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Cement grinding aid reinforcing agent and preparation method thereof

A grinding aid and cement technology, applied in the field of cement admixture, can solve the problems of high price, unstable performance of cement grinding aid, high cost of cement grinding aid, etc., and achieve low dosage and enhanced grinding effect Visible, stable performance

Active Publication Date: 2013-09-04
安徽海螺材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the cement grinding aid enhancer reported above is prepared by a simple physical mixing method, the performance of the cement grinding aid enhancer is unstable, and phenomena such as precipitation and deterioration are prone to occur in practical applications; secondly, the above cement grinding aid enhancer The triethanolamine used in the process is a downstream product of the petrochemical industry, and the price is relatively high, which makes the cost of cement grinding aids higher, and at the same time causes the cement grinding aids to be greatly affected by the cement production process
[0004] In recent years, major manufacturers and institutions of higher learning have continuously organized professionals to study synthetic cement grinding aids, with the aim of combining various functional groups into the polymer molecular chain structure, thereby solving the problem of compound cement grinding aid enhancement. There are problems such as unstable performance of the agent

Method used

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  • Cement grinding aid reinforcing agent and preparation method thereof
  • Cement grinding aid reinforcing agent and preparation method thereof
  • Cement grinding aid reinforcing agent and preparation method thereof

Examples

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preparation example Construction

[0030] The invention discloses a preparation method of a cement grinding aid enhancer, comprising the following steps:

[0031] Step a) under the action of a catalyst, the addition reaction of urea and the first formaldehyde in water;

[0032] Step b) performing a condensation reaction on the reaction product of the addition reaction, sodium p-aminobenzenesulfonate and second formaldehyde to obtain a cement grinding aid enhancer.

[0033] In the above-mentioned preparation process, the present invention first utilizes the addition reaction of urea and formaldehyde to prepare methylol urea with a grinding-aiding and strengthening effect having a molecular structure similar to triethanolamine, and then combines methylol urea, formaldehyde, and Sodium p-aminobenzenesulfonate was subjected to polycondensation reaction to prepare a macromolecular substance with grinding aid enhancement effect.

[0034] The step a) specifically includes: step a1) adding urea and water into the reac...

Embodiment 1

[0047] (1) Add 60g of urea and 60g of water into the reaction flask, stir until the urea is dissolved, then add 10g of sodium hydroxide; raise the temperature of the system to 50°C, add 100g of formaldehyde solution dropwise within 1h, and continue the reaction for 1h;

[0048] (2) Add 50g of sodium p-aminobenzenesulfonate to the reaction flask, continue to stir and keep the above temperature constant, start to add the remaining 65g of formaldehyde solution dropwise, and keep adding dropwise within 2 hours;

[0049] (3) The temperature of the reaction system was raised to 75° C., and the reaction was maintained for 3 hours; then the temperature was lowered and the material was discharged to obtain a light red liquid, that is, a cement grinding aid enhancer.

Embodiment 2

[0051] (1) Add 70g of urea and 70g of water into the reaction flask, stir until the urea is dissolved, then add 15g of potassium hydroxide; raise the temperature of the system to 55°C, add 182g of formaldehyde solution dropwise within 2h, and continue the reaction for 1h;

[0052] (2) Add 50g of sodium p-aminobenzenesulfonate to the reaction flask, continue to stir and keep the above temperature constant, start to add the remaining 78g of formaldehyde solution dropwise, and keep adding dropwise within 2.5 hours;

[0053] (3) The temperature of the reaction system was raised to 80° C., and the reaction was maintained for 4 hours; then the temperature was lowered and the material was discharged to obtain a light red liquid, that is, a cement grinding aid enhancer.

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Abstract

The invention discloses a preparation method of a cement grinding aid reinforcing agent, which comprises the following steps: adding first formaldehyde to urea in water in the presence of a catalyst; condensing the product of the addition reaction, sodium sulfanilate and a second formaldehyde; and obtaining the cement grinding aid reinforcing agent. Designed on the basis of a molecular structure, the preparation method provided by the invention bonds reinforcing and grinding aiding active functional groups into a molecular chain and synthesizes the homogenous material which is insusceptible to temperature, pH value and the like and has stable performance by chemical reactions. Experiment results indicate the method does not need a triethanolamine raw material and that the prepared cement grinding aid reinforcing agent is doped in small amount and has obvious grinding aiding function and stable performance.

Description

technical field [0001] The invention relates to the technical field of cement admixtures, in particular to a cement grinding aid enhancer and a preparation method thereof. Background technique [0002] Energy saving and consumption reduction and improvement of cement quality are long-term and important tasks of my country's cement industry. Among them, the crushing and powder links in the cement production process are the main factors affecting cement quality and energy consumption in the whole production process. For example, in the cement grinding process In the process, when the fineness of cement increases, the fine particles of cement tend to aggregate, which leads to a sharp decline in the grinding efficiency of cement. Cement grinding aid enhancer is an additive that has grinding aid without damaging the performance of cement. The promotion and selection of suitable cement grinding aid enhancer can greatly improve the efficiency of cement powder. Further, the cement g...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G12/12C08G12/08C04B24/22C04B103/52
Inventor 宋南京赵洪义朱化雨孟凡军徐明双
Owner 安徽海螺材料科技股份有限公司
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