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Low-temperature-resistant ultra-toughness modified nylon alloy material and preparation method thereof

A technology for modifying nylon and alloy materials, applied in coatings and other directions, can solve problems such as unsatisfactory low temperature resistance and toughness, and achieve the effects of inhibiting copper pollution, high toughness, and high comprehensive performance.

Active Publication Date: 2012-11-07
LUOHE KELAIBAO TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is: aiming at the defects of the existing PA66 (nylon) material in the application of outdoor use occasions such as railway equipment, automobile parts, construction machinery and sports equipment, etc., to provide a durable Low-temperature super-tough modified nylon alloy material and preparation method thereof

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The low-temperature-resistant super-tough modified nylon alloy material of the product of the present invention is represented by weight percentage, and its raw material composition is PA66 73%, PA6 10%, polyolefin thermoplastic elastomer TPV 7%, thermoplastic elastomer TPE 3%, Malay Anhydride grafted ethylene-octene copolymer POE-g-MAH 5%, UV absorber UV-326 0.8%, UV absorber UV-9 0.2%, antioxidant 1076 0.3%, 2-mercaptobenzimidazole MB 0.2 % and ethylene bis stearic acid amide 0.5%.

Embodiment 2

[0027] Embodiment 2: basically the same as Embodiment 1, the difference is:

[0028] The product of the present invention is a low-temperature-resistant super-tough modified nylon alloy material, expressed in weight percentage, its raw material composition is PA66 75%, PA6 8%, polyolefin thermoplastic elastomer TPV 6%, thermoplastic elastomer TPE 2%, Malay Anhydride grafted ethylene-octene copolymer POE-g-MAH 7%, UV absorber UV-326 0.6%, UV absorber UV-9 0.3%, antioxidant 1076 0.2%, 2-mercaptobenzimidazole MB 0.3 % and ethylene bis stearic acid amide 0.6%.

Embodiment 3

[0029] Embodiment 3: basically the same as Embodiment 1, the difference is:

[0030] The product of the present invention is a low-temperature-resistant super-tough modified nylon alloy material, expressed in weight percentage, and its raw material composition is PA66 70%, PA6 12%, polyolefin thermoplastic elastomer TPV 6.3%, thermoplastic elastomer TPE 4%, Malay Anhydride grafted ethylene-octene copolymer POE-g-MAH 6%, UV absorber UV-326 0.5%, UV absorber UV-9 0.2%, antioxidant 1076 0.4%, 2-mercaptobenzimidazole MB 0.2 % and ethylene bis stearic acid amide 0.4%.

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PUM

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Abstract

The invention discloses a low-temperature-resistant ultra-toughness modified nylon alloy material and a preparation method thereof. The low-temperature-resistant ultra-toughness modified nylon alloy material is prepared from the following raw materials: PA (poly A) 66, PA6, a main flexibilizer, an auxiliary flexibilizer, a compatilizer, a main ultraviolet absorption agent, an auxiliary ultraviolet absorption agent, a main antioxidant, an auxiliary antioxidant and a lubricating agent. The preparation method comprises the following steps of: mixing the raw materials in a high mixing machine uniformly; putting the mixture into a dual-screw extrusion pelletizer for heating and fusing, vacuumizing, slicing and pelletizing; drying materials after pelletization in a vacuum box, so as to obtain the product granulate low-temperature-resistant ultra-toughness modified nylon alloy material provided by the invention. The product low-temperature-resistant ultra-toughness modified PA66 alloy material provided by the invention has high comprehensive performances and excellent temperature-resistant performance, achieves the advanced level of similar products abroad, can replace imported materials, and meets the high-quality requirement of the domestic market on the ultra-toughness PA66 alloy.

Description

technical field [0001] The invention relates to a nylon alloy material and a preparation method thereof, in particular to a low-temperature resistant super-tough modified nylon alloy material and a preparation method thereof. Background technique [0002] As a widely used engineering plastic, nylon (polyamide) is flexible, wear-resistant and has high mechanical strength. At the same time, polyamide (PA) is a crystalline high polymer, which will have a sharp yield point when it is subjected to tensile stress, and the stress will gradually increase with the increase of strain after passing the yield point. Therefore, if unmodified nylon is used in certain fields, its ductility, notched impact strength and low temperature toughness need to be modified. [0003] The existing nylon toughening modification methods mainly include the following: 1) Copolymerization with other lactams or amino acids; 2) Toughening with rubber or elastomer components; 3) Core-shell polymers Tougheni...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08L23/00C08L23/06C08L75/04C08L23/16C08L51/06C08L51/00C08K5/526C08K5/378C08K5/372C08K5/3475C08K5/20C08K5/134C08K5/132B29B13/06B29B9/04B29B9/16B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/625B29C48/92B29C2948/92704B29C2948/92904
Inventor 李蕾赵书伟李崇勋李拴成农秉茂张向前
Owner LUOHE KELAIBAO TECH CO LTD
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