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Preparation method of cuprous oxide hollow nanometer cubes

A hollow nanometer, cuprous oxide technology, applied in copper oxide/copper hydroxide, nanotechnology and other directions, can solve the problems of affecting the product, inconvenient cleaning of the product, affecting the purity of the final product, etc., and achieve a simple reaction system and simple production equipment. Effect

Inactive Publication Date: 2012-07-11
HUAIYIN TEACHERS COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the addition of surfactants also has some negative issues
One is that the concentration of surfactants often directly affects the final shape of the product, and the concentration of surfactants needs to be precisely regulated in the preparation process, which brings a lot of trouble to industrial production; the other is that surfactants are easily adsorbed on the product. The surface of the product brings inconvenience to the cleaning of the product, thus affecting the purity of the final product

Method used

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  • Preparation method of cuprous oxide hollow nanometer cubes
  • Preparation method of cuprous oxide hollow nanometer cubes
  • Preparation method of cuprous oxide hollow nanometer cubes

Examples

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Comparison scheme
Effect test

Embodiment 1

[0019] Embodiment 1: Prepare cuprous oxide hollow nanocubes according to the following steps

[0020] (1) Add copper acetylacetonate to the polyol, and raise the temperature to the reaction temperature at a certain heating rate under the stirring condition of 1000 rpm, wherein the weight ratio of the polyol to copper acetylacetonate is 1:0.0005; wherein, The polyol is ethylene glycol; wherein, the heating rate is 2°C / sec; wherein, the reaction temperature is 180°C;

[0021] (2) After reacting for 6 hours, the above solution was left to cool to room temperature, and the product was washed several times with ethanol and deionized water to obtain a light yellow precipitate, which was dried at 70°C to obtain a cuprous oxide hollow nanometer cube.

Embodiment 2

[0022] Embodiment 2: Prepare cuprous oxide hollow nanocubes according to the following steps

[0023] (1) Add copper acetylacetonate to the polyol, and raise the temperature to the reaction temperature at a certain heating rate under the stirring condition of 1100 rpm, wherein the weight ratio of the polyol to copper acetylacetonate is 1:0.001; wherein, The polyol is sorbitol; wherein, the heating rate is 3°C / sec; wherein, the reaction temperature is 200°C;

[0024] (2) After reacting for 5 hours, the above solution was left to cool to room temperature, and the product was washed several times with ethanol and deionized water to obtain a light yellow precipitate, which was dried at 70°C to obtain hollow cuprous oxide nanoparticles cube.

Embodiment 3

[0025] Embodiment 3: Prepare cuprous oxide hollow nanocubes according to the following steps

[0026] (1) Add copper acetylacetonate to the polyol, and raise the temperature to the reaction temperature at a certain heating rate under the stirring condition of 1250 rpm, wherein the weight ratio of the polyol to copper acetylacetonate is 1:0.01; wherein, Polyhydric alcohol is glycerol; Wherein, described heating rate is 4 ℃ degree / second; Wherein, described reaction temperature is 220 ℃ degree;

[0027] (2) After reacting for 3 hours, the above solution was left to cool to room temperature, and the product was washed several times with ethanol and deionized water to obtain a light yellow precipitate, which was dried at 70°C to obtain a cuprous oxide hollow nanometer cube.

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Abstract

The invention discloses a preparation method of cuprous oxide hollow nanometer cubes. According to the preparation method, a chemical reducing method is adopted, polyhydric alcohol is used as solvents and reducing agents, cuprous diacetone is reduced at high temperature, the cuprous oxide hollow nanometer cubes are obtained, the edge length of the obtained cuprous oxide hollow nanometer cubes is about 150nm, and the wall thickness is about 20nm. The preparation method has the advantages that the process is simple, any surfactants do not need to be added, the operation is simple and convenient, the cost is low, and the preparation method is suitable for mass production.

Description

technical field [0001] The invention relates to a method for preparing cuprous oxide, in particular to a method for preparing cuprous oxide hollow nanocubes. Background technique [0002] As a functional material with a novel structure, the hollow material has the characteristics of low density, high surface activity, and strong surface permeability compared with bulk materials. Show great potential application value. In addition, due to its special core-shell structure, the hollow part can often accommodate a large number of guest molecules: on the one hand, it can be used as a microreactor for the synthesis of other materials; Controlled release. [0003] Cuprous oxide (Cu 2 O) is a very important p-type semiconducting metal oxide with a band gap of 2.0 eV. It has a wide range of applications in the fields of photocatalysis, new solar cells, magnetic storage devices, biosensing and coatings. Currently, on Cu 2 The research on O nanomaterials mainly focuses on the sy...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G3/02B82Y40/00
Inventor 程志鹏仲慧徐继明褚效中张维光李荣清殷竟洲
Owner HUAIYIN TEACHERS COLLEGE
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