Coating composition and applications thereof
A composition and coating technology, applied in coatings, plastic/resin/wax insulators, devices for coating liquids on surfaces, etc. problems such as poor coating, to achieve the best coating uniformity, good reworkability and adhesion
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[0033] The synthesis method of the block copolymer (A) of the present invention comprises the following steps: (1) polymerization reaction, respectively dissolving the vinyl aromatic monomer and the conjugated diene monomer in an organic solvent, and then Adding a polymerization initiator to carry out anionic polymerization to form a block copolymer precursor; and (2) hydrogenation reaction, performing a hydrogenation reaction on the block copolymer precursor in the presence of a hydrogenation catalyst to obtain the block copolymer precursor of the present invention Copolymer (A).
[0034] (1) Polymerization reaction:
[0035] When preparing the block copolymer, preferably, the vinyl aromatic monomer and / or the conjugated diene monomer can be diluted with an organic solvent to an appropriate concentration, and then mixed and polymerized. In a specific embodiment of the present invention, the diluted concentration is 25% by weight.
[0036] Preferably, the organic solvent is ...
Synthetic example 1
[0079] Under nitrogen ambient gas, will contain the cyclohexane solution of the styrene (styrene) of 15 weight parts, the n-butyllithium of 0.13 weight part, and the tetramethylethylenediamine of 0.05 weight part [randomization agent (randomizer (randomizer) )] placed in an autoclave with a stirrer, and polymerized at a temperature of 70° C. for 20 minutes. Next, a cyclohexane solution containing 70 parts by weight of 1,3-butadiene was added to the autoclave over 50 minutes, and a polymerization reaction was performed at 70° C. for 5 minutes. Next, a cyclohexane solution containing 15 parts by weight of styrene was added, and a polymerization reaction was performed at 70° C. for 25 minutes. After the reaction, a solvent removal treatment was performed to obtain a block copolymer (A-1).
Synthetic example 2
[0081] Under nitrogen ambient gas, the cyclohexane solution containing 20 parts by weight of styrene, the n-butyllithium of 0.13 parts by weight, and the tetramethylethylenediamine of 0.05 parts by weight are placed in an autoclave with a stirrer , and carry out the polymerization reaction at a temperature of 70° C. for 20 minutes. Next, a cyclohexane solution containing 20 parts by weight of styrene and 30 parts by weight of 1,3-butadiene was added into the autoclave within 50 minutes, and a polymerization reaction was performed at 70° C. for 5 minutes. Next, a cyclohexane solution containing 15 parts by weight of 1,3-butadiene was further added, and polymerization reaction was performed at 70° C. for 5 minutes. Next, a cyclohexane solution containing 15 parts by weight of styrene was added, and the polymerization reaction was carried out at 70° C. for 25 minutes. After the reaction, a hydrogenation catalyst was added to the reaction solution containing the block copolymer pr...
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