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Magnesium-ferrum-aluminum-calcium three-layer composite brick and production method thereof

A magnesia-iron-aluminum layer composite technology, applied in the field of refractory materials, can solve problems such as increased heat dissipation of the kiln shell, increased heat consumption of clinker, and brick drop, to prolong the service life of equipment, save energy consumption, and achieve good refractory insulation The effect of thermal effects

Inactive Publication Date: 2012-08-01
SUZHOU LOW CARBON ENERGY CONSERVATION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the existing refractory bricks and heat insulation bricks are made of a single material. When using them, bricks with various properties need to be used together. If they are used on relatively fixed equipment, such as tunnel kilns and downdraft kilns, they can meet the requirements. , but on some relatively moving equipment, such as a rotary kiln, it is difficult to meet the requirements when used together
Some manufacturers and research units have conducted research and research on this, and have introduced some composite bricks that combine heavy materials and light materials. However, due to the low structural strength of the light parts, they cannot meet the requirements for use, and the The light part is easy to react due to material problems, which affects product performance and use effect, so it has not been widely promoted, and heavy bricks are still the main ones
[0003] Taking the 10,000t / d rotary kiln of Conch Group as an example, spinel bricks are used in the front transition zone, and magnesia-chrome bricks are used in the firing zone. Due to the large thermal conductivity of spinel bricks in the front transition zone and magnesia-chrome bricks in the firing zone (≥ 2.7W / m·K), so that the temperature of the outer wall of the kiln shell is relatively high (about 380°C, and it can reach 420°C at high temperature), which will increase the heat dissipation of the kiln shell on the one hand, thereby increasing the heat consumption of clinker. It will cause an increase in the unit cost of clinker; on the other hand, it is very easy to cause the cylinder to expand due to heat, resulting in an increase in the temperature of the supporting wheel in the middle of the kiln, especially in the later period of use or in summer, which will bring great hidden dangers to the normal operation of the equipment.
The overheating of the cylinder increases the damage probability of mechanical equipment and accelerates the deformation of the cylinder, and the deformation of the cylinder accelerates the mechanical damage of the inner lining. The result is brick falling and kiln shutdown, which affects the operation rate of the cement rotary kiln

Method used

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  • Magnesium-ferrum-aluminum-calcium three-layer composite brick and production method thereof
  • Magnesium-ferrum-aluminum-calcium three-layer composite brick and production method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0022] Such as figure 1 As shown, the magnesium-iron-aluminum-calcium three-layer composite brick of this embodiment includes a heavy working layer 1, a light heat insulating layer 3, and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3.

[0023] in:

[0024] The particle gradation and mass percentage of the raw materials used in the heavy working layer 1 are: fused magnesia with a particle size of 1-3mm: 21%; calcium hexaaluminate with a particle size of 1-3mm: 10%; Iron-aluminum spinel with a diameter of 1-3mm: 4%; fused magnesia with a particle size of less than 1mm and greater than 325 mesh: 35%; iron-aluminum spinel powder with a particle size not greater than 325 mesh: 3%; particle size not greater than 325 mesh fused magnesium powder: 27%. The binding agent used when preparing materials is pulp waste liquid, and its weight is 5% of the weight of the heavy working layer.

[0025] The particle size distribution and mass perce...

Embodiment 2

[0034] Such as figure 1 As shown, the magnesium-iron-aluminum-calcium three-layer composite brick of this embodiment includes a heavy working layer 1, a light heat insulating layer 3, and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3.

[0035] in:

[0036] The particle gradation and mass percentage of the raw materials used in the heavy working layer 1 are: sintered magnesia with a particle size of 1-3mm: 35%; iron-aluminum spinel with a particle size of 1-3mm: 10%; Iron-aluminum spinel with a diameter of less than 1mm and greater than 325 mesh: 6%; sintered magnesia with a particle diameter of less than 1mm and greater than 325 mesh: 19%; sintered magnesium powder with a particle diameter not greater than 325 mesh: 13%; particle diameter not greater than 325 mesh Calcium hexaaluminate: 15%; particle size not greater than 325 mesh α-Al 2 o 3 Powder: 2%. The binding agent used when preparing materials is pulp waste liquid, and...

Embodiment 3

[0046] Such as figure 1 As shown, the magnesium-iron-aluminum-calcium three-layer composite brick of this embodiment includes a heavy working layer 1, a light heat insulating layer 3, and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3.

[0047] in:

[0048] The particle gradation and mass percentage of the raw materials used in the heavy working layer 1 are: sintered magnesia with a particle size of 1-3mm: 33%; iron-aluminum spinel with a particle size of 1-3mm: 7%; Sintered magnesia with a diameter of less than 1mm and greater than 325 mesh: 5%; calcium hexaaluminate with a particle diameter of less than 1mm and greater than 325 mesh: 30%; sintered magnesium powder with a particle diameter not greater than 325 mesh: 25%. The binding agent used when preparing materials is pulp waste liquid, and its weight is 3% of the weight of the heavy working layer.

[0049] The gradation and mass percentage of raw material particles used in t...

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Abstract

The invention provides a magnesium-ferrum-aluminum-calcium three-layer composite brick high in abrasion resistance, refractoriness, structural strength and heat insulating performance, and a production method of the magnesium-ferrum-aluminum-calcium three-layer composite brick, which can realize a refractory and heat insulation integrated function of the composite brick and improve energy conservation effect of a rotary kiln. The magnesium-ferrum-aluminum-calcium three-layer composite brick comprises a heavy operating layer, a light heat insulating layer and a transitional layer between the heavy operating layer and the light heat insulating layer, wherein the heavy operating layer is made of dolomite materials, the light heat insulating layer is made of electric-smelted hollow spheres, and the transitional layer is made of spinel, magnesia-alumina-chrome, magnesia-alumina-titanium or magnesium spinel zirconium materials. The transitional layer is introduced into the magnesium-ferrum-aluminum-calcium three-layer composite brick, reaction between the heavy operating layer and the light heat insulating layer can be avoided, excellent refractory and heat insulation effects can be achieved without shortening the service life of materials of the product, and accordingly energy consumption, material consumption and rotary kiln refractory usage can be reduced, and the service life of equipment can be effectively prolonged.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a magnesium-iron-aluminum-calcium three-layer composite brick and a preparation method thereof. Background technique [0002] With the continuous emergence of new technologies for cement production, the main equipment of cement production is developing in the direction of large-scale, increasing production, improving quality, saving energy, reducing consumption, and reducing costs have become the key to increasing efficiency in production management. Most of the existing refractory bricks and heat insulation bricks are made of a single material. When using them, bricks with various properties need to be used together. If they are used on relatively fixed equipment, such as tunnel kilns and downdraft kilns, they can meet the requirements. , but on some relatively moving equipment, such as a rotary kiln, it is difficult to meet the requirements when used to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66
Inventor 王家邦
Owner SUZHOU LOW CARBON ENERGY CONSERVATION TECH
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