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High-concentration nitrogen oxide waste gas catalytic decomposing method

A technology for catalytic decomposition, nitrogen oxides, applied in separation methods, chemical instruments and methods, dispersed particle separation, etc., to achieve the effect of facilitating control, avoiding consumption, and facilitating heating temperature

Active Publication Date: 2015-02-04
朝阳金美镓业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invention solves the problem of non-toxic treatment of high-concentration nitrogen oxide waste gas generated in the process of nitrification reaction

Method used

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  • High-concentration nitrogen oxide waste gas catalytic decomposing method

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Comparison scheme
Effect test

Embodiment 1

[0013] Embodiment 1: see figure 1 , a method for catalytic decomposition of high-concentration nitrogen oxide exhaust gas. The catalytic decomposition device used includes a housing 9, a cavity 5, an exhaust gas inlet 10, an exhaust gas outlet 7, and a catalyst feed port 6. The cavity is also provided with a catalyst The bed 1 and the catalyst bed are used to place the catalyst catalyst 3; an electric heating device 2 is also provided in the cavity, and the electric heating device can be provided with a control device for heating temperature and heating time, so as to facilitate the control of the catalytic reaction. The inner wall of the cavity 5 is provided with an insulating layer 8, and the insulating layer is ceramic insulating cotton. The material of the shell is stainless steel. The chamber body is cylindrical, and its lower part is provided with a cleaning chamber 11 for collecting scattered catalytic catalyst 3 and catalytic reaction products, so as to facilitate tim...

Embodiment 2

[0016] Embodiment 2: It differs from Embodiment 1 in that the exhaust gas inlet is arranged at the bottom of the catalytic decomposition device, and the exhaust gas outlet is arranged at the top of the catalytic decomposition device. Add 1kg of catalytic catalyst coke in its catalyst bed, start the electric heating device, set the temperature to be 1000°C, make it reach the set temperature and keep it. Take 1000ml concentrated HNO 3 (68%) reacts with excess red copper. When the reaction is carried out, the nitrogen oxide waste gas produced is passed into the waste gas inlet through the introduction pipe. From the observation window, the brown-red gas entering from the introduction can be seen. After passing through the catalyst bed, It becomes a colorless gas and is discharged from the exhaust gas outlet.

[0017] Through theoretical calculation: 1000ml concentrated HNO 3 (68%) react with excess copper, producing NO on average per hour 2 42.3L, a total of 169.2L was produce...

Embodiment 3

[0018] Embodiment 3: It differs from Embodiment 2 in that the catalytic catalyst is activated carbon. Start the electric heating device and set the temperature to 930°C.

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Abstract

The invention discloses a high-concentration nitrogen oxide waste gas catalytic decomposing device. The high-concentration nitrogen oxide waste gas catalytic decomposing device comprises a housing, a cavity, a waste gas inlet and a waste gas outlet, wherein the cavity is internally provided with a catalyst bed which is used for placement of a catalyst; the cavity is also provided with a heating device which can be an electric heating device; the inner wall of the cavity is provided with an insulating layer which is ceramic insulating cotton; and the housing is made of stainless steel. By adopting the high-concentration nitrogen oxide waste gas catalytic decomposing device, the problem of detoxifying treatment of the high-concentration nitrogen oxide waste gas produced in the process of nitration reaction is solved.

Description

technical field [0001] The invention relates to a treatment method for nitrogen oxide waste gas, in particular to a catalytic decomposition method for high-concentration nitrogen oxide waste gas generated in the nitrification process. Background technique [0002] Nitrogen oxides are poisonous, harmful and highly corrosive gases. Chemical reactions involving nitro compounds and nitric acid will produce harmful gases containing nitrogen oxides, which seriously endanger the environment and the health of humans and animals. [0003] Automobile exhaust contains low concentrations of nitrogen oxides, which have been treated with catalyst tubes composed of catalysts made of rare precious metals and rare earth metals. High concentrations of nitrogen oxides produced in industry are generally absorbed by leaching with lye or reducing agent solution, but this is not thorough and causes secondary pollution. The latest coke reduction method has a good treatment effect, but its disadvan...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/86B01D53/56
Inventor 范家骅杜万毅吕学平邱才涌
Owner 朝阳金美镓业有限公司