of sodium lauryl sulfate and add it to 9mL of deionized In water, after being completely dissolved, mix the two solutions, and stir with a magnetic stirrer at room temperature for 30 minutes to obtain a mixed solution of rare earth ions and sodium dodecyl sulfate; weigh 1.26g of sodium fluoride and dissolve it in 5mL of deionized water to obtain fluoride Sodium fluoride solution: Add sodium fluoride solution dropwise to the mixed solution of rare earth ions and sodium dodecyl sulfate, continue stirring at room temperature for 30 minutes to obtain a mixed solution, transfer it to a 50mL reaction kettle, and react at 180°C After 24 hours, the reactor was taken out, naturally cooled to room temperature, centrifu...

Embodiment 3

[0021] Embodiment 3: take by weighing 442mgY 2 o 3 and 11 mg Eu 2 o 3 In a beaker, add 5mL of dilute nitric acid (the volume ratio of nitric acid and deionized water is 1:1) to dissolve, add 21mL of deionized water after cooling to form a rare earth ion solution; weigh 1.08g of sodium lauryl sulfate and add it to 9mL of deionized After being completely dissolved in water, the two solutions were mixed, and stirred with a magnetic stirrer at room temperature for 30 minutes to obtain a mixed solution of rare earth ions and sodium lauryl sulfate. Weigh 1.26g of sodium fluoride and dissolve it in 5mL of deionized water to obtain a sodium fluoride solution; add the sodium fluoride solution dropwise to the mixed solution of rare earth ions and sodium lauryl sulfate, and continue stirring at room temperature for 30 minutes to obtain a mixed solution. solution, transferred it to a 50mL reaction kettle, reacted at 180°C for 36h, took out the reaction kettle, cooled to room temperatur...

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Abstract

The invention provides a method for preparing rare earth ion europium-doped sodium gadolinium tetrafluoride (NaGdF4:Eu3+) luminescent nanorods and a method thereof, belonging to the technical field of preparation of rare earth doped luminescent materials. The present invention comprises the following steps: (1) mixing compound rare earth ions and sodium lauryl sulfate in proportion, and then adding fluoride to form a mixed solution; (2) carrying out hydrothermal reaction on the mixed solution at a certain temperature and time, Obtain the NaGdF4:Eu3+luminescent nanorods. The method has a simple synthesis process and is easy to produce in batches, and the prepared NaGdF4:Eu3+ nanorods have good red luminescent properties. The invention uses rare earth metal oxides as raw materials and sodium lauryl sulfate as a surfactant, and the whole reaction is carried out in an aqueous solution without any organic solvent, which is economical and environmentally friendly, has strong practicability, and has wide application prospects.

Description

technical field [0001] The invention relates to a rare earth europium ion doped sodium gadolinium tetrafluoride (NaGdF 4 :Eu 3+ ) The method for preparing nanorods belongs to the technical field of preparation of rare earth doped luminescent materials. Background technique [0002] Rare earth-doped luminescent material is an important luminescent material in the family of inorganic luminescent materials. It is widely used in display lighting, lasers, optical fiber amplifiers, anti-counterfeiting technology and bioluminescent marking. NaYF 4 and NaGdF 4 The representative rare earth tetrafluoride is a kind of fluoride host material with low phonon energy, and the degree of rare earth ion excited state quenching is small, and has high thermal and environmental stability. Therefore, nano-luminescent materials based on tetrafluoride research has attracted great attention. [0003] NaGdF 4 :Eu 3+ It is a very important fluoride red luminescent material, and its preparation...

Claims

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Application Information

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IPC IPC(8): C09K11/85B82Y30/00B82Y40/00
Inventor 刘桂霞王进贤董相廷于洪娇于淑晶王晓玲
Owner CHANGCHUN UNIV OF SCI & TECH
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