Coal tar catalytic upgrading method

A coal tar and coal coking technology, which is applied in the fields of hydrocarbon oil cracking and petroleum industry, can solve the problems of excessive heat, difficulty in catalytic cracking, consumption, etc., and achieve the goals of saving heat energy, increasing tar utilization efficiency, good application prospects and economic benefits Effect

Inactive Publication Date: 2014-11-05
TAIYUAN UNIV OF TECH
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Problems solved by technology

[0006] The shortcomings of the above technologies are mainly reflected in: 1. For the heavy components (bitumen) of coal tar up to 50%, there is no good treatment method at present; 2. The heavy components (bitumen) in the condensed tar It has already been highly condensed, and catalytic cracking is more difficult; 3. After the coal tar is condensed and separated, the light components of the tar are then heated and hydrotreated, and the process consumes more heat

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Embodiment Construction

[0019] The present invention will be further described in detail below in conjunction with specific examples.

[0020] In order to verify the feasibility of the present invention, select coking coal as the research object, carry out the pyrolysis and catalysis experiment of coking coal in fast pyrolysis instrument, the volatile matter gained from pyrolysis is separated by gas chromatography and mass spectrometry respectively before and after catalysis, to determine its Composition and content of each component. By comparing the difference between the products before and after the catalysis, the feasibility of the present invention can be judged.

[0021] Sampling by quartering method, after crushing, grinding and sieving Fenxi coking coal, select 60-100 mesh coking coal samples. 13X molecular sieve and Fe 3 o 4 Separately crush, grind and sieve, select 13X molecular sieve and Fe 3 o 4 as a catalyst.

[0022] Add a quartz column to the quartz cracking tube of the fast pyr...

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Abstract

The invention discloses a coal tar catalytic upgrading method which is as follows: a catalytic segment is added into the coal coking process, a catalyst is put into the catalytic segment, the catalytic segment is arranged between a coke oven coal pyrolysis crude coal gas outlet and an ammonia cooling section, 650 to 800 DEG C discharged crude coal gas from a coke oven directly enters into the catalytic segment to fully contact with the catalyst in the catalytic segment for catalytic cracking of heavy components in coal tar, and then enters into the ammonia cooling section for ammonia condensation. The method can effectively reduce the heavy component content in tar, promote low polycyclic aromatic compound formation, improve the yield of chemical products, increase the tar utilization efficiency and avoid the pipeline blocking problem caused by heavy tar condensation for the reason of systematic temperature change, reduces heavy subsequent purification processing work, and has the good application prospect and economic benefit.

Description

technical field [0001] The invention relates to a method for upgrading coal tar, in particular to a method for realizing on-line lightening of heavy components of coal tar in a coal coking process. Background technique [0002] Coal is the main fossil energy in my country in the next 50 years, and it is the energy guarantee for the development of the national economy. There are many ways of coal processing and utilization, and the coal coking industry to support the steel industry is one of the main ways of processing and utilization. Coal tar is an associated product in the coking process, and its output accounts for about 3% of the coal in the furnace. Tar is rich in unique fused-ring aromatic compounds and is a valuable chemical industry resource. Reasonable processing of coal tar can extract valuable chemical products and improve the utilization efficiency of tar. [0003] In the current tar rectification and separation process, the yield of heavy components of coal t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G47/20
Inventor 闫伦靖白永辉李凡李冠龙赵瑞芳
Owner TAIYUAN UNIV OF TECH
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