Method for synthesizing cyclohexenone from cyclohexene
A technology of cyclohexenone and cyclohexene, which is applied in the field of synthesizing cyclohexenone, can solve the problems of low yield, environmental pollution, high cost, etc., and achieve the effects of low consumption, cost reduction, and increased production capacity
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Embodiment 1
[0018] In a 1 L autoclave, copper acetate and cyclohexene were sequentially added, and the dosage is shown in Table 1.
[0019] substance molecular weight Amount of substance / mol Mass / g Volume / mL Cyclohexene 82 1 82 101 copper acetate 200 0.5×10 -3 0.1 -
[0020] Inflate air to pressurize to 0.2MPa, heat to 120°C, react for 6 hours and then cool. A small amount of the reaction solution was analyzed by gas chromatography, and the gas chromatography analysis showed that the conversion rate was 24.1%, and the selectivity was 83.6%. The remaining reaction liquid was recovered unreacted cyclohexene by atmospheric distillation, and the residual liquid was distilled under reduced pressure (77~79°C, 2.66kPa) to obtain 17.2 g of cyclohexenone.
Embodiment 2
[0022] Use other copper compounds to replace copper acetate as the catalyst, and other conditions are the same as in Example 1 (the amount of catalyst used is 0.5×10 -3 mol, the molar ratio of each component in the composite catalyst is marked in brackets), and the results are shown in Table 2.
[0023] serial number catalyst Conversion rate / % selectivity / % 1 copper trifluoroacetate 19.2 76.8 2 copper sulfate 13.2 65.3 3 Copper oxide 12.0 77.6 4 Copper chloride 19.8 72.2 5 copper bromide 6.5 53.2 6 Copper acetate (90%) - copper oxide (10%) 23.3 82.1 7 Copper acetate (70%) - copper oxide (30%) 20.1 81.0 8 Copper acetate (50%) - copper oxide (50%) 17.8 80.7 9 Copper acetate (30%) - copper oxide (70%) 15.3 79.2 10 Copper acetate (10%) - copper oxide (90%) 14.6 78.2 11 Copper acetate (50%)-copper sulfate (50%) 20.0 80.9 12 Copper oxide (50%) - copper chloride (50%) 18.8 8...
Embodiment 3
[0026] Change the consumption of catalyzer copper acetate, other conditions are with embodiment 1, and the results are shown in Table 3.
[0027] Catalyst dosage / mol% 0.01 0.1 0.2 0.5 1.0 Conversion rate / % 13.6 24.6 18.7 17.2 18.0 selectivity / % 74.2 73.5 74.4 63.4 52.2
[0028] The above results show that the best catalyst dosage is 0.01mol%~0.5mol%, and the increase of catalyst dosage will significantly reduce the selectivity.
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