Halogen-free flame-retardant polyethylene material and preparation method thereof
A technology of flame-retardant polyethylene and polyethylene, which is applied in the field of halogen-free flame-retardant polyethylene materials and its preparation, can solve the problem of affecting the mechanical properties and processing properties of materials, low flame-retardant efficiency of flame-retardant systems, and large additions of flame retardants and other problems, to achieve the effect of good appearance, excellent comprehensive performance and low smoke emission
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Embodiment 1
[0018] A halogen-free flame-retardant polyethylene material, whose components are proportioned by mass percentage: polyethylene 70%, compound halogen-free flame retardant 15%, nano calcium carbonate 8%, ethylene-methyl acrylate-methyl The compound of glycidyl acrylate terpolymer (E-MA-GMA) 4%, polyethylene wax 1.5%, aluminum titanium composite coupling agent 0.5%, hindered phenol antioxidant 1010 and phosphite antioxidant 168 Compound 1%. Wherein, the compound type halogen-free flame retardant is a mixture of 50wt% amine polyphosphate (APP), 25wt% polyphosphate melamine salt (MPP) and 25wt% nano-montmorillonite.
[0019] Preparation method: (1) Weigh 50wt% of amine polyphosphate (APP), 25wt% of polyphosphate melamine salt (MPP) and 25wt% of nano-montmorillonite according to the weight ratio, and mix them uniformly to obtain a compound halogen-free The flame retardant is then dried at 80℃~85℃ for 30~45 minutes, set aside; (2) Weigh the nano calcium carbonate and aluminum titanium...
Embodiment 2
[0021] A halogen-free flame-retardant polyethylene material whose components are proportioned by mass percentage: polyethylene 55%, compound halogen-free flame retardant 28%, nano calcium carbonate 10%, ethylene-methyl acrylate-methyl Compound of glycidyl acrylate terpolymer (E-MA-GMA) 4%, polyethylene wax 1.6%, aluminum titanium composite coupling agent 0.8%, hindered phenol antioxidant 1010 and phosphite antioxidant 168 Compound 0.6%. Wherein, the compound type halogen-free flame retardant is a mixture of 50wt% amine polyphosphate (APP), 25wt% polyphosphate melamine salt (MPP) and 25wt% nano-montmorillonite.
[0022] Preparation method: (1) Weigh 50wt% of amine polyphosphate (APP), 25wt% of polyphosphate melamine salt (MPP) and 25wt% of nano-montmorillonite according to the weight ratio, and mix them uniformly to obtain a compound halogen-free The flame retardant is then dried at 80℃~85℃ for 30~45 minutes, set aside; (2) Weigh the nano calcium carbonate and aluminum titanium c...
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