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Nitrile rubber for UHV large oil-immersed transformers

A technology of nitrile rubber and transformers, applied in the rubber field, can solve the problems of transformer breakdown, influence of normal operation of transformers, unsafe transformers, etc., to improve oil aging performance, solve gas production and insulation performance decline, and maintain safe operation. Effect

Inactive Publication Date: 2016-04-06
SHENYANG POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the gas content exceeds a certain standard, it will affect the normal operation of the transformer, resulting in the decline of the insulation performance and thermal conductivity of the transformer oil, and serious consequences such as the breakdown of the transformer, which will become an unsafe factor for the operation of the transformer.

Method used

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  • Nitrile rubber for UHV large oil-immersed transformers
  • Nitrile rubber for UHV large oil-immersed transformers
  • Nitrile rubber for UHV large oil-immersed transformers

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] In terms of mass fraction: 100 parts of nitrile rubber NBR, 0.1 part of stearic acid, 10 parts of carbon black, 10 parts of spray carbon black, 1 part of zinc oxide, 0.1 part of vulcanizing agent DTDM, and 0.1 part of vulcanizing agent TETD 0.1 part, 0.1 part of vulcanizing agent TMTD, 0.1 part of accelerator CZ, 0 part of anti-aging agent RD, 0.1 part of anti-aging agent MB, 0.1 part of anti-aging agent 4010, 1 part of paraffin wax, 1 part of Coumaron The dosage of octyl ester is 5 parts.

Embodiment 2

[0038] In terms of mass fraction: 100 parts of nitrile rubber NBR, 20 parts of stearic acid, 80 parts of carbon black, 80 parts of spray carbon black, 30 parts of zinc oxide, 20 parts of vulcanizing agent DTDM, and 20 parts of vulcanizing agent TETD 20. The amount of vulcanizing agent TMTD is 20 parts, the amount of accelerator CZ is 20 parts, the amount of anti-aging agent RD is 20 parts, the amount of anti-aging agent MB is 20 parts, the amount of anti-aging agent 4010 is 20 parts, the amount of paraffin is 20 parts, the amount of coumarone is 30 parts, sebacin The amount of ester is 50 parts.

Embodiment 3

[0040] In terms of mass fraction: 100 parts of nitrile rubber NBR, 1 part of stearic acid, 35 parts of carbon black, 20 parts of spray carbon black, 5 parts of zinc oxide, 2 parts of vulcanizing agent DTDM, and 2 parts of vulcanizing agent TETD 0.87, vulcanizing agent TMTD dosage 0.87, accelerator CZ dosage 1.45 parts, antioxidant RD dosage 1.5 parts, antioxidant MB dosage 1 part, antioxidant 4010 dosage 1 part, paraffin dosage 1 part, coumarone dosage 5 parts, sebacin The amount of ester is 10 parts.

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PUM

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Abstract

The invention belongs to the technical field of rubber, and mainly relates to a nitrile rubber used for an ultra-high voltage large oil-immersed transformer. The components and relative contents of the nitrile rubber are calculated by mass as follows: nitrile rubber NBR? 100 parts, 0.1-20 parts of stearic acid, 10-80 parts of carbon black, 10-80 parts of spray carbon black, 1-30 parts of zinc oxide, vulcanizing agent DTDM? 0.1-20 parts, vulcanizing agent TETD? 0.1-20, vulcanizing agent TMTD? 0.1-20, Accelerator CZ? 0.1-20 parts, anti-aging agent RD? 0-20 parts, antioxidant MB? 0.1-20 parts, anti-aging agent 4010? 0.1-20 parts, 1-20 parts of paraffin, 1-30 parts of coumarone, 5-50 parts of capryl decane. The nitrile rubber described in the invention has further improved compatibility with transformer oil, solves the problem of rubber gas production in the transformer, and ensures the stability and safety of the operation of the UHV large oil-immersed transformer.

Description

technical field [0001] The invention relates to the technical field of rubber, in particular to a nitrile rubber suitable for use in ultra-high voltage large oil-immersed transformers. Background technique [0002] In my country's implementation of the development strategy of "power transmission from west to east", power transformers are one of the most important and key equipment for the safe operation of my country's interconnection grid. Economic losses are immeasurable. Therefore, ensuring the safe operation of large power transformers occupies an extremely important position in the power system. [0003] Nitrile rubber (NBR) is made by butadiene CH 2 =CH-CH=CH 2 with acrylonitrile CH 2 =CH-CN is a general-purpose non-crystalline oil-resistant rubber obtained by emulsion polymerization. Its production process is similar to that of emulsion polymerization of styrene-butadiene rubber. At present, some nitrile rubber in the world is produced on the shared equipment of em...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L9/02C08K13/02C08K5/09C08K3/04C08K3/22
Inventor 张松汤丽文孙默冉胡方张春华
Owner SHENYANG POLYTECHNIC UNIV
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