Method for re-concentrating vanadium-titanium magnetite concentrate through alkaline leaching, acid pickling and magnetic separation

Abstract

The invention discloses a method for re-concentrating vanadium-titanium magnetite concentrate through alkaline leaching, acid pickling and magnetic separation. The method comprises the following steps: placing the vanadium-titanium magnetite concentrate in an alkali solution of which the mass concentration is 5-52% to be subjected to alkaline leaching reaction at the temperature of 280-370 DEG C for 0.5-5 hours, and filtering to obtain a filtrate and an alkaline leached filter cake A; preparing the filter cake A into ore pulp by adding water according to the fact that the mass ratio of solid to liquid is 1:(1-10), placing the ore pulp into an H2SO4 solution of which the mass concentration is 1-10% to be subjected to acid pickling at the temperature of 50-90 DEG C for 5-60 minutes, and filtering to obtain a filtrate and an acid picked filter cake B; preparing the filter cake B into ore pulp of which the mass concentration is 30-35% by adding water to be subjected to magnetic separation, so as to obtain iron ore concentrate of which the TFe content is 64-68% and titanium concentrate of which the TiO2 content is 40-60%. The method has the advantages that the vanadium-titanium magnetite concentrate can be efficiently sorted, the alkali consumption is low, the content of impurities such as Al and Si entering a blast furnace, especially the content of detrimental impurities such as TiO2 and S, is reduced, the utilization coefficient of the blast furnace is increased, the iron-making cost is reduced, the problem of high S content in the smelting process is solved, and the comprehensive utilization ratio of a titanium resource is increased at the same time.

Description

technical field

[0001] The invention relates to a beneficiation process of vanadium-titanium magnetite concentrate, in particular to a method for re-selecting vanadium-titanium magnetite concentrate by alkali leaching, pickling and magnetic separation. Background technique

[0002] Vanadium-titanium magnetite is a compound ore of multi-metal elements, which is a symbiotic magnetite mainly containing iron, vanadium and titanium. The vanadium-titanium magnetite concentrate is one of the products obtained from vanadium-titanium magnetite through ore dressing, in which vanadium exists in the titanium magnetite in the same quality and isomorphism to replace high-valent iron ions. Titanomagnetite is the main crystal mineral (Fe 3 o 4 ) and guest crystal ore [titanium iron spar 2FeO·TiO 2 , Ilmenite FeO TiO 2 , Al-Mg spinel (Mg, Fe) (Al, Fe) 2 o 4 ] The complex formed. For example, the chemical multi-element analysis results of vanadium-titanium magnetite raw ore and vanadiu...

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