Special catalyst for hydrosilylation
A hydrosilylation reaction and catalyst technology, which is applied in physical/chemical process catalysts, organic compounds/hydrides/coordination complex catalysts, organic chemistry, etc., can solve the problems of increased side reactions and reduce purification costs, The effect of saving raw materials and lowering reaction temperature
Inactive Publication Date: 2012-01-04
TIANJIN SHENGBIN CHEM
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Problems solved by technology
[0005] The relatively mature catalyst ligand used in the past is chloroplatinic acid-isopropanol. When the addition reaction of trichlorosilane and chloropropionic acid occurs, it needs to be catalyzed above 60 ° C, which requires low boiling point trichloro Hydrogen silicon must be excessive, because the temperature is too high, resulting in an increase in side reactions, so the reaction yield is between 63% and 65%, and the purity is 98%.
Method used
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Experimental program
Comparison scheme
Effect test
Embodiment 1
[0021] A special catalyst for hydrosilylation reaction, the composition and weight are as follows:
[0022] Chloroplatinic acid 2kg
[0023] Divinyltetramethyldisiloxane 1kg.
Embodiment 2
[0025] A special catalyst for hydrosilylation reaction, the composition and weight are as follows:
[0026] Chloroplatinic acid 4kg
[0027] Divinyltetramethyldisiloxane 8kg.
[0028] When using, mix the two evenly.
[0029] The effect obtained after using this catalyst:
[0030] When the addition reaction of trichlorosilane and chloropropionic acid occurs, the reaction temperature is room temperature, the yield of gamma-chloropropyl trichlorosilane is between 65% and 67%, and the purity is 99%.
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The invention relates to a special catalyst for hydrosilylation, which comprises the following components in parts by weight: 1.5-2.5 parts of chloroplatinic acid and 0.8-1.2 parts of divinyl tetramethyl disiloxane. The invention relates to a catalyst which is used in the hydrosilylation of producing Gamma-chloropropyl trichlorosilane. The catalyst is a bran-novel chlorine platinum acid ligand, i.e. the divinyl tetramethyl disiloxane (tetramethyl divinyl disiloxane) which can catalyze the addition reaction at the room temperature, therefore, the energy used in the heating process is saved, the energy consumption is reduced and the equipment requirement is also reduced.
Description
technical field [0001] The invention belongs to the field of catalysts, in particular to a special catalyst for hydrosilylation reaction. Background technique [0002] γ-Chloropropyltrichlorosilane is the most basic monomer in silane coupling agents, and it can be used as the main raw material for deep processing to produce dozens of high-grade silane coupling agents and other products, such as γ-chloropropyl triethoxy Silane, γ-chloropropyltrimethoxysilane, γ-aminopropyltriethoxysilane, dental composite resin, silicone antibacterial finishing agent, optical glass antifogging agent, etc. Silane coupling agent is mainly used in glass fiber reinforced materials and rubber products, which can strengthen the physical functions of composite materials, such as strength, toughness, electrical properties, water resistance, corrosion resistance, etc.; in addition, it is also used as epoxy, nitrile Adhesives such as rubber and tackifiers in sealants such as polyurethane and neoprene,...
Claims
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IPC IPC(8): B01J31/22C07F7/12
Inventor 陈俊钢
Owner TIANJIN SHENGBIN CHEM