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Preparation method of moisture-proof konjac glucomannan packaging film

A konjac glucomannan and packaging film technology, which is applied in packaging, wrapping paper, biological packaging, etc., can solve the problems of complex chemical modification process, poor resistance to boiling water, and difficult control of the process, achieving good application prospects, Effects of improved moisture barrier performance, light transmittance and mechanical properties

Inactive Publication Date: 2015-12-02
SHANDONG INST OF COMMERCE & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In terms of chemical modification, "Science and Engineering of Polymer Materials" published the article "Research on Konjac Glucomannan Acrylamide Film" by Li Na et al. The graft copolymerization of KGM and acrylamide was prepared by grafting and copolymerization of KGM and acrylamide. It was found that the modified KGM film after grafting had excellent water resistance, but the ability of this film to withstand boiling water was poor, and the short-term Soaking in boiling water will make it swell or even dissolve
Moreover, the chemical modification process is complicated, the operation is cumbersome, and the process is not easy to control

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Preparation of deacetylated konjac glucomannan-based film: Slowly dissolve 1wt% KGM in distilled water under stirring, stir at room temperature for 3 hours and add 0.3wt% Na 2 CO 3 The solution was stirred for 10 minutes and then allowed to stand for 40 minutes to fully deacetylate to obtain deacetylated konjac glucomannan, marked as I.

[0018] After I was cast on a polystyrene plate, it was dried in an oven at 50°C for 6 hours.

[0019] The dried film was washed with running water and then with distilled water to remove the residual alkali in the film, and then the wet film was dried in air at room temperature to obtain a dry KGM base film.

[0020] Preparation of shellac and stearic acid composite coating: Dissolve 20wt% bleached shellac in 95% ethanol solution under stirring, after stirring evenly, add PEG400 accounting for 8wt% of the dry weight of shellac, and continue stirring for 40min. Quality 15-30min, obtain shellac paint.

[0021] Add 5wt% stearic acid in...

Embodiment 2

[0024] Preparation of deacetylated konjac glucomannan-based film: Slowly dissolve 0.5wt% KGM in distilled water under stirring, stir at room temperature for 2 hours and add 0.15wt% Na 2 CO 3 The solution was stirred for 5 minutes and then allowed to stand for 30 minutes to fully deacetylate to obtain deacetylated konjac glucomannan, marked as I. After casting I on a glass plate, dry it in an oven at 45°C for 4h. The dried film was washed with running water and then with distilled water to remove the residual alkali in the film, and then the wet film was dried in air at room temperature to obtain a dry KGM base film.

[0025] Preparation of shellac and stearic acid composite coating: Dissolve 6wt% bleached shellac in 95% ethanol solution under stirring, after stirring evenly, add PEG400 accounting for 6wt% of the dry weight of shellac, and continue stirring for 30min. Quality 15min, obtain shellac paint. 20wt% stearic acid was added to the shellac paint under stirring state,...

Embodiment 3

[0028] Preparation of deacetylated konjac glucomannan-based film: Slowly dissolve 1.5wt% KGM in distilled water under stirring, stir at room temperature for 4 hours and add 0.45wt% Na 2 CO 3 The solution was stirred for 15 minutes and then allowed to stand for 60 minutes to fully deacetylate to obtain deacetylated konjac glucomannan, marked as I.

[0029] After casting I on a Petri dish, dry it in an oven at 65°C for 10 hours. The dried film was washed with running water and then with distilled water to remove the residual alkali in the film, and then the wet film was dried in air at room temperature to obtain a dry KGM base film.

[0030]Preparation of shellac and stearic acid composite coating: dissolve 30wt% bleached shellac in 95% ethanol solution under stirring state, after stirring evenly, add PEG400 accounting for 12wt% of shellac dry weight, after continuing to stir for 60min, homogeneous Quality 30min, obtain shellac paint. Add 40wt% stearic acid into the shellac p...

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PUM

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Abstract

The invention belongs to the field of natural polymer materials, and in particular relates to a preparation method of a konjac glucomannan packaging film with significant moisture resistance. The preparation method of the konjac glucomannan packaging film comprises the steps of (1) preparing a deacetylated konjac glucomannan base film; (2) preparing a lac and stearic acid composite coating; (3) coating the konjac glucomannan film with the lac and stearic acid composite coating. The konjac glucomannan film prepared by the method disclosed by the invention has significant moisture resistance, does not need further modification, has a writable surface, and is nontoxic, edible and biodegradable. The moistureproof konjac glucomannan packaging film is simple in technical process, and has a very good application prospect in the field of food packaging, storage and fresh keeping.

Description

technical field [0001] The invention belongs to the field of natural polymer materials, and in particular relates to a preparation method of a konjac glucomannan packaging film with remarkable moisture resistance. Background technique [0002] The extensive use of synthetic polymer packaging materials has caused serious environmental pollution problems, and it is imminent to seek renewable resources to replace petroleum. Konjac is a specialty resource in my country, with various varieties and abundant output. Konjac glucomannan (KGM) extracted from konjac is another renewable natural polymer polysaccharide with abundant sources after cellulose and starch. In recent years, the research and development of KGM film materials has become an important direction in the field of green packaging. However, due to the large number of hydrophilic groups on the KGM molecular chain, the KGM film has high deliquescence, poor water resistance, easy swelling or even dissolution, and cannot...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J5/18B65D65/46B65D65/42C08B37/02
CPCY02W90/13Y02A40/90Y02W90/10
Inventor 张长峰魏雪琴聂小宝侯成杰程丽林庞杰王国利
Owner SHANDONG INST OF COMMERCE & TECH