Preparation method for magnesium halogen-free flame retardant and application of magnesium halogen-free flame retardant to flame-retardant high-temperature-resistant tape

A flame retardant and high-temperature-resistant technology, which is applied in the field of composite flame retardant processing, can solve the problems of severe molten droplets, high price, and restrictions on the development of flame retardants, and achieve low production costs, cheap raw materials, and environmental protection against molten droplets. The effect of combustion characteristics

Inactive Publication Date: 2013-04-17
大连亚泰科技新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] [0003] At present, the most commonly used flame retardants for high temperature resistant conveyor belts are mainly organic phosphorus, bromine, chlorine, and antimony compounds. Organic phosphorus flame retardants are expensive, and halogen flame retardants generate a lot of smoke and are toxic and corrosive when burned The disadvantages such as strong gas, and severe molten droplets during combustion severely restrict the development of flame retardants in the field of high-temperature conveyor belts.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Example 1: Take 3kg of silane coupling agent and 70kg of magnesium hydroxide with an average particle size of 1 μm and mix them evenly in a high-speed mixer, then add 3kg of paraffin in turn, flame retardant synergist: MB-202 8kg, TPP8kg, zinc borate 5kg, DOP5kg, at a temperature of 100°C, high-speed stirring treatment with a high-speed mixer for 45 minutes to prepare a magnesium-based halogen-free flame retardant for high-temperature-resistant tapes.

Embodiment 2

[0023] Example 2: Take 3kg of silane coupling agent and 75kg of magnesium hydroxide with an average particle size of 1 μm, add them to a high-speed mixer and mix them evenly, then add 3kg of paraffin in turn, flame retardant synergists: MB-202 8kg, TPP8kg, zinc borate 5kg, DOP5kg, at a temperature of 100°C, high-speed stirring treatment with a high-speed mixer for 45 minutes to prepare a magnesium-based halogen-free flame retardant for high-temperature-resistant tapes.

Embodiment 3

[0024] Example 3: Take 3kg of silane coupling agent and 80kg of magnesium hydroxide with an average particle size of 1 μm and mix them evenly in a high-speed mixer, then add 3kg of paraffin in turn, flame retardant synergist: MB-202 8kg, TPP8kg, zinc borate 5kg, DOP5kg, at a temperature of 100°C, high-speed stirring treatment with a high-speed mixer for 45 minutes to prepare a magnesium-based halogen-free flame retardant for high-temperature-resistant tapes.

[0025] Application of the magnesium-based halogen-free flame retardant of the present invention in flame-retardant and high-temperature-resistant tapes: 30 g of the magnesium hydroxide prepared in Example 1, Example 2, and Example 3 were mixed with EPDM rubber 60 g, chlorine 40 g of butyl rubber was mixed on a two-roll mill to obtain a rubber sample, and the rubber sample was vulcanized on a molding vulcanization plate at 120° C. to obtain a rubber sample sheet.

[0026] The smoke density level and oxygen index test were...

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Abstract

The invention belongs to the field of composite flame retardant processing. The invention is characterized in that a magnesium halogen-free flame retardant comprises the following components in percentage by weight: 50-80% of ore type magnesium hydroxide, 1-5% of a surface modifier, 10-30% of a flame retardant synergist, 2-5% of a processing additive and 0-10% of a plasticizer. A preparation process for the magnesium halogen-free flame retardant comprises the steps as follows: adding the weighed surface modifier and magnesium hydroxide into a reactor, controlling the temperature to be 60-110 DEG D, uniformly mixing, adding the raw materials according to the weight ratio, and stirring by a high-speed stirrer to prepare the magnesium halogen-free flame retardant; and 2, diluting the weighed surface modifier through 20-50 parts of ethanol or acetone as a solvent, mixing with magnesium hydroxide in a low-speed kneading machine, heating, adding the raw materials according to the weight ratio, and stirring at a high speed to prepare the magnesium halogen-free flame retardant. The magnesium halogen-free flame retardant is strong in environment-friendly flame-retardant performance, cheap in the raw materials, low in production cost and better in economic and social benefits.

Description

technical field [0001] The invention belongs to the field of composite flame retardant processing, and in particular relates to a preparation method of a magnesium-based halogen-free flame retardant and its application in flame-retardant and high-temperature-resistant adhesive tapes, which are used for the preparation of high-temperature-resistant adhesive tapes below T4 level. Background technique [0002] High temperature resistant conveyor belts are mainly used in metallurgy, building materials, chemical industry and other industries to transport sintered ore, pelletized ore, cement clinker, lime, coke, fertilizer and other high temperature materials. In recent years, judging from the casualties after fires in coal mines, most of the victims died of suffocation due to inhalation of smoke and toxic gases generated during combustion. Conveyor belts are an urgent need for safe production in coal mines. [0003] [0003] At present, the most commonly used flame retardants for...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K13/06C08K9/06C08K9/04C08K3/22C08K5/3492C08K3/38C08K3/32C08K9/10C08K3/02C08L23/16C08L11/00
Inventor 孙忠祥
Owner 大连亚泰科技新材料股份有限公司
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