Shoulder wedge composite material and manufacturing method thereof
A composite material and tire shoulder pad rubber technology, which is applied in the field of rubber composite materials, can solve the problems of increased dynamic heat generation of rubber composite materials, practical application in unfavorable dynamic occasions, and limited improvement of thermal conductivity, and achieves excellent processing performance and good processing. performance, the effect of prolonging the service life
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[0021] The preparation method includes the following steps: 1) After the rubber is masticated in an internal mixer, add coarse-grained carbon black, carbon-based nano-thermal conductive fillers, surfactants, octyl phenolic resin, and other additives, and the temperature is controlled at 80- 120°C, mix for 30-60 seconds; 2) Add silane coupling agent, control the temperature at 120-160°C, mix for 3-5 minutes, discharge the rubber, and form a master batch after cooling; 3) Add the cooled master batch Vulcanizing agent and anti-scorch agent are added into the internal mixer at the same time, and discharged after the temperature reaches 100-105°C. The shoulder pad rubber composite material of the load radial tire prepared by the invention not only has good processability, mechanical properties and low heat generation performance, but also has high thermal conductivity, and can effectively improve the durability of the load radial tire.
[0022] Concrete embodiment and comparative e...
Embodiment 1
[0024] Using 100 parts of natural rubber, 15 parts of CNT, 20 parts of N660, 3 parts of triethanolamine, 3 parts of Si69, 3 parts of zinc oxide, 1 part of stearic acid, 2 parts of octyl phenolic resin, 1 part of anti-aging agent 4020, 1.2 parts of anti-aging Agent RD, 1.5 parts of accelerator CZ, 3 parts of insoluble sulfur IS6033, 0.2 parts of anti-scorch agent CTP. Vulcanized on a flat vulcanizer at 151℃×30min, the tensile strength of the rubber material is 25MPa, the 100% constant extension is 2.2MPa, the 300% constant extension is 11.4MPa, the elongation at break is 532%, the tear strength is 112KN / m, and the compression fatigue temperature Rise 12.6 ℃, compression set 2.7%, thermal conductivity 0.356W / mK.
Embodiment 2
[0026] Using 100 parts of natural rubber, 13 parts of CNTB, 22 parts of N660, 2.5 parts of triethanolamine, 4 parts of Si69, 3.5 parts of zinc oxide, 1 part of stearic acid, 3 parts of octyl phenolic resin, 1.2 parts of anti-aging agent 4020, 1.5 parts of anti-aging Agent RD, 1.6 parts of accelerator CZ, 3.1 parts of insoluble sulfur IS6033, 0.3 parts of anti-scorch agent CTP. Vulcanized on a flat vulcanizer at 151℃×30min, the tensile strength of the rubber material is 27MPa, the 100% constant extension is 2.3MPa, the 300% constant extension is 12.4MPa, the elongation at break is 502%, the tear strength is 122KN / m, and the compression fatigue temperature Rise 13.6 ℃, compression set 3.3%, thermal conductivity 0.379W / mK.
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