Lithium ion battery negative electrode material and preparation method thereof as well as lithium ion battery negative electrode plate and lithium ion battery

A technology for lithium-ion batteries and negative electrode materials, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of high cost, low energy density of lithium-ion batteries, and low specific capacity of negative electrode materials, and achieve high rate performance and high capacity, less responsive effect

Active Publication Date: 2014-03-26
厦门海辰新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of this, the first aspect of the embodiment of the present invention provides a lithium ion battery negative electrode material to solve the problem of lithium titanate Li 4 Ti 5 o 12 The specific capacity of the negative electrode material is low, and the lithium-ion battery made of it has low energy density and high cost.

Method used

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  • Lithium ion battery negative electrode material and preparation method thereof as well as lithium ion battery negative electrode plate and lithium ion battery
  • Lithium ion battery negative electrode material and preparation method thereof as well as lithium ion battery negative electrode plate and lithium ion battery
  • Lithium ion battery negative electrode material and preparation method thereof as well as lithium ion battery negative electrode plate and lithium ion battery

Examples

Experimental program
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Embodiment 1

[0076] A kind of preparation method of negative electrode material of lithium ion battery

[0077] Add 25.0g polyvinylidene fluoride (PVDF) to 500g N-2-methylpyrrolidone (NMP), add 25.0g graphite conductive agent after stirring for 4 hours, add lithium titanate Li after stirring for 2 hours 4 Ti 5 o 12 360.0g, stirred for 4 hours, then added 90.0g of FeS material, stirred for 4 hours to obtain a stable mixed negative electrode slurry, which is the negative electrode material for lithium ion batteries. Wherein, the temperature during stirring is 30° C., and the stirring speed is 2500 rpm for rotation and 30 rpm for revolution.

[0078] Preparation of Lithium-ion Battery Negative Electrode

[0079] Take the above-mentioned lithium ion battery negative electrode material slurry, and coat it on the perforated aluminum foil, and the coating weight is 8.66g / cm 2 (without aluminum foil), bake the electrode in an oven at 100-120°C, roll the baked and dried electrode sheet to obtai...

Embodiment 2

[0084] A kind of preparation method of negative electrode material of lithium ion battery

[0085] Add 21.4g polyvinylidene fluoride (PVDF) to 500g N-2-methylpyrrolidone (NMP), add 42.9g carbon black conductive agent after stirring for 1 hour, add lithium titanate Li after stirring for 2 hours 4 Ti 5 o 12 162.9g, stirred for 1 hour, then added 8.6g of FeS material, stirred for 3 hours to obtain a stable mixed negative electrode slurry, which is the negative electrode material for lithium ion batteries. Wherein, the temperature during stirring is 30° C., and the stirring speed is 3500 rpm for rotation and 40 rpm for revolution.

[0086] Preparation of negative electrode sheet for lithium ion battery

[0087] Take the above-mentioned lithium ion battery negative electrode material slurry, and coat it on the perforated aluminum foil, and the coating weight is 12.01g / cm 2 (without aluminum foil), bake the electrode in an oven at 100-120°C, roll the baked and dried electrode sh...

Embodiment 3

[0091] A kind of preparation method of negative electrode material of lithium ion battery

[0092] Add 36.7g polyvinylidene fluoride (PVDF) to 500g N,N-dimethylformamide (DMF), stir for 2 hours, add 61.1g carbon fiber, stir for 3 hours, add lithium titanate Li 4 Ti 5 o 12308.0g, stirred for 1 hour, then added 205.3g of NiS material, stirred for 4 hours to obtain a stable mixed negative electrode slurry, which is the negative electrode material for lithium ion batteries. Wherein, the temperature during stirring is 30° C., and the stirring speed is 3000 rpm for rotation and 50 rpm for revolution.

[0093] Preparation of Lithium-ion Battery Negative Electrode

[0094] Take the above-mentioned lithium ion battery negative electrode material slurry, and coat it on the perforated aluminum foil, and the coating weight is 9.04g / cm 2 (without aluminum foil), bake the electrode in an oven at 100-120°C, roll the dried electrode sheet to obtain a negative electrode sheet with a thickn...

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Abstract

The embodiment of the invention provides a lithium ion battery negative electrode material. The lithium ion battery negative electrode material comprises a negative electrode active material, a conductive agent, a bonding agent and an organic solvent, wherein the negative electrode active material comprises lithium titanate Li4Ti5O12 and transition metal sulfide; the lithium titanate Li4Ti5O12 accounts for 50%-95% of the total mass of the negative electrode active material; the transition metal sulfide is one or more of NiS, FeS2, FeS, TiS2, MoS and Co9S8; the negative electrode active material, the conductive agent and the bonding agent account for 70%-90%, 5%-20% ad 5%-10% of the total mass of the negative electrode active material, the conductive agent and the bonding agent respectively; the organic solvent accounts for 30%-70% of the total mass of the lithium ion battery negative electrode material. The lithium ion battery negative electrode material is high in capacity and has good cycling stability and durability. The embodiment of the invention further provides a preparation method of the lithium ion battery negative electrode material, a negative electrode plate containing the lithium ion battery negative electrode material and a lithium ion battery.

Description

technical field [0001] The invention relates to the field of lithium ion batteries, in particular to a lithium ion battery negative electrode material and a preparation method thereof, a lithium ion battery negative electrode sheet and a lithium ion battery. Background technique [0002] Since the 1990s, among many alternative energy products, lithium-ion batteries have attracted people's close attention due to their high energy density, good cycle performance, and no memory effect. With the low-carbon economy in the ascendant, lithium-ion batteries are actively developing in the direction of power vehicles and grid energy storage. Therefore, the development of lithium-ion batteries with high energy density and long cycle life has become the focus of industry research. [0003] At present, most commercial lithium-ion batteries use carbon-based materials as negative electrode active materials, but carbon-based negative electrode materials have many defects. Failure risks and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/485H01M4/62
CPCY02E60/122H01M4/364H01M4/485H01M4/5815H01M4/622H01M4/625H01M10/0525Y02E60/10
Inventor 张光辉叶海林
Owner 厦门海辰新材料科技有限公司
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