Optical film for 3D image display, 3D image display device, and 3D image display system
An image display element and optical film technology, applied in the field of optical films, can solve the problems of not describing the details of the liquid crystal material, not revealing the disc-type liquid crystal, etc., and achieve the effect of improving the viewing angle characteristics
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[0336] [Preparation of Low Refractive Index Layer]
[0337] The low refractive index layer can be prepared by dissolving or dispersing a fluorine-containing antifouling agent having at least one polymerizable unsaturated group, a fluorine-containing copolymer having at least one polymerizable unsaturated group, inorganic fine particles, and any desired The ingredients prepare a coating liquid and apply it to a surface. Simultaneously with coating or after coating and drying, its crosslinking reaction or polymerization is performed under ionizing radiation such as light and electron beams or heat irradiation, thereby hardening.
[0338] Specifically, if the low-refractive index layer is prepared by cross-linking reaction or polymerization of ionizing radiation curable compounds, it is preferable to perform cross-linking or polymerization in an atmosphere having an oxygen concentration of 10 vol% or less. By forming the layer in an atmosphere having an oxygen concentration of 1...
example 1
[0380]
[0381] Cellulose acylate solution A was prepared by placing the following ingredients in a mixing tank and dissolving by stirring with heat.
[0382]
[0383] Additive Solution B was prepared by placing the following ingredients in separate mixing tanks and dissolving by stirring with heat.
[0384]
[0385] Compound B1:
[0386]
[0387] Compound B2:
[0388]
[0389] >
[0390] 40 parts by mass of additive solution B was added to 477 parts by mass of cellulose acylate solution A and thoroughly stirred to prepare a dope. The paint was cast via a casting spout onto barrels cooled at 0 degrees Celsius. When the solvent content therein reached 70% by mass, the formed film was peeled off, and both sides in the width direction thereof were fixed with a pin tenter (described in JP-A4-1009 image 3 middle). When the solvent content in the film is 3% by mass to 5% by mass and the distance at the pin tenter is controlled so that the stretch ratio of the fil...
example 2
[0452]
[0453] TD80UL (manufactured by FUJIFILM) was prepared and used as transparent support B. TD80UL has a thickness of 80 microns, its in-plane retardation Re(550) is 2 nm, and its thickness-wise retardation Rth(550) is 40 nm.
[0454]
[0455] A patterned optically anisotropic layer B was fabricated in the same manner as in Example 1, except that the transparent support A was changed to the above-mentioned transparent support B, and the formula of the rubbing alignment layer coating liquid was changed to the following formula. The thickness of the alignment layer was 0.5 micrometers, and the thickness of the optically anisotropic layer was 0.9 micrometers.
[0456]
[0457] Photoacid generator I-33:
[0458]
[0459] The first retardation domain and the second retardation domain of the patterned optically anisotropic layer B thus formed were analyzed according to TOF-SIMS (time-of-flight secondary ion mass spectrometry, using TOF-SIMS V from ION-TOF). The sec...
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