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Composite calcium-base octa-polyurea lubricating grease and preparation method thereof

A technology of octapolyurea-based lubricating grease and lubricating grease, which is applied in lubricating compositions, petroleum industry, thickeners, etc., can solve the problems of poor comprehensive performance of calcium-based polyurea lubricating grease, and achieve excellent comprehensive performance, excellent The effect of mechanical stability and excellent overall performance

Active Publication Date: 2013-09-11
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the hardening problem that complex calcium base grease exists, those skilled in the art try to introduce polyurea grease in complex calcium base grease, for example, CN1364859A and CN1657599A disclose respectively by introducing dipolyurea in complex calcium base grease And the obtained calcium-based polyurea grease, however, the overall performance of these calcium-based polyurea greases is not good

Method used

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  • Composite calcium-base octa-polyurea lubricating grease and preparation method thereof
  • Composite calcium-base octa-polyurea lubricating grease and preparation method thereof
  • Composite calcium-base octa-polyurea lubricating grease and preparation method thereof

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preparation example Construction

[0043] The present invention also provides a preparation method of composite calcium-based octapolyurea grease, the method comprising the following steps:

[0044] (1) In the presence of lubricating base oil, diisocyanate, diamine and monoamine are contacted and reacted, and the mixture obtained after the reaction is heated and refined, wherein the molar ratio of diisocyanate, diamine and monoamine is (3.9- 4.1):(2.9-3.1):2;

[0045] (2) In the presence of lubricating base oil, calcium hydroxide is contacted with higher fatty acids, dibasic aromatic acids and C1-C6 fatty acids, and the mixture obtained after the reaction is heated and dehydrated;

[0046] (3) The product obtained in step (1) is mixed with the product obtained in step (2).

[0047] According to the method of the present invention, step (1) and step (2) are respectively implemented in different reactors, by preparing octapolyurea grease and complex calcium-based grease respectively, and then octapolyurea grease...

Embodiment 1

[0078] This example is used to illustrate the complex calcium-based octapolyurea grease provided by the present invention and its preparation method.

[0079] (1) Preparation of octapolyurea grease

[0080] Raw material components: HVI500SN base oil (purchased from ExxonMobil Chemical Company, viscosity at 100°C is 11mm 2 / s): 435g; octadecylamine (purchased from ACROS company): 20.39g; ethylenediamine: 6.81g; 4,4'-diphenylmethane diisocyanate (purchased from ACROS company, MDI): 37.80g;

[0081] First mix 150g of HVI500SN base oil and 37.8g of MDI and heat to 50°C, then add 4.54g of ethylenediamine, and raise the temperature to 80°C, react for 30 minutes, then add 2.27g of ethylenediamine, and continue the reaction for 30 minutes Minutes to obtain mixture A1; mix 150g of HVI500SN base oil with 20.39g of octadecylamine, heat to 60°C, and add it to mixture A1, raise the temperature to 80°C for 30 minutes, then raise the temperature to 210°C for 10 minutes, and then cool natura...

Embodiment 2

[0097] This example is used to illustrate the complex calcium-based octapolyurea grease provided by the present invention and its preparation method.

[0098] Prepare complex calcium-based octapolyurea grease according to the method of Example 1, the difference is that in the process of preparing complex calcium-based grease in step (2), replace terephthalic acid with the same molar amount of isophthalic acid Formic acid to prepare complex calcium-based octapolyurea grease.

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Abstract

The invention relates to a composite calcium-base octa-polyurea lubricating grease which contains lubricating base oil, octa-polyurea and composite calcium soap, wherein the composite calcium soap is a mixture of higher fatty acid calcium, binary aromatic acid calcium and C1-C6 fatty acid calcium. The invention also relates to a preparation method of the composite calcium-base octa-polyurea lubricating grease, which comprises the following steps: (1) in the presence of the lubricating base oil, carrying out contact reaction on diisocyanate, diamine and monoamine in a mol ratio of (3.9-4.1):(2.9-3.1):2, and heating the reaction mixture for refinement; (2) in the presence of the lubricating base oil, carrying out contact reaction on the calcium hydroxide, higher fatty acid, binary aromatic acid and C1-C6 fatty acid, and heating to dehydrate the reaction mixture; and (3) mixing the product obtained in the step (1) with the product obtained in the step (2). The composite calcium-base octa-polyurea lubricating grease provided by the invention has excellent comprehensive properties.

Description

technical field [0001] The invention relates to a composite calcium-based octapolyurea lubricating grease and a preparation method of the lubricating grease. Background technique [0002] Polyurea grease (referred to as polyurea grease) is a grease prepared by thickening base oil with organic compounds containing urea groups in the molecule. Since the polyurea thickener is different from the metal soap-based thickener, it does not contain metal ions, which avoids the catalytic oxidation of the metal ions in the soap-based thickener to the grease base oil, so the polyurea grease has good oxidation stability. Excellent performance and thermal stability, making polyurea grease more suitable for lubrication under high temperature conditions. [0003] At present, the reports of articles and patents mainly focus on the preparation and synthesis of dipolyurea grease. The shear stability of dipolyurea grease is poor, and the difference between 100,000 times of work and 60 times of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M123/02C10M177/00
Inventor 王佳孙洪伟何懿峰刘磊翟浩川段庆华刘中其姜靓
Owner CHINA PETROLEUM & CHEM CORP
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