Homogeneous same-phase silica mud for large coke oven

A mud and coke oven technology, applied in the field of siliceous mud, can solve the problems of neglecting bond strength, asynchronous volume effect, large thermal expansion rate of mud, etc., and achieves the effect of reducing production cost, significant economic benefits, and increasing plasticity and strength.

Active Publication Date: 2013-03-27
REFRACTORY MATERIAL OF SINOSTEEL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The second generation of silicon fire clay is prepared with natural siliceous sand and soft bonded clay in a certain proportion, and sometimes additives are added. This generation of silicon fire clay focuses on solving the construction performance, ignoring the bonding strength. When using natural silicon materials to prepare fire clay The mud still implements the YB384-63 standard, but the important component of silica brick powder is omitted, resulting in some coke oven silica fire clay and silica bricks not bonding, which is the biggest shortcoming of the second-generation sili

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Ingredients and process: particle size 1-0.5mm, SiO 2 23 parts of waste silica bricks with a content of 94%, 15 parts of waste silica bricks with a particle size of 0.5mm-0.2mm, 10 parts of waste silica bricks with a particle size of 0.2-0mm, 13 parts of waste silica bricks with a particle size of 220 mesh 11 parts of silica brick powder. SiO 2 8 parts of 98% natural silica with a particle size of 0.5-0.2mm, 15 parts of 180-mesh silica powder, 5 parts of Guangxi bonded clay, plus 0.1 part of polyphosphate, 0.5 part of white dextrin, polymer Polymer polyacrylamide 0.1 part, medium temperature sintering agent sodium carbonate 0.05 part. Put it into a closed screw mixer for pre-mixing for 15 minutes, then put it into a strong sand mixer, add 28 parts of tap water accounting for the total weight of all raw materials, stir for 10 minutes, and then leave it for 15-30 minutes.

Embodiment 2

[0026] Ingredients and process: particle size 1-0.5mm, SiO 2 23 parts of waste silica bricks with a content of 94%, 16 parts of waste silica bricks with a particle size of 0.5mm-0.2mm, 10 parts of waste silica bricks with a particle size of 0.2-0mm, 15 parts of waste silica bricks with a particle size of 220 mesh 11 parts of silica brick powder. SiO 2 10 parts of 98% natural silica with a particle size of 0.5-0.2mm, 10 parts of 180-mesh silica powder, 2 parts of Guangxi bonded clay, plus 0.1 part of polyphosphate, 0.5 part of white dextrin, polymer Polymer polyacrylamide 0.15 parts, medium temperature sintering agent sodium carbonate 0.1 part. Put it into a closed screw mixer for pre-mixing for 15 minutes, then put it into a strong sand mixer, add 28 parts of tap water accounting for the total weight of all raw materials, stir for 10 minutes, and then leave it for 15-30 minutes.

Embodiment 3

[0028] Ingredients and process: particle size 1-0.5mm, SiO 2 25 parts of waste silica bricks with a content of 94%, 15 parts of waste silica bricks with a particle size of 0.5mm-0.2mm, 8 parts of waste silica bricks with a particle size of 0.2-0mm, 14 parts of waste silica bricks with a particle size of 220 mesh 14 parts of silica brick powder. SiO 2 7 parts of 98% natural silica with a particle size of 0.5-0.2mm, 14 parts of 180-mesh silica powder, 3 parts of Guangxi bonded clay, plus 0.1 part of polyphosphate, 0.5 part of white dextrin, polymer 0.15 part of polymer polyacrylamide, 0.2 part of medium temperature sintering agent sodium carbonate. Put it into a closed screw mixer for pre-mixing for 15 minutes, then put it into a strong sand mixer, add 28 parts of tap water accounting for the total weight of all raw materials, stir for 10 minutes, and then leave it for 15-30 minutes.

[0029] The detection index of above-mentioned three embodiments is as follows:

[0030] It...

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Abstract

The invention discloses a homogeneous same-phase silica mud for a large coke oven, which comprises the following components in parts by weight: 70-80 parts of waste silica bricks with SiO2 content higher than 94%, 17-25 parts of natural silica with SiO2 content higher than 98%, 2-5 parts of soft binding clay with Al2O3 content higher than 25%, 0.05-0.1 part of carboxymethyl cellulose, 0.1-0.2 part of white dextrin, 0.1-0.2 part of medium-temperature sintering agent sodium carbonate and 0.1-0.2 part of high-molecular polymer polyacrylamide. The homogeneous same-phase silica mud according to claim 1 comprises the granularity of the waste silica bricks comprises the following parts in parts by weight: 23-25 parts of 1-0.5mm waste silica bricks, 15-16 parts of 0.5-0.2 mm waste silica bricks, 8-10 parts of 0.2-0mm waste silica bricks, 13-15 parts of 180-mesh waste silica bricks and 11-14 parts of 220-mesh waste silica bricks. The homogeneous same-phase silica mud for the large coke oven according to claim 1 is characterized in that the sieving rate for the soft binding clay to pass through a 180-mesh sieve is bigger than 95%. A preparation method for the homogeneous same-phase silica mud according to claim 1 comprises the following steps: 1, preparing and adding 70-80 parts of waste silica bricks, 17-25 parts of natural silica, 2-5 parts of soft binding clay, 0.05-0.1 part of carboxymethyl cellulose, 0.1-0.2 part of white dextrin, 0.1-0.2 part of medium-temperature sintering agent sodium carbonate and 0.1-0.2 part of high-molecular polymer polyacrylamide to a double-helix mixing mill for pre-mixing; 2, packaging the mixed material based on piece weight; 3, adding the silica mud to a sand mixer at a using site, and directly adding the silica mud to the sand mixer, adding tap water which is 30-35% of the total weight of the silica mud for stirring for 10-15 minutes, and stewing the mixture for 30 minutes; and 4, directly coating the mixed materials to a brickwork for use.

Description

technical field [0001] The invention relates to a kind of material which is suitable for bricklaying of large-scale coke oven body, has the same quality and phase as the silica brick, and has the same thermal expansion rate as the silica brick. It consists of 70-80 parts of waste silica bricks, 17-25 parts of natural silica siliceous mud consisting of 2-5 parts of combined clay and 0.5-1 part of total weight of admixture. Background technique [0002] The siliceous mud used for coke oven silica brick masonry can be roughly divided into three generations. The 1970s was the first generation. The technical requirements of silicon cement are relatively smooth and simple, and the softening point under load is not even mentioned. The second generation of silicon fire clay is prepared with natural siliceous sand and soft bonded clay in a certain proportion, and sometimes additives are added. This generation of silicon fire clay focuses on solving the construction performance, i...

Claims

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Application Information

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IPC IPC(8): C04B35/66
Inventor 段桂芳杨志宾姚全灵马翔宏张玉涛杨俊瑞杨秀丽刘勇
Owner REFRACTORY MATERIAL OF SINOSTEEL CORP
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