Evaluation screening method and evaluation operating process for chlorine-containing disinfectants

A screening method and disinfectant technology, which is applied in the direction of material analysis by observing the influence of chemical indicators, analysis by making materials undergo chemical reactions, and analysis by using chemical indicators, can solve the problem of distortion of available chlorine indicators and disinfection effect. difference, distortion and other problems, to avoid refrigerator storage, simple calculation and simple operation

Active Publication Date: 2012-11-14
中国人民解放军69081部队防化修理所
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In actual use, the effective chlorine evaluation disinfectant determined by iodometric method encounters the following index distortion problems: First, although the measured effective chlorine content of different chlorine-containing disinfectants is the same, the disinfection effect is quite different, such as hypochlorous acid The disinfection effect of calcium solution is not as good as that of sodium hypochlorite solution within a certain period of time; the second is that the same disinfectant has the same effective chlorine but the disinfection effect is also significantly different, such as the three-in-two clarified solution is worse than its suspension; The disinfection effect of the stored compound chlorine-containing disinfectant is not as fast as that of the original chlorine-containing disinfectant
[0006] None of the above literatures have seen the improvement of the evaluation and screening methods of chlorine-containing disinfectants and the solution to the problem of distortion of available chlorine indicators

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1: Comparison test of starting chlorine equivalent of the same kind of chlorine-containing disinfectant.

[0026] After the three-in-two dry powder and water are prepared in a weight ratio of 1:6, the suspension and the clear liquid are respectively taken, and titrated according to the method of the available chlorine and the initial chlorine equivalent of the present invention. The measurement results showed that the available chlorine was the same, but the initial chlorine equivalent suspension and clear solution were 0.11% and 0.25%, respectively, indicating that the initial reaction capacity of the three-in-two clear solution was greater than that of the suspension. The above two disinfectants were added into a test tube with the same weight of mustard gas respectively. The highest temperature of the disinfection reaction of the clear solution was 42℃, and the highest temperature appeared at the 10th minute after the mustard gas was added; and the highest disinf...

Embodiment 2

[0027] Example 2: Stability evaluation test of chlorine-containing disinfectant.

[0028] After placing the sodium hypochlorite compound solution marked with 6.3% effective chlorine for 2 years, it is evaluated and determined according to the method of the present invention for effective chlorine and initial chlorine equivalent. As a result of the measurement, the effective chlorine content is 6.1%, and the initial chlorine equivalent is 0.071%. The reason for the long-term stability of the solution is that its initial chlorine equivalent is extremely low.

[0029] The term "initial chlorine equivalent" or "chlorine equivalent" in the present invention has the same mechanism of action as "available chlorine" in the chemical industry, except that the results are obtained under different test conditions. The chlorine equivalent emphasizes that it is measured without adding acid. The available chlorine is measured by the iodometric method under the condition that acid is added and t...

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PUM

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Abstract

The invention relates to an evaluation screening method and an evaluation operating process for chlorine-containing disinfectants. The evaluation screening method for chlorine-containing disinfectants comprises the following steps of: adding potassium iodide into a chlorine-containing disinfectant to be determined, so that the potassium iodide is oxidized and iodine is separated out; through taking starch as an indicator, carrying out titration by using a standard sodium thiosulfate solution; and calculating the initial chloride equivalent according to the consumption of the standard sodium thiosulfate solution. In the process of determining, the potassium iodide is directly added into the chlorine-containing disinfectant to be determined, so that the potassium iodide is oxidized and iodine is separated out, and the potassium iodide is not oxidized under the condition of adding an acid into the disinfectant. The operating process of implementing the evaluation method comprises the steps of adding a plurality of KI powder into a quantitative disinfectant to be determined, carrying out titration by using standard sodium thiosulfate, and calculating the initial chloride equivalent according to the consumption of the standard sodium thiosulfate. By using the evaluation screening method and operating process disclosed by the invention, the initial chloride equivalent of a disinfectant can be rapidly determined. The stability and storage capacity of a disinfectant and the initial reaction capacity (closely relevant to a spray disinfection method) of the disinfectant are evaluated by using the chlorine equivalent, thereby solving the problem of evaluation index distortion caused by separately using available chlorine.

Description

Technical field [0001] The invention relates to a method for evaluating and screening chlorine-containing disinfectants, which includes the steps of oxidation of available chlorine and potassium iodide in the disinfectants, the step of titrating iodine with a sodium thiosulfate standard solution, and the calculation is based on the consumption of the sodium thiosulfate standard solution Steps to find the available chlorine content. [0002] The invention also relates to an operating process for realizing the evaluation and screening method of the chlorine-containing disinfectant, including the chemicals used, operating steps and calculation formulas. Background technique [0003] Chlorine-containing disinfectants mainly include three-in-one, sodium hypochlorite, etc. It is a high-efficiency disinfectant, convenient to use and affordable, and is widely used in major disaster relief operations for epidemic prevention and biological and chemical poison decontamination. [0004] Accordi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N31/22G01N21/78
Inventor 徐云赵承进曾凡哲高庆生李旭赵生亚宋秀伟徐卫东
Owner 中国人民解放军69081部队防化修理所
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