The invention concerns high sensitivity
light scattering detection and its application to evaporative
light scattering detection in liquid
chromatography. The exemplary embodiment includes a detection
cell to accept particles suspended in a gas
stream and permit a polarized
light beam to pass through a trajectory of the particles and gas
stream. A sample
light detector is disposed to detect light scattered in the detection
cell. A light trap accepts the polarized beam after it passes through the detection
cell. The light trap includes an elongated housing through which the polarized beam passes, and light absorptive material within the elongated housing. An absorptive filter is aligned such that the
angle of incidence of the
light beam upon the filter approximates Brewster's angle and the
electric field vector of the beam is aligned with the
plane of incidence between the beam and the filter. Other embodiments of the invention provide increased light collection. Embodiments of the invention include temperature-controlled entrance and exit ports that control
particle trajectory. Embodiments of the invention include a
reference cell disposed between a detection cell and a light trap, and the
reference cell includes lensing and a spherical mirror to direct light toward a reference
light detector. The reference
light detector provides a reference
signal that may be used with
noise cancellation circuitry, operating in either
voltage or
current mode, to reduce
light source noise in the sample
signal.