Salt-thickened water-soluble branched polymer as well as preparation method and application thereof
A branched polymer, water-soluble technology, used in chemical instruments and methods, drilling compositions, etc., can solve problems such as limited improvement ability, and achieve the effect of stable product performance and high shear resistance.
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[0065] Example 1. Preparation of salt-thickened water-soluble branched polymer
[0066] (1) Preparation of zwitterionic monomers: 12g of 4-vinylpyridine and 10g of 13-propane sultone are prepared by ring-opening polymerization under the action of 2g of hydrochloric acid at a reaction temperature of 80°C and a reaction time of 8 hours (Formula I);
[0067] (2) Dissolve 71gAM and 12gVPPS in 400g H 2 O, mechanical stirring, pass condensate water, pass in N 2 ; Raise temperature to 45℃, inject CeCl 3 30mg, react for 1.5 hours;
[0068] (2) Inject 5.4mg HPG and add 30mg CeCl 3 , React for 1.5 hours, and keep at 45℃;
[0069] (3) Add 2g AM and 1g VPPS, add 2g fluorocarbon amphiphilic surfactant, and react for 1.5 hours;
[0070] (4) Place the reactor in an oven at 80°C for 4 hours.
[0071] (5) Take out the reactor and add 16.0g NaOH to it, pass the condensed water, mechanically stir, and hydrolyze at 140℃ for 2 hours.
[0072] The hydrogen NMR spectrum of the salt-thickened water-soluble branc...
Example Embodiment
[0075] Example 2. Preparation of salt-thickened water-soluble branched polymer
[0076] (1) Preparation of zwitterionic monomers: 14g vinyl pyridine and 14g 1,3-propane sultone are prepared by ring-opening polymerization under the action of 4g hydrochloric acid, reaction temperature 90℃, reaction time 6 hours;
[0077] (2) Dissolve 68gAM and 16gVPPS in 390g H 2 O, mechanical stirring, pass condensate water, pass in N 2 ; Heat up to 50℃, inject CeCl 3 40mg, react for 2 hours;
[0078] (3) Inject 5.0mg HPG and add 40mg CeCl 3 , React for 2 hours and keep at 50℃;
[0079] (4) Add 3g AM and 1.5g VPPS, add 3g fluorocarbon amphiphilic surfactant, and react for 2 hours;
[0080] (5) Place the reactor in an oven at 90°C for 6 hours.
[0081] (6) Take out the reactor and add 16.8g NaOH into it, pass the condensed water, mechanically stir, and hydrolyze at 120°C for 4 hours.
[0082] The hydrogen nuclear magnetic resonance spectrum of the water-soluble branched polymer prepared in this example and ...
Example Embodiment
[0085] Example 3. Preparation of salt-thickened water-soluble branched polymer
[0086] (1) Preparation of zwitterionic monomers: 16g vinyl pyridine and 14g 1,3-propane sultone are prepared by ring-opening polymerization under the action of 4g hydrochloric acid, reaction temperature 90℃, reaction time 7 hours;
[0087] (2) Dissolve 72gAM and 14g VPPS in 400g H 2 O, mechanical stirring, pass condensate water, pass in N 2 ; Raise the temperature to 48℃ and inject CeCl 3 35mg, react for 2 hours;
[0088] (3) Inject 6.0mg HPG and supplement 35mg CeCl 3 , React for 1.5 hours, and keep at 48℃;
[0089] (4) Add 2.5gAM1.25gVPPS, add 2.5g fluorocarbon amphiphilic surfactant, and react for 1.5 hours;
[0090] (5) Place the reactor in an oven at 85°C for 5 hours.
[0091] (6) Take out the reactor and add 17g NaOH to it, pass the condensed water, mechanically stir, and hydrolyze at 130°C for 3 hours.
[0092] The hydrogen nuclear magnetic resonance spectrum of the water-soluble branched polymer prepa...
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