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Light polymer base fibrilia reinforced composite and fabrication method thereof

A composite material and fiber reinforced technology, applied in the field of lightweight polymer-based hemp fiber reinforced composite materials and their preparation, can solve the problems of large density fluctuation of composite materials, different pore sizes, interference with chemical foaming process, etc. Taking into account the requirements of mechanical properties and density, the effect of weight loss is stable, and the effect of avoiding mutual interference

Inactive Publication Date: 2015-07-22
CHONGQING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The reasons are: ⑴The chemical foaming process is difficult to accurately control, resulting in large fluctuations in the density of composite materials, and it is difficult to form products with stable quality; ⑵AC foaming agent is an exothermic foaming agent, which must release a certain amount of heat during the foaming process , it is easy to cause the size of the holes formed in the material to be different, and even the holes are formed locally to collapse, which seriously affects the mechanical properties of the composite material.
(3) In the prior art, compatibilizers such as maleic anhydride grafts are often used to improve the mechanical properties of composite materials, but maleic anhydride grafts will interfere with the chemical foaming process, making it difficult to balance the performance and density of composite materials
(4) Chemical substances such as AC foaming agent and DCP crosslinking agent used in the chemical foaming method will release unpleasant taste, which is not conducive to the application of composite materials in automotive interior parts

Method used

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Examples

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Effect test

preparation example Construction

[0020] A method for preparing a lightweight polymer-based hemp fiber-reinforced composite material. In the method, the following raw materials are used in parts by weight: kenaf fiber 10-15, homopolypropylene 100, maleic anhydride grafted polypropylene 2.5-5, Hollow glass microsphere 5-20, coupling agent 0.1-0.15. Its method comprises the following steps:

[0021] (1), select the coupling agent, and use the coupling agent vaporization method to carry out surface treatment on the kenaf fiber;

[0022] (2) Weigh the hollow glass microspheres, and plasticize them with maleic anhydride grafted polypropylene, homopolypropylene and treated kenaf fiber in a double-roller masticator to form a composite material sheet, masticate The temperature is 125-135°C;

[0023] (3) After cutting the composite material sheet according to the size of the mould, put it in a flat vulcanizing machine for hot-pressing molding, the hot-pressing temperature is 165-175°C, and the hot-pressing pressure i...

Embodiment 1

[0025] Three kinds of hollow glass microspheres H32, H40 and H46 produced by Sinosteel Ma'anshan Mining Research Institute Co., Ltd. were used as weight reducers:

[0026] Weighing 10-15g of kenaf fiber and 0.1-0.15g of coupling agent, and adopting the coupling agent vaporization method to carry out surface treatment on the kenaf fiber. Weigh 10g of hollow glass microspheres H32, and masticate it with the processed kenaf fiber and 100g of homopolypropylene resin in a double-roller masticator to form a composite material sheet, and the mastication temperature is 125-135°C. After the composite sheet is cut according to the size of the mold, it is placed in a flat vulcanizing machine for hot-press molding. The hot-press temperature is 165-175°C and the hot-press pressure is 8-12MPa. The relevant mechanical properties and density are tested.

[0027] Weighing 10-15g of kenaf fiber and 0.1-0.15g of coupling agent, and adopting the coupling agent vaporization method to carry ou...

Embodiment 2

[0033] With different amounts of hollow glass microspheres H46 as weight reducer:

[0034] Weighing 10-15g of kenaf fiber and 0.1-0.15g of coupling agent, and adopting the coupling agent vaporization method to carry out surface treatment on the kenaf fiber. Take by weighing 5g hollow glass microspheres H46, and masticate it with the processed kenaf fiber and 100g homopolypropylene resin into a composite material sheet in a double-roller masticator, and the mastication temperature is 125-135°C. After the composite sheet is cut according to the size of the mold, it is placed in a flat vulcanizing machine for hot-press molding. The hot-press temperature is 165-175°C and the hot-press pressure is 8-12MPa. The relevant mechanical properties and density are tested.

[0035] Weighing 10-15g of kenaf fiber and 0.1-0.15g of coupling agent, and adopting the coupling agent vaporization method to carry out surface treatment on the kenaf fiber. Weigh 10g hollow glass microspheres H46,...

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PUM

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Abstract

The invention discloses a light polymer base fibrilia reinforced composite which comprises the following raw materials in parts by weight: 10-15 parts of kenaf fiber, 100 parts of homo-polypropylene, 2.5-5 parts of compatibilizer, 5-20 parts of weight reducing agent and 0.1-0.15 parts of coupling agent. In addition, the invention further discloses a fabrication method of the light polymer base fibrilia reinforced composite. The composite adopts a hollow glass microsphere, so that a weight reducing effect is stable; the density of the composite is controllable; mutual interference between the compatibilizer such as maleic anhydride grafted polymer and a chemical foaming agent can be avoided effectively; the action of the compatibilizer is exerted fully; the property of the composite is improved; requirements of the composite on both the mechanical property and the density are met; and the hollow glass microsphere is an inorganic substance, is tasteless and colorless, and does not affect an application of the composite in the field of automotive trim.

Description

technical field [0001] The invention relates to a lightweight polymer-based hemp fiber-reinforced composite material and a preparation method thereof, in particular to a light-weight polymer-based hemp fiber-reinforced composite material prepared by using hollow glass microspheres and a preparation method thereof. Background technique [0002] Hemp fiber is a large category of natural organic fillers, the main component of which is natural cellulose. The common types of hemp fiber are sisal, kenaf, flax, jute, ramie, hemp, kenaf and so on. After the hemp fiber is evenly mixed with polymer matrix such as thermoplastic or thermosetting resin, it can be made into automotive panels, automotive interior parts, etc. by injection molding, compression molding and other molding methods. Hemp fiber is a natural renewable resource with rich sources and low price. Using hemp fiber and synthetic resin to prepare interior parts such as car roofs and seat back panels has certain environme...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L97/02C08L51/06C08K7/28C08J5/06
Inventor 盛旭敏李又兵徐梁
Owner CHONGQING UNIV OF TECH
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