Stable and transparent super-hydrophobic or super-amphiphobic coating as well as preparation method and application thereof

A super-hydrophobic and super-amphiphobic technology, applied in coatings, pigmented coatings, paper coatings, etc., can solve problems such as weak adhesion, poor washing resistance, and complicated processes, and achieve excellent durability and The effects of firmness, simplification of construction procedures and steps, and simple construction methods

Active Publication Date: 2013-12-11
GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method requires the preparation of block copolymers with complex processes and harsh assembly conditions
[0006] The Chinese patent application with the application number 201110266897.9 proposes a method of blending fluorine-containing silicon-containing copolymers and silicon dioxide to form a film on the surface containing active groups, which can endow the surface with good super-amphiphobic properties , this method uses more fluorine-containing silicon-containing copolymers, and requires blending and assembly reactions when used, and the process is more complicated
[0007] Although in recent years, there have been many reports on the use of fluorop

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Blend the nanoparticles, epoxy resin and solvent to obtain an epoxy resin hybrid solution, in which the mass ratio of nanoparticles, epoxy resin and solvent is 1:0.1:1; at the same time, dissolve the fluorine-containing substance and catalyst in the solvent The fluorine-containing solution is prepared to obtain the fluorine-containing solution, wherein the mass ratio of the fluorine-containing substance, the catalyst and the solvent is 1:20:20. Spray the above-mentioned epoxy resin hybrid paint on the surface of the substrate, then place the substrate in an oven, and dry it at a temperature of 80°C for 0.5 hours, then spray the above-mentioned fluorine-containing solution on the surface of the substrate, and wait for the solvent to volatilize After drying, place the substrate in an oven and dry it at 80°C for 0.5 hours, and finally rinse the surface of the substrate with a solvent to prepare a stable and transparent super-amphiphobic coating. The nanoparticles are silic...

Embodiment 2

[0035] Blending nanoparticles, epoxy resin and solvent to obtain epoxy resin hybrid solution, wherein the mass ratio of nanoparticles, epoxy resin and solvent is 1:2:20, and fluorine-containing substances and catalysts are dissolved in the solvent The fluorine-containing solution is prepared to obtain the fluorine-containing solution, wherein the mass ratio of the fluorine-containing substance, the catalyst and the solvent is 1:200:500. Spray the above-mentioned epoxy resin hybrid coating on the surface of the substrate, then place the substrate in an oven, and dry it at a temperature of 130°C for 5 hours, then spray the above-mentioned fluorine-containing solution on the surface of the substrate, and wait for the solvent to volatilize After drying, place the substrate in an oven and dry it at 130°C for 5 hours. Finally, rinse the surface of the substrate with a solvent to prepare a stable and transparent super-amphiphobic coating. The nanoparticles are calcium oxide nanoparti...

Embodiment 3

[0037] Nanoparticles, epoxy resin and solvent are blended to obtain epoxy resin hybrid solution, wherein the mass ratio of nanoparticles, epoxy resin and solvent is 1:1:10, and the fluorine-containing substance and catalyst are dissolved in the solvent to prepare A fluorine-containing solution is obtained, wherein the mass ratio of the fluorine-containing substance, the catalyst and the solvent is 1:100:100. Spray the above-mentioned epoxy resin hybrid coating on the surface of the substrate, then place the substrate in an oven, and dry it at a temperature of 110°C for 3 hours, then spray the above-mentioned fluorine-containing solution on the surface of the substrate, and wait for the solvent to volatilize After drying, place the substrate in an oven and dry it at 120°C for 4 hours, and finally rinse the surface of the substrate with an organic solvent to prepare a stable and transparent super-hydrophobic coating. The nanoparticle is titanium dioxide with a particle size of 8...

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Abstract

The invention belongs to the field of super-amphiphobic materials, and discloses a stable and transparent super-hydrophobic or super-amphiphobic coating as well as a preparation method and the application thereof. The preparation method for the coating comprises the steps as follows: blending nanoparticles, epoxy resin with a solvent to obtain the epoxy resin hybridization solution; dissolving fluorine-containing substances and a catalyst into a solvent to obtain the fluorine-containing solution; spraying the epoxy resin hybridization solution on the surface of a substrate, drying the substrate for 0.5-5 h at the temperature of 80-130 DEG C, spraying the fluorine-containing solution on the surface of the substrate, drying the substrate for 0.5-5 h at the temperature of 80-130 DEG C after the solvent is volatilized, and finally washing the surface of the substrate by using the solvent, so as to obtain the stable and transparent super-hydrophobic or super-amphiphobic coating. The super-hydrophobic or super-amphiphobic coating can be applied to hydrophobic and oleophobic modification of surfaces of the vast majority of substrates.

Description

technical field [0001] The invention belongs to the field of super-amphiphobic materials, and in particular relates to a stable and transparent super-hydrophobic or super-amphiphobic coating and a preparation method and application thereof. Background technique [0002] Due to its unique hydrophobic and oleophobic properties, superamphiphobic surfaces can be applied in many fields. The superamphiphobic surface has a self-cleaning function and can be used for solar panels or some mirrors that need to be kept clean, such as the surface of a gas cooker. Furthermore, the formation of a superamphiphobic surface on the metal surface can also greatly improve the corrosion resistance of the metal surface. In addition, if a super-amphiphobic surface is built on the wire or high-voltage power grid, it can prevent the wire from forming a frozen layer on the surface of the ice storm or snowstorm, which will cause a short circuit and cause a large-scale power outage to stop production, ...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D163/02C09D163/04C09D7/12D06M15/55D06M11/79D06M13/33D06M11/46D06M13/265C04B41/48D21H19/38D21H19/44D21H19/62D06M101/06
Inventor 胡继文邹海良刘国军李妃林树东张干伟涂圆圆胡美龙
Owner GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI
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