New polymer and coloring composition comprising the same
A technology of polymer and molar mixing ratio, which is applied in the photoplate making process of patterned surface, photosensitive materials used in optomechanical equipment, instruments, etc., can solve the problem of discoloration of colored compositions, reduce bumps and prevent discoloration Yellow, excellent heat resistance effect
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Synthetic example 1
[0179] In the reaction vessel, 2.17 parts by weight of the thermal initiator V-65 were dissolved in the solvent, and then 1-adamantyl methyl methacrylate / styrene / methacrylic acid were dropped into 60 / 12 / 28 mole % respectively, The reaction was then maintained at 60° C. under a nitrogen atmosphere for 12 hours. The acid value of the prepared binder resin was 100 KOHmg / g, and the weight average molecular weight was 8,100.
Synthetic example 2
[0181] In a reaction vessel, dissolve 2.17 parts by weight of thermal initiator V-65 in a solvent, and then put 1-adamantyl methyl methacrylate / N-cyclohexyl at a molar % of 47 / 8 / 9 / 28 / 8 Maleimide / styrene / methacrylic acid / dodecyl methyl methacrylate followed by maintaining 60°C under nitrogen atmosphere and allowing the reaction to proceed for 12 hours. The acid value of the prepared binder resin was 98 KOHmg / g, and the weight average molecular weight was 8,500.
Synthetic example 3
[0183] In the reaction vessel, 2.17 parts by weight of the thermal initiator V-65 was dissolved in the solvent, and then 49 / 8 / 10 / 25 / 8 mole % were put into cyclohexyl methyl methacrylate / N-cyclohexyl maleic acid Imine / styrene / methacrylic acid / dodecylmethyl methacrylate, followed by maintaining 60°C under nitrogen atmosphere and allowing the reaction to proceed for 12 hours. The prepared binder resin had an acid value of 105 KOHmg / g and a weight average molecular weight of 8,000.
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