Gas-sensitive film and sensor applied to FBAR (film bulk acoustic resonator) and SAW (surface acoustic wave) sensor
A gas-sensitive membrane and sensor technology, applied in the direction of using sonic/ultrasonic/infrasonic waves to analyze fluids, etc., can solve the problems of high humidity response, poor gas permeability, affecting sensor sensitivity and selectivity, etc., and achieve fast response speed. , stable performance, fast reversible adsorption/desorption effect
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[0024] The invention is suitable for the gas sensitive film of surface acoustic wave (SAW) and film bulk acoustic wave (FBAR) gas sensors, and adopts the calixarene / diamond-like structure. Calixarenes are prepared on the bottom as a diamond-like surface. in:
[0025] The diamond-like carbon is a hydrogen-containing diamond-like carbon film a-C:H (1). This a-C:H film contains more CHn (n=1-3) bonds, is hydrophobic, hardly absorbs water vapor in the atmosphere, and can eliminate interference responses caused by humidity; its thermal expansion coefficient is small (1×10 -6 / K), insensitive to temperature changes, and does not tend to vitrify.
[0026] The calixarene (2) is a class of macrocyclic supramolecular compounds bridged by phenol and methylene, and a single calixarene looks like a bottomless cup, forming a hydrophobic cavity inside which can accommodate guest molecules; The calixarene self-assembled on a hydrogen-containing diamond-like carbon film (a-C:H) via a hydrop...
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