High-gloss washing resistant environmental-friendly print paste and preparation method thereof

A high-gloss, wash-resistant technology, used in dyeing, textiles and papermaking, etc., can solve the problems of higher washing fastness and gloss, insufficient color fastness to rubbing, poor coating elasticity, etc., to achieve excellent Color fastness and anti-sticking properties, good washing fastness, good elasticity

Active Publication Date: 2013-04-03
BAILIHE CHEM ZHONGSHAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the production of textile printing glue, it is generally divided into white glue and transparent glue. When white glue is printed on textiles, it will be a white pattern; The manufacturer's printing pattern requires adding different color pigments to print a coating of different color patterns; therefore, the quality of the printing white glue and transparent glue is directly related to the quality of the printing coating, especially the quality of the white glue, because of its film formation The material content is less and the powder is more, so the requirements for washing fastness and gloss are higher; at present, acrylic emulsion is generally used as the main raw material for pigment printing at home and abroad, and its disadvantages are: the rubbing fastness and rubbing fastness are not good enough, and the gloss Poor strength, high temperature sticking back and other shortcomings
Pigment printing with water-based polyurethane emulsion as the main raw material has good firmness and significantly improved gloss, but the coating has poor elasticity and is expensive; this is closely related to the structure, shape and post-crosslinking degree of the adhesive.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0062] Add 41.0 parts of water-based acrylic emulsion and 20.0 parts of modified water-based polyurethane emulsion into the dispersion tank, and then add 0.06 parts of ammonia water, 0.3 parts of antifoaming agent, 1.0 parts of preservative, 7.0 parts of water-based wax emulsion, and 5.0 parts of humectant part, 0.6 part of wetting and leveling agent, and 1.0 part of dispersant. After the addition is complete, stir for 10 minutes until completely uniform; filter with a 200-mesh filter bag. Add 25.0 parts of titanium dioxide to the above mixture, stir and disperse for 30-50 minutes, then add 2.0 parts of thickener, stir and disperse for 20 minutes, fineness ≤ 15um; then grind twice on a three-roller mill to fineness ≤ 10um; Inspection and packaging: Sampling and inspection of pH value to 7.0~8.0; viscosity at 25°C digital viscometer 4 # The rotor has passed the test and can be packed.

Embodiment 2

[0064] Add 26.0 parts of water-based acrylic emulsion and 24.0 parts of modified water-based polyurethane emulsion into the dispersion tank, add 0.15 parts of ammonia water, 0.4 parts of defoamer, 0.9 parts of preservative, 6.0 parts of water-based wax emulsion, and 9.0 parts of humectant in sequence while stirring. part, 0.4 part of wetting and leveling agent, and 0.8 part of dispersant. After the addition is complete, stir for 10 minutes until completely uniform; filter with a 200-mesh filter bag. Add 30.0 parts of titanium dioxide to the above mixture, stir and disperse for 30-50 minutes, then add 3.0 parts of thickener, stir and disperse for 15 minutes, the fineness is ≤15um; then grind 2 times on a three-roller mill until the fineness is ≤ 10um; testing package: sampling test pH value to 7.0 ~ 8.0; viscosity is 25 ℃ digital viscometer 4 # The rotor has passed the test and can be packed.

Embodiment 3

[0066] Add 30.0 parts of water-based acrylic emulsion and 30.0 parts of modified water-based polyurethane emulsion into the dispersion tank, while stirring, add 0.15 parts of ammonia water, 0.4 parts of defoamer, 0.9 parts of preservative, 6.0 parts of water-based wax emulsion, and 9.0 parts of humectant part, 0.8 part of wetting and leveling agent, and 0.6 part of dispersant. After the addition is complete, stir for 10 minutes until completely uniform; filter with a 200-mesh filter bag. Add 20.0 parts of titanium dioxide to the above mixture, stir and disperse for 30-50 minutes, then add 3.0 parts of thickener, stir and disperse for 15 minutes, the fineness is ≤15um; then grind 2 times on a three-roller mill until the fineness is ≤ 10um; testing package: sampling test pH value to 7.0 ~ 8.0; viscosity is 25 ℃ digital viscometer 4 # The rotor has passed the test and can be packed.

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Abstract

The invention discloses high-gloss washing resistant environmental-friendly print paste and a preparation method thereof; the printing paste comprises water-based acrylic emulsion, modified water-based polyurethane emulsion, ammonia, defoaming agent, preservative, water-based wax emulsion, wetting and leveling agent, dispersing agent, toner, moisturizing agent and thickener. The preparation method comprises the steps that: A. stirring and filtration: the water-based acrylic emulsion and the water-based polyurethane emulsion are added into a dispersion cylinder by the formula ratio, and are stirred while being sequentially added with the ammonia, the defoaming agent, the preservative, the water-based wax emulsion, the moisturizing agent, the wetting and leveling agent and the dispersing agent; after the materials are added in, the mixture is stirred for 10min to 20min until being uniform fully; the mixture is filtered by a 200-mesh filter mesh bag; B. dispersion and grinding: the toneris added into the liquid mixture, stirred and dispersed for 30min to 50min; the thickener is added in, stirred and dispersed for 10min to 20min; and then the liquid mixture is ground on a three-roll grinder; and C. detection and packaging: the product is sampled to detect the pH value, the viscosity and the fineness, and the product is packaged after all the indexes are qualified.

Description

technical field [0001] The invention relates to a high-gloss washable and environment-friendly printing glue, and also relates to a preparation method of the printing glue. Background technique [0002] Aiming at the disadvantages of traditional dyeing process, such as complicated, polluting, high cost and long price cycle, pigment printing has emerged at home and abroad. The process of pigment printing is simple, saves energy, has no waste water discharge, complete color spectrum, convenient color matching and imitation, and clear printing outline. The authenticity rate is high, the reproducibility is strong, and the general light fastness is good. my country only began to import acrylic adhesives for pigment printing in the 1960s, and then began research work in this area. In recent years, many new materials can be used in the pigment printing process, especially with the development of synthetic fibers and their blended fabrics, the superiority and importance of pigment ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/52D06P1/673
Inventor 陈万春欧继安杨剑张鲁桂
Owner BAILIHE CHEM ZHONGSHAN
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