Shoulder wedge composite material and manufacturing method thereof

A composite material and tire shoulder pad rubber technology, which is applied in the field of rubber composite materials, can solve the problems of increased dynamic heat generation of rubber composite materials, practical application in unfavorable dynamic occasions, and limited improvement of thermal conductivity, and achieves excellent processing performance and good processing. performance, the effect of prolonging the service life

Active Publication Date: 2013-01-30
BEIJING UNIV OF CHEM TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Wang Zhenhua and others proposed to add a large number of parts (above 100 parts) of nano-alumina thermally conductive fillers to improve the thermal conductivity of rubber composites (rubber nano-reinforcement mechanism and research on the preparation, structure and performance of new enhanced thermally conductive rubber composites. Doctoral dissertation ), but due to the excessive amount of filler, it will lead to high cost and difficult processing
When Wu Ning and othe

Method used

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  • Shoulder wedge composite material and manufacturing method thereof

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Experimental program
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Example Embodiment

[0021] The preparation method includes the following steps: 1) After the rubber is masticated in the internal mixer, add coarse particle carbon black, carbon-based nano thermally conductive filler, surfactant, octyl phenolic resin, and other additives, and the temperature is controlled at 80- 120℃, mix for 30-60 seconds; 2) Add silane coupling agent, control the temperature at 120-160℃, mix for 3-5 minutes, discharge the rubber, and form a masterbatch after cooling; 3) Add the cooled masterbatch Add vulcanizing agent and anti-scorching agent into the internal mixer at the same time, and discharge after the temperature reaches 100-105℃. The radial truck tire shoulder pad rubber composite material prepared by the invention has good processing performance, mechanical performance and low heat generation performance, and at the same time has high thermal conductivity, and can effectively improve the durability of the truck radial tire.

[0022] The raw material compositions of specifi...

Example Embodiment

[0023] Example 1

[0024] Using 100 parts of natural rubber, 15 parts of CNT, 20 parts of N660, 3 parts of triethanolamine, 3 parts of Si69, 3 parts of zinc oxide, 1 part of stearic acid, 2 parts of octyl phenolic resin, 1 part of antioxidant 4020, 1.2 parts of anti-aging Agent RD, 1.5 parts of accelerator CZ, 3 parts of insoluble sulfur IS6033, 0.2 parts of anti-scorching agent CTP. Vulcanize at 151℃×30min on a flat vulcanizer. The tensile strength of the rubber compound is 25MPa, 100% fixed elongation 2.2MPa, 300% fixed elongation 11.4MPa, elongation at break 532%, tear strength 112KN / m, compression fatigue temperature The temperature rise is 12.6℃, the compression set is 2.7%, and the thermal conductivity is 0.356W / mK.

Example Embodiment

[0025] Example 2

[0026] Using 100 parts of natural rubber, 13 parts of CNTB, 22 parts of N660, 2.5 parts of triethanolamine, 4 parts of Si69, 3.5 parts of zinc oxide, 1 part of stearic acid, 3 parts of octyl phenolic resin, 1.2 parts of antioxidant 4020, 1.5 parts of anti-aging Agent RD, 1.6 parts of accelerator CZ, 3.1 parts of insoluble sulfur IS6033, 0.3 parts of anti-scorching agent CTP. Vulcanized at 151℃×30min on a flat vulcanizer. The tensile strength of the rubber is 27MPa, 100% fixed elongation 2.3MPa, 300% fixed elongation 12.4MPa, breaking elongation 502%, tear strength 122KN / m, and compression fatigue temperature. The temperature rise is 13.6℃, ​​the compression set is 3.3%, and the thermal conductivity is 0.379W / mK.

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Abstract

The invention discloses a shoulder wedge composite material and a manufacturing method thereof. The shoulder wedge composite material consists of the following raw materials in part by weight: 100 parts of natural rubber, 10 to 50 parts of carbon series nano thermal conducting filler, 10 to 35 parts of coarse particle size carbon black, 2 to 6 parts of octyl phenolic resin, 2 to 4 parts of surfactant, 1 to 8 parts of silane coupling agent, 1.5 to 9 parts of vulcanizing agent and the balance of other common aids. The preparation method comprises the following steps of: plasticating the rubber in an internal mixer, adding the coarse particle size carbon black, the carbon series nano thermal conducting filler, the octyl phenolic resin, the surfactant and the other aids into the internal mixer, mixing and controlling the temperature to be between 80 and 120 DEG C; adding the silane coupling agent into the mixture, controlling the temperature to be between 120 and 160 DEG C, and discharging the sizing material; adding a master batch and the vulcanizing agent into the internal mixer and discharging products until the temperature is 80 to 120 DEG C, wherein if the other aids contain scorch retarder, the scorch retarder and the vulcanizing agent are added together. The shoulder wedge composite material provided by the invention meets the requirements of mechanical properties, and is low in themogenesis, high in thermal conductivity, and excellent in machinability.

Description

technical field [0001] The invention belongs to rubber composite materials, in particular to a shoulder pad rubber for improving the durability of a load-bearing radial tire and a preparation method thereof. Background technique [0002] In recent years, automobiles have become more and more popular and high-speed. Due to the viscoelastic properties of rubber, tires generate a lot of heat under periodic loads, and rubber is a poor conductor of heat, so it is difficult to discharge heat in time. Due to heat accumulation, the temperature inside the tire will increase, which will cause the shoulder void phenomenon in the thicker part of the tire, which will affect the durability and service life of the tire. The shoulder pad rubber connects the tread, the carcass layer and the second belt layer in the shoulder part, and plays a vital role in the heat dissipation of the shoulder part. How to prepare shoulder pad rubber with low heat generation and high thermal conductivity has ...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L61/06C08K13/06C08K9/06C08K9/04C08K7/00C08K3/04C08K3/20
Inventor 卢咏来王宽张立群田明王小娟李昭杨艳平刘磊
Owner BEIJING UNIV OF CHEM TECH
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