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Low-shrinkage high-toughness ABS (Acrylonitrile Butadiene Styrene) composite and preparation method thereof

A composite material and low-shrinkage technology, applied in the field of ABS composite materials and its preparation, can solve the problems of poor impact strength, poor compatibility, poor oxidation resistance and ultraviolet radiation resistance, etc., and achieve good low temperature Impact properties, simple preparation process, and good application prospects

Inactive Publication Date: 2013-06-12
宁波锦地工程塑料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current PC / ABS alloy has the following disadvantages, first: the compatibility between PC and ABS is not good, resulting in poor overall mechanical properties of the alloy; second: the flame retardancy is not good, and the content of halogen elements is too high , has a certain pollution effect on the environment; third: poor impact strength, especially at low temperature, its impact toughness will be sharply reduced, which will easily lead to material failure; fourth: anti-oxidation ability and anti-ultraviolet radiation ability Poor, the service life of the material is not high

Method used

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  • Low-shrinkage high-toughness ABS (Acrylonitrile Butadiene Styrene) composite and preparation method thereof
  • Low-shrinkage high-toughness ABS (Acrylonitrile Butadiene Styrene) composite and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0020] The raw materials are calculated by weight percentage, PC30% (pre-dried at 120°C for 4 hours), ABS47% (pre-dried at 80°C for 2 hours), grafted POE5%, talcum powder 15%, antioxidant 10761.0%, phase Compatible agent MBS2% was added to the mixer and mixed for 10 minutes, and the temperature of the extruder was set: Zone 1: 240 °C; Zone 2: 250 °C; Zone 3: 230 °C; Zone 4: 230 °C; Zone 5: 225 °C; Zone: 220°C; Zone 7: 210°C; Zone 8: 225°C; Zone 9: 250°C; Extrude the premixed material through the extruder, pull the strips and cool them in the water tank, blow dry and pull them to the cutting The feeder completes the granulation, and it is ready. After testing, the shrinkage is 0.21% at -20°C, and the impact strength can reach 28.7kJ / m 2 .

Embodiment 2

[0022] The raw materials are calculated by weight percentage, PC25% (pre-dried at 120°C for 6 hours), ABS51% (pre-dried at 80°C for 4 hours), grafted POE7%, talcum powder 15%, antioxidant 10760.5%, phase Compatible agent MBS1.5% was added to the mixer and mixed for 20 minutes, and the temperature of the extruder was set: Zone 1: 240°C; Zone 2: 250°C; Zone 3: 240°C; Zone 4: 240°C; Zone 5: 235°C ; Six zone: 230℃; Seven zone: 220℃; Eight zone: 240℃; Until the cutting machine completes pelletizing, it is ready. After testing, the shrinkage is 0.23% at -20°C, and the impact strength can reach 26.0kJ / m 2 .

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Abstract

The invention relates to a low-shrinkage high-toughness ABS (Acrylonitrile Butadiene Styrene) composite and a preparation method thereof. The composite comprises ingredients in percentage by weight: 20-40% of PC, 40-60% of ABS, 5-15% of a flexibilizer, 10-25% of talcum powder, 0.3-1.0 of an antioxidant, and 0.5-2% of others. The preparation method comprises the steps of: according to the proportion, adding the PC, ABS and other raw materials into a mixer for mixing for 10-20minutes, extruding the premixed materials through an extruder, drawing and performing water cooling through a water tank, blowing to be dry for dragging to a stock cutter so as to complete dicing, thereby obtaining the low-shrinkage high-toughness ABS composite. The composite has small low-temperature shrinkage which is smaller than 0.25 and less than half of the normal shrinkage of the ABS under the condition of - 20 DEG C, and the composite also has good low-temperature impact property, and the impact strength can achieve 25kJ / m<2>; and the preparation technique is simple, and the cost is low, thereby having good application prospects.

Description

technical field [0001] The invention belongs to the field of ABS composite material and its preparation, in particular to a low-shrinkage high-toughness ABS composite material and a preparation method thereof. Background technique [0002] PC is an engineering plastic with excellent performance. It has excellent mechanical properties, dimensional stability, heat resistance and cold resistance. advantage. On the one hand, it can improve the heat resistance, impact resistance and tensile properties of ABS, making ABS used in high-end fields; on the other hand, it can reduce the melt viscosity of PC, improve the flow of PC, and improve its processing performance. Reduce the internal stress of the product, reduce the sensitivity of impact strength to notch and thickness, so that PC can be used in the manufacture of thin-walled long-process products. In recent years, PC / ABS alloys have been widely used in mobile phones, computer casings, electrical connectors and other supplies...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08L69/00C08K3/34C08K5/134B29C47/92B29C48/92
Inventor 沈国璋林先进汪涛
Owner 宁波锦地工程塑料有限公司
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