Method for preparing single polymer composite material by using two-component composite fiber

A composite fiber fabric and composite fiber technology, which is applied in fiber processing, fabrics, textiles, and papermaking, etc., can solve the problems of not considering material recycling and reuse, complex process equipment and preparation processes, and increase in composite material waste. Meet modern environmental protection requirements, ideal impregnation effect, easy to recycle and reuse

Active Publication Date: 2012-04-04
SHANGHAI GENIUS ADVANCED MATERIAL (GRP) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The key to preparing thermoplastic composites lies in the interface bonding between fibers and resins. However, since the matrix of thermoplastic composites lacks reactive active functional groups, it is difficult to form a good chemical bond with fibers, so the interface problem has always restricted its development; Solving the impregnation of reinforcing fibers with thermoplastic resins has become a key technology for preparing thermoplastic composite materials in various countries; in addition, the extensive use of composite materials has led to an increase in composite material waste, and the recycling and reuse of materials has become the current trend of material design
This method can produce continuous fiber-reinforced thermoplastic resin composite material prepreg tape with better impregnation effect, but since the raw material is a pre-manufactured mixed fiber yarn, it is necessary to melt-spin the thermoplastic resin first, and then combine it with other fibers. Therefore, to achieve the mixing at the monofilament level, the process equipment and preparation process are complicated, and the modern environmental protection requirements of material recovery and reuse are not considered.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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preparation example Construction

[0020] The preparation method of the bicomponent composite fiber of the present invention to manufacture a single polymer composite material comprises the following steps:

[0021] (1) Preparation of bicomponent composite fibers

[0022] The reinforcing phase polymer and the matrix polymer are subjected to two-component composite spinning according to the designed weight ratio. For example, the arrangement of the composite fibers adopts the core-sheath type arrangement, the core material is the reinforcing phase polymer, and the surface material is the matrix polymer. things. Preparation of bicomponent composite fibers.

[0023] Composite spinning process parameters are as follows:

[0024] Spinning speed: 20-1000m / min, preferably 400-800

[0025] Stretch ratio: 2~8, preferably 4~6

[0026] Composite fiber linear density: 1-200tex, preferably 3-50tex

[0027] Weight percentage of reinforcing phase polymer: 20%-85%, preferably 30%-60%.

[0028] (2) Preparation of composit...

Embodiment 1

[0034] Composite spinning of PA66 (1000 parts) and PA6 (1000 parts) adopts a core-sheath arrangement, in which PA66 is the core material (reinforcing phase polymer), and PA6 is the surface layer material (matrix polymer). Component composite fibers. The spinning process parameters are as follows: spinning speed: 600m / min, draw ratio: 5, composite fiber linear density: 4.5tex. Then, the obtained conjugate fiber was made into a unidirectional conjugate fiber stitch-bonded fabric on a stitchbonding machine. Then, 12 layers of the obtained unidirectional composite fiber stitch-woven fabric were laminated in the same direction, and then formed by vacuum bag thermocompression at a molding temperature of 235-245°C to obtain a PA66 continuous fiber-reinforced PA6 composite material.

Embodiment 2

[0036] Composite spinning of PET (1000 parts) and PBT (800 parts) in a core-sheath arrangement, in which PET is the core material (reinforcing phase) and PBT is the surface material (matrix) to prepare the corresponding two-component composite fiber . The spinning process parameters are as follows: spinning speed: 500m / min, draw ratio: 5, composite fiber linear density: 4tex. Then, the obtained conjugate fiber was made into a unidirectional conjugate fiber stitch-bonded fabric on a stitchbonding machine. Then, 14 layers of the obtained unidirectional composite fiber stitch-woven fabric were laminated in the same direction, and formed by vacuum bag thermocompression at a forming temperature of 235-245°C to obtain a PET continuous fiber-reinforced PBT composite material.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The present invention relates to a method for preparing a single polymer composite material by using two-component composite fiber. The method comprises the following steps: (1) adopting a composite spinning technology to prepare two homogeneous polymers into two-component composite fiber, wherein the two homogeneous polymers comprise a matrix polymer and a reinforcement phase polymer, the arrangement of the two-component composite fiber is a parallel type arrangement or a core-sheath type arrangement, when the arrangement of the two-component composite fiber is the core-sheath type arrangement, the core material is the reinforcement phase polymer, and the surface material is the matrix polymer; (2) weaving the two-component composite fiber from the step (1) to form composite fiber fabric; (3) carrying out hot pressing for the composite fiber fabric from the step (2) at the temperature between the melting point of the reinforcement phase polymer and the melting point of the matrix polymer, such that the matrix polymer is molten, and compounded to form the single polymer composite material. Compared to the prior art, the method of the present invention has advantages of simple process, large-scale production, environmental protection and the like.

Description

technical field [0001] The invention belongs to the technical field of preparation of thermoplastic composite materials, and in particular relates to a preparation method for manufacturing single-polymer composite materials from bicomponent composite fibers. Background technique [0002] Due to their excellent mechanical properties such as high tensile strength, flexural strength / modulus, high and low temperature impact strength, etc., and relatively low density and many other advantages, thermoplastic composite materials have been greatly developed at home and abroad in recent years. [0003] The key to preparing thermoplastic composites lies in the interface bonding between fibers and resins. However, since the matrix of thermoplastic composites lacks reactive active functional groups, it is difficult to form a good chemical bond with fibers, so the interface problem has always restricted its development; Solving the impregnation of reinforcing fibers with thermoplastic re...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06N7/00D03D15/00D01D5/34B29C51/00D03D15/292
Inventor 张冠
Owner SHANGHAI GENIUS ADVANCED MATERIAL (GRP) CO LTD
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