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Method for improving hydration activity of steel slag

An active, steel slag technology, used in cement production and other directions, can solve the problem of low hydration activity of steel slag, shorten the final setting time, improve the compressive strength, and ensure the effect of sorting.

Active Publication Date: 2015-05-20
北京中科领向环保研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In short, the existing technology for improving the hydration activity of steel slag does not involve the treatment of 30% RO phase inert minerals in steel slag, and cannot fundamentally solve the problem of low hydration activity of steel slag. For large-scale application of mixed materials, a new steel slag treatment technology must be developed

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  • Method for improving hydration activity of steel slag

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Effect test

Embodiment 1

[0024] A method for improving the hydration activity of steel slag. The steel slag is processed into steel slag powder by grinding equipment, and then the RO phase is separated by gravity. The specific process is as follows:

[0025] The raw steel slag is crushed to less than 5mm through a rod mill, and after removing the metal iron from the material, it is ground in a disc mill or a vertical roller mill. The particle size of the steel slag powder is less than 65μm, so that the RO phase monomer mineral dissociation degree Reach over 80%. The steel slag powder passes through a magnetic iron remover to remove the metal iron particles dissociated from the grinding, and the steel slag powder is dispersed in an inert liquid medium or an air medium, and sieved with a sieve with a mesh size of about 30μm to 45μm. The coarse-grained products on the sieve are RO phase products; the fine-grained products under the sieve are active steel slag powder products.

Embodiment 2

[0027] A method for improving the hydration activity of steel slag. The steel slag is processed into steel slag powder by grinding equipment, and then the RO phase is separated by gravity. The specific process is as follows:

[0028] The raw steel slag is crushed to less than 5mm through a rod mill, and after removing the metal iron from the material, it is ground in a disc mill or a vertical roller mill. The particle size of the steel slag powder is less than 65μm, so that the RO phase monomer mineral dissociation degree Reach over 80%. The steel slag powder passes through the magnetic iron remover to remove the metal iron particles that have been ground and dissociated, and the steel slag powder is dispersed in a heavy liquid (such as diiodomethane, density 3.32g / cm 3 Etc.) or resuspension (a solid-liquid two-phase dispersion system composed of high-density solid particles and water, such as a two-phase dispersion system composed of ferrosilicon or magnetite and water, the mixin...

Embodiment 3

[0031] A method to improve the hydration activity of steel slag. The steel slag is processed into steel slag powder by grinding equipment, and then the RO phase is separated by gravity. The gravity separation is to separate the steel slag powder in a gravity field and a centrifugal field at a sedimentation rate Different size classification, the final settlement velocity of steel slag powder particles in the gravity field u 1 =d 2 (p s -p)g / (18μ), the sedimentation rate u of steel slag powder particles in the centrifugal field 2 =d 2 (p s -p)ω 2 r / (18μ). Where: d is the particle size; P s , P are the particle and air density respectively; μ is the air viscosity; ω is the angular velocity of the particle in the centrifugal field; r is the radius of rotation; g is the acceleration of gravity. The RO phase component has a large density and particle size, while the associated mineral density and particle size are small, the RO phase product with a large sedimentation rate, and the a...

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Abstract

A method for improving hydration activity of steel slag utilizes a grinding device to process the steel slag into a steel slag powder, and then utilizes gravity, a magnetic force or an electrostatic field to sort out an RO phase; and another method for sorting the RO phase is that the RO phase can be sorted out by combinatorial sorting. The hydration activity of the steel slag is improved by sorting the RO phase, and the characteristics of steel slag active minerals cannot be changed in the process. The original steel slag powder and the steel slag powder having the RO phase sorted are respectively ground into a same granularity level and are respectively used for preparing cement according to a proportion of the steel slag powder and a mineral waste residue powder and a gypsum powder of 35:60:5, a final setting time of the cement prepared from the steel slag powder having the RO phase sorted is shortened by 5.5 hours, and the 28 day compressive strength is increased by 8.5 MPa. With the combinatorial sorting mode, the content of the RO phase in an active steel slag powder product is decreased to 5% or less, and the purity of an RO phase product is increased to 90% or more. Therefore, the method can improve the hydration activity of the steel slag, and the steel slag obtained after sorting is used as a building raw material with relatively high content of gelling minerals.

Description

Technical field [0001] The invention belongs to the technical field of steel slag treatment, and particularly relates to a method for improving the hydration activity of steel slag. Background technique [0002] Steel slag is the waste slag produced in the steelmaking process. In 2011, China's crude steel output reached 683.883 million tons, and the output of steel slag was about 109.421 million tons. In 2010, the comprehensive utilization rate of steel slag was only 21%. Steel slag contains the cementing minerals of Portland cement clinker: alite (A mine), belite (B mine), iron aluminate, which can be used as a cement mixture or raw cement material. Steel slag also contains about 30% RO phase (divalent metal oxide solid solution) inert minerals. Too much steel slag will affect the early performance of cement. The existing steel slag modification methods: 1) Strengthen the mechanical activation of grinding, steam curing, and chemical activation with activator. This requires add...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B5/00C04B7/147
CPCY02P40/10
Inventor 侯新凯袁静舒李虎森贺宁董跃斌杨洪艺方红
Owner 北京中科领向环保研究院有限公司