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Polycarbonate/ABS (acrylonitrile, butadiene and styrene) resin plastic alloy

A technology of polycarbonate resin and ABS resin, which is applied in the field of polycarbonate/ABS resin plastic alloy, can solve the problems of low impact strength of PC/ABS alloy and cannot meet the application requirements of high impact strength, etc., and achieve good mechanical properties, excellent Effects of mechanical properties, processability, and ultra-high impact strength

Active Publication Date: 2012-10-24
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to overcome the low impact strength of the PC / ABS alloy prepared by the existing production method and cannot meet the shortcomings of some high impact strength application requirements (such as automobile bumpers, instrument panels, etc.). It is found that the technical scheme of plastic alloy composed of polycarbonate resin, bulk polymerization ABS resin, compatibilizer SMA resin and additives can better solve this problem

Method used

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  • Polycarbonate/ABS (acrylonitrile, butadiene and styrene) resin plastic alloy
  • Polycarbonate/ABS (acrylonitrile, butadiene and styrene) resin plastic alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Weigh 2.475 kg of bisphenol A polycarbonate (PC-1) produced by Sabic Company with an MFR (300°C, 1.2kg) of 10.5g / 10min, an MFR (220°C, 10kg) of 16g / 10min, and an average 2.175 kilograms of bulk polymerization ABS resin (ABS-1) with a rubber particle diameter of 0.8 microns, MFR (230°C, 2.16kg) is 7g / 10min, 0.300 kilograms of SMA resin with maleic anhydride weight percent content of 18%. 25 grams of oxygen agent 1010, 25 grams of white oil (12#), put into a container and mix evenly with a stirrer, then add it to the feeder of the twin-screw extruder for subsequent use. Twin-screw extruder (screw diameter 27mm, length / diameter ratio 36, Germany Leistritz company) barrel temperature is set in ten sections from the feed inlet to the extrusion outlet at 200°C, 220°C, 230°C, 240°C, 245°C , 250°C, 250°C, 250°C, 250°C, 245°C, when the temperature of each section reaches the set value, turn on the screw of the main engine and the screw of the feeder at 150 rpm and 60 rpm Extrud...

Embodiment 2

[0051] Weigh 2.725 kg of bisphenol A polycarbonate (PC-2) produced by Sabic Company with an MFR (300°C, 1.2kg) of 7.0g / 10min, an MFR (220°C, 10kg) of 16g / 10min, and an average 1.975 kilograms of bulk polymerization ABS resin (ABS-1) with a rubber particle size of 0.8 micron, MFR (230°C, 2.16kg) is 7g / 10min, 0.250 kilograms of SMA resin with maleic anhydride weight percent content of 18%. Oxygen agent 1010 25 grams, white oil (12#) 25 grams, put into a container and mix homogeneously with agitator, then add in the twin-screw extruder feeder and prepare polycarbonate / ABS alloy by the same condition of embodiment 1 , Injection molded strips and test performance, the results are shown in Table 2.

Embodiment 3

[0053]Weigh 2.475 kg of bisphenol A polycarbonate (PC-1) produced by Sabic Company with an MFR (300°C, 1.2kg) of 10.5g / 10min, an MFR (220°C, 10kg) of 32g / 10min, and an average 2.275 kilograms of bulk polymerization ABS resin (ABS-2) with a rubber particle diameter of 0.8 microns, MFR (230°C, 2.16kg) is 7g / 10min, 0.200 kilograms of SMA resin with maleic anhydride weight percent content 18%, anti- Oxygen agent 1010 25 grams, white oil (12#) 25 grams, put into a container and mix homogeneously with agitator, then add in the twin-screw extruder feeder and prepare polycarbonate / ABS alloy by the same condition of embodiment 1 , Injection molded strips and test performance, the results are shown in Table 2.

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Abstract

The invention relates to a polycarbonate / ABS resin plastic alloy to mainly solve a problem of low impact strength of polycarbonate / ABS plastic alloys prepared through previous technologies. The problem is well solved through adopting a technical scheme that the plastic alloy is composed of a polycarbonate resin, a bulk polymerization ABS resin, a compatilizer SMA resin, and auxiliary agents of an antioxidant and the like in the invention. The polycarbonate / ABS plastic alloy can be applied to the production of various plastic products needing the high impact strength, such as automobile bumpers, meter panels and the like.

Description

technical field [0001] The invention relates to a polycarbonate / ABS resin plastic alloy. Background technique [0002] Polycarbonate resin is a kind of engineering plastic with excellent performance. It has the highest impact strength among all resins (Izod notched impact strength of 3.17mm thick sample reaches 800-1000J / m) and high heat resistance and transparency. , electrical insulation and dimensional stability, but its high melt viscosity limits its application as injection molding products: the processing temperature is high, and it is difficult to inject large-scale products; High stress, prone to stress cracking. ABS resin is a copolymer or blend of acrylonitrile-styrene-diene rubber, which has the characteristics of easy molding and processing, stable size, and good stress crack resistance. Blending polycarbonate resin and ABS resin to make PC / ABS plastic alloy can well solve the above-mentioned shortcomings of polycarbonate resin, and at the same time have high h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L55/02C08L35/06
Inventor 傅荣政王芳姚斌
Owner CHINA PETROLEUM & CHEM CORP
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