This invention relates to the field of organic photovoltaic (PV) device technology, specifically to an organic PV device based on disk-shaped
liquid crystal molecules, its fabrication method, and its applications. The organic PV device based on disk-shaped
liquid crystal molecules provided by this invention comprises an
anode substrate, a
hole transport layer, an
active layer, an
electron transport layer, and a
metal cathode stacked sequentially. The
active layer is composed of a donor material, an
acceptor material, and a benzo[a]
phenanthrene disk-shaped
liquid crystal derivative. The benzo[a]
phenanthrene disk-shaped liquid
crystal derivative self-assembles into a two-dimensional columnar
superlattice nanostructure. The benzo[a]
phenanthrene disk-shaped liquid
crystal derivative has the structure shown in Formula I and / or Formula II, where R1 and R2 independently comprise a
cycloalkane-furanyl or adamantyl group. Based on the self-
assembly behavior of the benzo[a]phenanthrene disk-shaped liquid
crystal derivative, this invention constructs an ordered columnar
superlattice structure by controlling its steric hindrance and
dipole interactions, significantly improving the charge transport efficiency and
energy conversion efficiency of the device.