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A kind of processing method of berberine hydrochloride wastewater

A technology of berberine hydrochloride and a treatment method, which is applied in the field of treatment of berberine hydrochloride waste water, can solve the problems such as speed and efficiency that have not yet reached the requirements of large-scale application in engineering, water effluent effect that is difficult to meet discharge standards, and limited engineering application value, etc. To achieve the effect of saving manpower, reducing pollution load and toxicity, and low cost of treatment

Active Publication Date: 2016-06-22
LIAONING UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The speed and efficiency of physical and chemical methods have not yet met the requirements of large-scale application in engineering, and the cost is also high, so the application value of actual engineering is limited
Moreover, due to the antibacterial properties of antibacterial substances at low concentrations and bactericidal at high concentrations, when the initial concentration of berberine hydrochloride changes greatly, the treatment effect is likely to be unsatisfactory, which makes it difficult for the effluent effect to meet the corresponding discharge requirements of the country. standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Take 300mL of berberine hydrochloride solution with a concentration of 400mg / L in a 500mL beaker, add NaNO 3 , so that the concentration of nitrate in the solution is 0.1, 0.5, 1.0, 2.0mmol / L, then add humic acid to make the concentration 2mg / L, add hydrogen peroxide to make the concentration 1mmol / L, and place it in the photodegradation reaction In the equipment, react for 3h. Take out the beaker after the reaction finishes, and measure the berberine hydrochloride content in the solution. The results are shown in Table 1.

[0015] Table 1

[0016] Nitrate concentrationmmol / L

Embodiment 2

[0018] Take 400mg / L berberine hydrochloride solution 300mL in a 500mL beaker, add NaNO 3 1.0mmol / L, add humic acid respectively, so that the concentration of humic acid in the solution is 2, 5, 8, 10mg / L, then add hydrogen peroxide to make the concentration 20mmol / L, and place it in the photodegradation reaction equipment , Reaction 3h. Take out the beaker after the reaction finishes, and measure the berberine hydrochloride content in the solution. The results are shown in Table 2..

[0019] Table 2

[0020] Humic acid concentration mg / L

Embodiment 3

[0022] Get the berberine hydrochloride solution 300mL that concentration is 400mg / L in 500mL beaker, add sodium nitrate and make its concentration be 1.0mmol / L, add humic acid and make its concentration be 5mg / L, add hydrogen peroxide (30% peroxide) again Hydrogen peroxide solution), so that the concentration of hydrogen peroxide in the solution is 1, 5, 10, 20mmol / L respectively, placed in the photodegradation reaction equipment, and reacted for 3h. Take out the beaker after the reaction finishes, and measure the berberine hydrochloride content in the solution. The results are shown in Table 3.

[0023] table 3

[0024] Concentration of hydrogen peroxide mmol / L

[0025] In sum, the present invention passes, and initial concentration is the berberine hydrochloride waste water of 400mg / L, adopts photodegradation method to degrade berberine hydrochloride optimal condition is: add nitrate in waste water, make the nitrate concentration in the solution be 1mmol / L L, add...

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PUM

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Abstract

The invention relates to a method for treating berberine hydrochloride wastewater. The technical scheme adopted is: use photodegradation to treat berberine hydrochloride wastewater: adjust the concentration of wastewater to an initial concentration of berberine hydrochloride of 400 mg / L, and add appropriate amount of nitrate, humic acid and hydrogen peroxide to the wastewater. The invention has the advantages of simple operation, energy saving, manpower saving, no secondary pollutants in the treatment process, good pollutant removal effect, and significantly improved effluent quality.

Description

technical field [0001] The invention relates to a water treatment method, in particular to a treatment method for berberine hydrochloride wastewater. Background technique [0002] Berberine Hydrochloride Molecular Formula C 20 h 18 ClNO 4 , Molecular weight 407.85, yellow crystalline powder, synthetic broad-spectrum antibacterial drug. Berberine hydrochloride has pharmacological effects such as antibacterial and antidiarrheal, antiarrhythmic, positive inotropic, hypoglycemic, and inhibition of platelet aggregation, and also has anticancer activity. As a broad-spectrum antibacterial drug, berberine hydrochloride is widely used in medical treatment, pharmacy, animal husbandry, and aquaculture. However, when berberine hydrochloride is prepared, berberine hydrochloride often flows into natural water bodies or soil along with wastewater. The refractory and accumulation of pollutants in water containing berberine hydrochloride will have serious adverse effects on water ecologi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/30C02F101/38
Inventor 徐成斌东天王闻烨马溪平孟雪莲李万龙李鲜珠
Owner LIAONING UNIVERSITY