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Composite fiber modified nylon material and preparation method thereof

A composite fiber and modified nylon technology, which is applied in the field of engineering plastics, can solve the problems of high injection pressure, injection speed, injection temperature, low price of polyimide fiber, and high production cost of modified PA, so as to reduce the amount of use , high fatigue resistance, high strength effect

Inactive Publication Date: 2016-12-28
ANHUI KEJU NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, in the molding process of glass fiber reinforced PA, due to poor fluidity, higher injection pressure, injection speed and injection temperature are required; in addition, because the glass fiber will be oriented along the flow direction during the injection molding process, it will cause mechanical properties and shrinkage. The ratio is enhanced in the orientation direction, resulting in easy deformation and warping of the product; if the proportion of glass fiber added is large, it will also cause greater wear on the plasticizing components of the injection molding machine
[0004] It is also reported that PA is enhanced by adding other high-performance fibers, such as polyimide fibers. Since the price of polyimide fibers is not advantageous, the production cost of modified PA is relatively high.

Method used

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  • Composite fiber modified nylon material and preparation method thereof
  • Composite fiber modified nylon material and preparation method thereof

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preparation example Construction

[0036] Correspondingly, the embodiment of the present invention also provides a preparation method of the above composite fiber modified nylon material. The process flow diagram of the method is as figure 1 As shown, the method includes the following steps:

[0037] S01. Weighing formula components: weigh each component according to the above-mentioned composite fiber modified nylon material formula;

[0038] S02. Obtaining composite fibers: blending the above-mentioned glass fibers and polyimide fibers, and using a silane coupling agent to perform surface treatment on the blended fabrics to obtain the composite fibers;

[0039] S03. Form a mixed material: use the above-mentioned silane coupling agent to mix the composite fiber obtained in step S02 with the above-mentioned nylon and auxiliary agents, and melt extrude to obtain the above-mentioned composite fiber modified nylon material; wherein, the temperature of melt extrusion is 260 ~280℃, pressure 1.2~2.5MPa, rotation sp...

Embodiment 1

[0047] A composite fiber modified nylon material, comprising the formula components in the following percentages by weight:

[0048] Nylon 65%

[0049] Composite fiber 30%

[0050] Auxiliary 5%,

[0051] Among them, the above-mentioned composite fibers are formed by surface treatment of long fiber glass fibers with a diameter of 7 nm and a length of 50 mm and polyimide fibers with a diameter of 0.20 mm and a length of 50 mm through a silane coupling agent. The weight percentage of the amine fiber is 5:1, and the weight percentage of the total weight of the glass fiber and the polyimide fiber to the silane coupling agent is 40:10.

[0052] The preparation method of this composite fiber modified nylon material is as follows:

[0053] S11. Weigh each component respectively according to above-mentioned composite fiber modified nylon material formula;

[0054] S12. Stir and mix the above-mentioned glass fibers and polyimide fibers for blending, and use a silane coupling agent t...

Embodiment 2

[0057] A composite fiber modified nylon material, comprising the formula components in the following percentages by weight:

[0058] Nylon 55%

[0059] Composite fiber 40%

[0060] Auxiliary 5%,

[0061] Among them, the above-mentioned composite fibers are formed by surface treatment of long fiber glass fibers with a diameter of 7 nm and a length of 50 mm and polyimide fibers with a diameter of 0.2 mm and a length of 50 mm through a silane coupling agent. The weight percentage of the amine fiber is 6:1, and the weight percentage of the total weight of the glass fiber and the polyimide fiber to the silane coupling agent is 40:10.

[0062] The preparation method of this composite fiber modified nylon material is as follows:

[0063] S21. Weigh each component respectively according to above-mentioned composite fiber modified nylon material formula;

[0064] S22. Stir and mix the above-mentioned glass fibers and polyimide fibers for blending, and use a silane coupling agent to...

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Abstract

The invention discloses a composite fiber modified nylon material and a preparation method thereof. The composite fiber modified nylon material comprises the following components in percentage by weight: 50% to 70% of nylon, 29% to 50% of composite fibers, 1% to 20% of addition agent, wherein the composite fibers comprise glass fibers and polyimide fibers; the percentage by weight of the glass fibers to polyimide fibers is (1 to 9) to 1. Composite fiber is formed by the glass fibers and the polyimide fibers so as to modify the nylon. Therefore, the modified nylon material which has the advantages of strong intensity, excellent stability and excellent fatigue resistance is obtained, the defects that products are easy to deform and warp due to glass fibers are overcome by the polyimide fibers, the glass fibers enable the usage amount of the polyimide fibers to be reduced, and the cost is reduced. The preparation method mainly comprises two steps: mixing and performing melt extrusion, the technology is simple, complex equipment is not required to be added, the cost is low, the performance of composite high polymer materials is improved, and the composite fiber modified nylon material is suitable for industrial production.

Description

technical field [0001] The invention belongs to the technical field of engineering plastics, and in particular relates to a composite fiber modified nylon material and a preparation method thereof. Background technique [0002] With the miniaturization of automobiles, the high performance of electronic and electrical equipment, and the acceleration of the lightweight of mechanical equipment, the demand for nylon (PA) will greatly increase. In particular, as a structural material, PA has high requirements for its strength, heat resistance, and cold resistance. However, pure PA materials have the disadvantages of strong polarity, strong hygroscopicity, and poor dimensional stability. [0003] It has been reported that adding about 30% glass fiber to PA will significantly improve the mechanical properties, dimensional stability, heat resistance and aging resistance of PA, among which the fatigue strength is 2.5 times that before adding glass fiber . However, in the molding p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/00C08K9/06C08K7/00C08K7/14
Inventor 徐东徐永马琦入
Owner ANHUI KEJU NEW MATERIALS