The invention relates to the field of a super capacitor and particularly provides a metal conductive material utilized as a potassium ion hybrid super capacitor cathode and a potassium ion hybrid super capacitor, and a preparation method thereof. The potassium ion hybrid super capacitor comprises a negative electrode, an isolation film, a positive electrode and an electrolyte, wherein the negative electrodes is metal, alloy or a composite metal material capable of realizing alloying with potassium ions of the electrolyte, the positive electrode comprises a positive electrode material and a positive electrode current collector, a positive electrode active material of the positive electrode material is a carbon material capable of realizing reversible adsorption and desorption of anions of the electrolyte, and the potassium ions are contained in the electrolyte of the hybrid super capacitor. The potassium ion hybrid super capacitor is advantaged in that the metal, the alloy or the composite metal material capable of realizing alloying with the potassium ions of the electrolyte is taken as the negative electrode, the material has the double functions as the negative electrode active material and the negative electrode current collector, not only can the production process of the super capacitor be simplified, production cost is reduced, but also energy density and theoretical specific capacity of the super capacitor are improved.