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Electrochromatic epoxy resin polymer and preparation method thereof

An epoxy resin and electrochromic technology, applied in the direction of color-changing fluorescent materials, chemical instruments and methods, etc., can solve the problems of easy peeling off of the film and difficulty in measuring the electrochromic performance, and achieve good bonding performance, good mechanical properties, Good effect of acid and alkali resistance and heat resistance

Inactive Publication Date: 2012-09-19
HEILONGJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0011] The purpose of the present invention is to solve the problem that the existing polymer film is easy to fall off in an organic solution, and it is difficult to measure its electrochromic performance, and provides a kind of epoxy resin polymer with electrochromic performance and its preparation method

Method used

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  • Electrochromatic epoxy resin polymer and preparation method thereof
  • Electrochromatic epoxy resin polymer and preparation method thereof
  • Electrochromatic epoxy resin polymer and preparation method thereof

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specific Embodiment approach 1

[0036] Embodiment 1: The chemical structural formula of a kind of epoxy resin polymer with electrochromic performance in this embodiment is as follows:

[0037]

[0038] Among them, n is 10~20, R is

[0039]

[0040]

[0041] The epoxy resin polymer of this embodiment has good bonding performance, a shear strength of about 30MPa, good acid and alkali resistance and heat resistance, and the highest service temperature can reach 120°C. It has good mechanical properties, and at the same time has aniline Electrochromic properties. The self-luminous response speed of the epoxy resin polymer in this embodiment is 1000 times that of liquid crystals, and has potential value in the development of molecular designers. The epoxy resin polymer synthesized in this embodiment has an epoxy value of 0.12-0.30 equivalent / 100g, and has adhesive and coating properties.

specific Embodiment approach 2

[0042] Specific embodiment two: a kind of preparation method of epoxy resin polymer with electrochromic performance of the present embodiment is carried out according to the following steps:

[0043] 1. Synthesis of monomers

[0044] a. Mix diaminotriphenylamine derivatives and p-hydroxybenzaldehyde in a molar ratio of 1:2~3 to obtain a mixture; b. Mix the mixture obtained in step a and the solvent in a mass-volume ratio of 0.8-2.1g : Mix 100mL evenly to obtain a mixture, then raise the temperature to 120°C~140°C under nitrogen protection, stir at a speed of 20~50rpm for 12h, when the solvent in the mixture evaporates until the volume of the mixture is the original volume At 1 / 4, stop stirring and collect the remaining 1 / 4 volume of liquid; c. Put the remaining 1 / 4 volume of liquid collected in step b into distilled water, let it stand for 6~12h, and then put it under the condition of vacuum degree of 0.09MPa Suction filtration under low temperature to collect the solid phase...

specific Embodiment approach 3

[0048] Specific embodiment 3: The difference between this embodiment and specific embodiment 2 is that the diaminotriphenylamine derivative described in step 1 is 4,4′-diamino-4″-N-carbazolyltriphenylamine, N, N-bis(4-aminophenyl)-N′,N′-diphenyl-1,4-phenylenediamine, N′-(4-aminophenyl)-N′-(4-ethoxy) Phenyl-1,4-phenylenediamine, N,N′-bis(β-naphthyl)-N,N′-bis(4-aniline)-p-phenylenediamine or N′-(4-aminophenyl) -N'-phenyl-1,4-phenylenediamine, N',N'-diphenyl-N,N'-bis(4-aniline)-p-phenylenediamine, N',N'-diphenyl -N,N'-bis(4-phenylamine)biphenylenediamine or N,N'-bis(α-naphthyl)-N,N'-bis(4-phenylamine)biphenylenediamine.Others are the same as step 2 same.

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Abstract

The invention relates to an epoxy resin polymer and a preparation method thereof, particularly relates to an electrochromatic epoxy resin polymer and a preparation method thereof, and aims to solve the problem that existing polymer films are prone to shed in organic solution and difficult in detection of electrochromatic performance. The chemical formula of the epoxy resin polymer is shown as follows. The method includes: adding hydroxyl-contained monomer material A into epichlorohydrin, stirring at 60-80 DEG C while dripping aqueous sodium hydroxide solution into epichlorohydrin solution of the material A, and reacting for two to eight hours to obtain the electrochromatic epoxy resin polymer. The epoxy resin polymer is highly adhesive, highly resistant to acid, alkali and heat and high in mechanical performance, and has the electrochromatic performance of triphenylamine, the shear strength of the epoxy resin polymer is about 30MPa, and the maximum service temperature of the epoxy resin polymer is up to 120 DEG C. The electrochromatic epoxy resin polymer and the preparation method thereof are applicable to the field of electrochromism.

Description

technical field [0001] The invention relates to an epoxy resin polymer and a preparation method thereof. Background technique [0002] 1. Epoxy resin adhesive [0003] As an emerging chemical material, epoxy adhesive has good chemical stability, small curing shrinkage, and excellent bonding performance, and its role in various fields is increasing. [0004] Epoxy glue has the following characteristics, (1) a wide range of bonding, which solves the problem of bonding with large performance differences (such as steel and concrete) and large size differences (such as extremely thin and extremely thick), (2) the connecting parts are in the joint Under reasonable conditions, the force on the connection part is uniform. (3) Compared with traditional adhesives, the connection process is light in weight, which is very important for aircraft and aerospace. Of course, there are also shortcomings, such as impact strength, peel strength is not high, and the quality of bonding is affec...

Claims

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Application Information

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IPC IPC(8): C08G18/58C08G59/06C09K9/02
Inventor 牛海军孙岩郝丽苹张坤张春雨温海林
Owner HEILONGJIANG UNIV
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