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Dissolving-dispersing detergent for scale in pipes of high-temperature high-pressure boiler superheater in power station

A high-temperature, high-pressure, superheater tube technology, applied in the field of chemical cleaning, can solve the problems of difficult scale dissolution and removal, superheater tube blockage, blade damage, etc., and achieve good solubility and dispersibility, personal safety assurance, and improved safety Effect

Inactive Publication Date: 2013-10-02
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] After a long period of operation of the high-temperature and high-pressure unit of the power station, a layer of scale is easily formed in the superheater tube, and the main component is iron oxide. , causing damage to the leaves
At present, the boiler descaling technology mainly uses chemical cleaning, but the superheater generally adopts vertically arranged U-shaped tubes. If the cleaning residue cannot be discharged outside the boiler with the cleaning liquid, it will definitely cause tube explosion.
High-temperature and high-pressure boilers generally use 12CrMoV material. Under the action of high-temperature and high-pressure steam, dense scaling is formed. It is difficult for conventional cleaning agents to dissolve and remove the scale formed by this material.

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0020] The preparation process of the cleaning agent of the present invention is as follows: respectively weighing according to the above formula, dissolving in desalinated water, and fully stirring evenly.

[0021] When in use, first make this cleaning agent into a desalination solution with an effective content of 3-10%. The cleaning agent is acidic and is best used at a temperature of 85°C-98°C, and the best cleaning time is 8-20 hours. The solubility of iron oxide scale in the superheater of high-temperature and high-pressure boiler is very good, especially for the iron oxide scale in the superheater of the boiler with 12CrMoV as the superheater material. The corrosion rate of 12CrMoV steel meets the corresponding power industry standards.

[0022] The following examples illustrate the present invention in further detail.

Embodiment 1

[0024] The invention is a cleaning agent for dissolving and dispersing scale in the superheater tube of a high-temperature and high-pressure boiler in a power station, which is composed of the following components according to the mass percentage:

[0025] Formic acid accounted for 1.5%, glycolic acid accounted for 3%, citric acid accounted for 1%, ethylenediaminetetraacetic acid accounted for 1%, methamphetamine accounted for 0.1%, mercaptobenzothiazole accounted for 0.2%, sodium dodecylsulfonate accounted for 0.1%, demineralized water accounted for 93.1%.

[0026] During implementation, take 300ml of the above-mentioned cleaning agent and clean the superheater tube sample made of 12CrMoV under the condition of 98°C. After the tube sample is processed, the length is 50mm and the thickness is 3mm. The cleaning time is 10 hours. After cleaning, the descaling rate It was 98.2%, and the dissolution rate after washing was 95.8%.

Embodiment 2

[0028] The invention is a cleaning agent for dissolving and dispersing scale in the superheater tube of a high-temperature and high-pressure boiler in a power station, which is composed of the following components according to the mass percentage:

[0029] Formic acid accounts for 1%, glycolic acid accounts for 3%, citric acid accounts for 1.5%, ethylenediaminetetraacetic acid accounts for 1%, methenamine accounts for 0.1%, mercaptobenzothiazole accounts for 0.2%, sodium dodecylsulfonate accounts for 0.1%, desalinated water 93.1%.

[0030] During implementation, take 300ml of the above-mentioned cleaning agent and clean the superheater tube sample made of 12Cr2MoWVTiB at 98°C. After the tube sample is processed, the length is 50mm and the thickness is 3mm. The cleaning time is 10 hours. After cleaning, the descaling rate It was 98.6%, and the dissolution rate after washing was 97.5%.

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Abstract

The invention belongs to the technical field of chemical cleaning and in particular relates to a dissolving-dispersing detergent for scale in pipes of a high-temperature high-pressure boiler superheater in power station. The dissolving-dispersing detergent comprises the following components in percentage by mass: 1%-4% of formic acid, 1%-6% of glycolic acid, 1%-5% of citric acid, 1%-5% of edetic acid, 0.1%-0.5% of a corrosion inhibitor, 0.1%-1% of surfactant and the balance of demineralized water. The detergent has good solubility and dispersity on iron oxide scale in the high-temperature high-pressure boiler superheater, especially has solubility and dispersity remarkably better than those of the detergent in the prior art on 12CrMoV oxide scale,. Moreover, the detergent has remarkable effects of complete cleaning and cleaning to achieve the purpose of cleaning the superheater in a circulating manner, so that the operation safety performance of the high-temperature high-pressure unit in the power station is remarkably improved, and the body safety of unit working personnel is ensured. Besides, the dissolving-dispersing detergent is suitable for cleaning a water supply system before a power station boiler, a coal saver, a water cooling wall and a superheater system.

Description

technical field [0001] The invention belongs to the technical field of chemical cleaning, and in particular relates to a cleaning agent for dissolving and dispersing scale in superheater tubes of high-temperature and high-pressure boilers in power stations. Background technique [0002] After a long period of operation of the high-temperature and high-pressure unit of the power station, a layer of scale is easily formed in the superheater tube. The main component is iron oxide. , causing damage to the leaves. At present, the boiler descaling technology mainly uses chemical cleaning, but the superheater generally adopts vertically arranged U-shaped tubes. If the cleaning residue cannot be discharged outside the boiler with the cleaning liquid, it will definitely cause a tube burst. High-temperature and high-pressure boilers generally use 12CrMoV material. Under the action of high-temperature and high-pressure steam, dense scaling is formed. It is difficult for conventional c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G1/06C23G1/08
Inventor 何凤元潘浩苗宇张庆阳田芳程晓云沈继军
Owner STATE GRID CORP OF CHINA
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