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Method for processing toxic matter-containing water and processing device

A technology of harmful substances and treatment methods, which is applied in water/sewage treatment, adsorbed water/sewage treatment, water/sludge/sewage treatment, etc. It can solve the problems of poor sludge sedimentation, achieve excellent sedimentation, and improve fluorine removal. Excellent effect, excellent fluorine removal effect

Inactive Publication Date: 2013-06-26
MITSUBISHI MATERIALS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The present invention solves the problem of poor settleability of the sludge generated in the above-mentioned conventional treatment methods, and provides a treatment system excellent in the adsorption effect on fluorine and the settleability of the generated sludge

Method used

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  • Method for processing toxic matter-containing water and processing device
  • Method for processing toxic matter-containing water and processing device
  • Method for processing toxic matter-containing water and processing device

Examples

Experimental program
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Embodiment 1

[0100] pass Figure 4 The shown treatment system treats fluoridated water as follows. First, fluorine-containing water (fluorine concentration: 20 mg / L) was introduced into the addition tank 10 , and polyaluminum chloride was added so that the aluminum concentration in the water became 240 mg / L. On the other hand, all the sludge separated in the solid-liquid separation tank 40 was returned to the second addition tank 20, where 1 g / L of magnesia was added to 1 L of fluorine-containing water. This sludge was introduced into the reaction tank 30, mixed with polyaluminum chloride-added fluorine-containing water, stirred for 30 minutes, and reacted at a temperature of 20° C. for 30 minutes. After the reaction, sodium hydroxide was added as a pH regulator to adjust the pH to 8.5 to 9.5, and the generated slurry containing sludge was introduced into a solid-liquid separation tank 40 (concentration tank) and left to stand for 20 hours to make the sludge settlement. In addition, 2 m...

Embodiment 2

[0107] pass image 3 In the shown treatment system, the fluoride-containing water is treated as follows. First, fluorine-containing water (fluorine concentration: 20 mg / L) was introduced into the addition tank 10 , and aluminum sulfate was added so that the aluminum concentration in the water became 240 mg / L. This is introduced into the reaction tank 30 . On the other hand, all the sludge separated in the solid-liquid separation tank 40 is returned to the reaction tank 30 . Then, 1 g / L of magnesium oxide was added to 1 L of fluorine-containing water in the reaction tank 30 , mixed with the fluorine-containing water to which aluminum sulfate was added, stirred for 30 minutes, and reacted at a temperature of 20° C. for 30 minutes. After the reaction, sodium hydroxide is added as a pH regulator to adjust the pH to 8.5 to 9.5, and then the slurry containing the generated sludge is introduced into the solid-liquid separation tank 40 (concentration tank) and left to stand for 20 h...

Embodiment 3

[0114] pass Figure 4 In the shown treatment system, water containing harmful substances including fluorine and heavy metals is treated as follows. First, water containing harmful substances (the concentration of harmful substances in raw water is described in Table 5) was introduced into the addition tank 10, and polyaluminum chloride was added so that the aluminum concentration in the water became 240 mg / L. This is introduced into the reaction tank 30 . On the other hand, all the sludge separated in the solid-liquid separation tank 40 was returned to the second addition tank 20, where 1 g / L of magnesium oxide was added to 1 L of water containing harmful substances. The sludge was returned to the reaction tank 30, mixed with water containing harmful substances to which polyaluminum chloride was added, stirred for 30 minutes, and reacted at a temperature of 20° C. for 30 minutes. After the reaction, sodium hydroxide was added as a pH regulator to adjust the pH to 8.5 to 9.5,...

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Abstract

Provided is a method for processing toxic matter-containing water, comprising: a step for adding an insoluble metal oxide with a layered double hydroxide as a component thereof and a soluble metal compound to water containing toxic matter; a reaction step for reacting the insoluble metal oxide, the soluble metal compound, and the toxic matter-containing water under alkaline conditions and generating a slurry that includes a sludge with layered double hydroxides formed on the surface of the insoluble metal oxide; and a solid / liquid separation step for removing toxic matter captured in the sludge to outside the system, by precipitating the sludge and solid / liquid separating the slurry.

Description

technical field [0001] The present invention relates to a method and device for treating water containing harmful substances, and more specifically, to a method for removing harmful substances from waste water containing harmful substances such as fluorine, boron, nitrogen compounds, phosphorus, and heavy metals. The treatment system of the present invention has excellent solid-liquid separation property of the sludge in which harmful substances are collected, and can settle the sludge in a short time to remove harmful substances. [0002] This application claims priority based on Japanese Patent Application No. 2010-244772 for which it applied in Japan on October 29, 2010, The content is used for this specification. Background technique [0003] Conventionally, there is known a method of trapping and removing harmful substances contained in wastewater in layered double hydroxides. For example, Japanese Patent Publication No. 2003-285076 (Patent Document 1) describes the fo...

Claims

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Application Information

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IPC IPC(8): C02F1/28C02F1/58C02F1/62
CPCC02F1/281C02F2101/14
Inventor 二瓶智也林浩志
Owner MITSUBISHI MATERIALS CORP